• Membrane Journal
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• v.32 no.5
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• pp.292-303
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• 2022

An eco-friendly energy conversion device without the emission of pollutants has gained much attention due to the rapid use of fossil fuels inducing carbon dioxide emissions ever since the first industrial revolution in the 18th century. Polymer electrolyte membrane fuel cells (PEMFCs) that can produce water during the reaction without the emission of carbon dioxide are promising devices for automotive and residential applications. As a key component of PEMFCs, polymer electrolyte membranes (PEMs) need to have high proton conductivity and physicochemical stability during the operation. Currently, perfluorinated sulfonic acid-based PEMs (PFSA-PEMs) have been commercialized and utilized in PEMFC systems. Although the PFSA-PEMs are found to meet these criteria, there is an ongoing need to improve these further, to be useful in practical PEMFC operation. In addition, the well-known drawbacks of PFSA-PEMs including low glass transition temperature and high gas crossover need to be improved. Therefore, this review focused on recent trends in the development of high-performance PFSA-PEMs in three different ways. First, control of the side chain of PFSA copolymers can effectively improve the proton conductivity and thermal stability by increasing the ion exchange capacity and polymer crystallinity. Second, the development of composite-type PFSA-PEMs is an effective way to improve proton conductivity and physical stability by incorporating organic/inorganic additives. Finally, the incorporation of porous substrates is also a promising way to develop a thin pore-filling membrane showing low membrane resistance and outstanding durability.

• International Journal of Automotive Technology
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• v.6 no.1
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• pp.1-8
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• 2005

Recently, the HSDI (High Speed Direct Injection) diesel engine has been spotlighted as a next generation engine because it has a good potential for high thermal efficiency and fuel economy. This study was carried out to investigate the in-cylinder flow characteristics generated in a HSDI diesel engine with a 4-valve type cylinder head. The four kinds of cylinder head were manufactured to elucidate the effect of intake port geometry on the in-cylinder flow characteristics. The steady flow characteristics such as coefficient of flow rate $(C_{f})$, swirl ratio (Rs), and mass flow rate (m,) were measured by the steady flow test rig and the unsteady flow velocity within a cylinder was measured by PIV. In addition, the in-cylinder flow patterns were visualized by the visualization experiment and these results were compared with simulation results calculated by the commercial CFD code. The steady flow test results indicated that the mass flow rate of the cylinder head with a short distance between the two intake ports is $13\%$ more than that of the other head. However, the non-dimensional swirl ratio is decreased by approximately $15\%$. As a result of in-cylinder flow characteristics obtained by PIV and CFD calculation, we found that the swirl center was eccentric from the cylinder center and the position of swirl center was changed with crank angle. As the piston moves to near the TDC, the swirl center corresponded to the cylinder center and the velocity distribution became uniform. In addition, the results of the calculation are in good agreement with the experimental results.

• Journal of the Korean Institute of Gas
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• v.15 no.6
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• pp.28-33
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• 2011

The purpose of this paper analyzes and studies to improve the failure cases on the computer that one of electronic control elements for engine in liquified petroleum gas vehicle. The first case, it certified the non-starting phenomenon of engine that it's electronic control unit didn't control the fuel for idle speed actuator because of no given action signal in slow-cut solenoid valve. The second case, it knew the bad condition phenomenon of engine and back-fire by the wire melting of ignition coil and firing of transistor being inside ECU. The third case, it certified the action stoping phenomenon of engine and malfunctioning signal for engine ECU because of leakage of current and an excess current by moisture inflowing inside ECU curcuit plate. Therefore, it is thought that will elevate the durability and reliability of engine computer throughout procure of quality.

• Journal of Energy Engineering
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• v.22 no.4
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• pp.338-346
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• 2013

The conventional lead acid battery is optimized for cranking performance of engine. Recently electric devices and fuel economy technologies of battery have influenced more deep cycle of dynamic behavior of battery. I also causes to reduce battery life-time. This study proposed that aging battery model is focused for increasing of battery durability. The stress factors of battery aging consist of discharge rate, charging time, full charging time and temperature. This paper considers the electrochemical kinetics, the ionic species conservation, and electrode porosity. For prediction of battery life cycle we consider battery model containing strong impacts, corrosion of positive grid and shedding. Finally, we validated that modeling results were compared with the accelerated thermal measurement data.

• Korean Journal of Computational Design and Engineering
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• v.21 no.4
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• pp.389-396
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• 2016

The necessity for environment-friendly material development has emerged in the recent automotive field due to stricter regulations on fuel economy and environmental concerns. Accordingly, the automotive industry is paying attention to carbon fiber reinforced plastic (CFRP) material with high strength and stiffness properties while the lightweight. In this study, we determine a shape of lower control arm (LCA) for maximizing the strength and stiffness by optimizing the thickness of each layer when the stacking angle is fixed due to the CFRP manufacturing problems. Composite materials are laminated in the order of $0^{\circ}$, $90^{\circ}$, $45^{\circ}$, and $-45^{\circ}$ with a symmetrical structure. For the approximate optimal design, we apply a sequential two-point diagonal quadratic approximate optimization (STDQAO) and use a process integrated design optimization (PIDO) code for this purpose. Based on the physical properties calculated within a predetermined range of laminate thickness, we perform the FEM analysis and verify whether it satisfies the load and stiffness conditions or not. These processes are repeated for successive improved objective function. Optimized CFRP LCA has the equivalent stiffness and strength with light weight structure when compared to conventional aluminum design.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.4
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• pp.26-31
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• 2006

An experimental investigation of an early injection strategy was conducted on a small single cylinder common-rail DI diesel engine to reduce the oxides of nitrogen($NO_x$) emission. The main objectives of this study were to investigate the emissions, performance and combustion characteristics in a diesel engine with early and two-stage injections. The two- stage injection was conducted to reduce the wall-wetting of early injected fuels on the cylinder wall or to promote the ignition of premixed charge. The engine test was performed at conditions of 1500rpm, injection timing ranging from TDC to BTDC $80^{\circ}$. The experimental results show that $NO_x$ emissions were decreased in both cases of early injection and two stage injection compared to the conventional diesel combustion by the near TDC injection. However, soot and products of incomplete products (i.e. HC and CO) are slightly increased. Also, the second injection near TDC promoted the ignition of premixed fuel, therefore, IMEP was increased.

• Transactions of the Korean Society of Automotive Engineers
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• v.19 no.4
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• pp.78-83
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• 2011

Natural gas is one of the most promising alternatives to gasoline and diesel fuels because of its high thermal efficiency and lower harmful emissions, including $CO_2$. Although the high octane value of natural gas increases engine output and efficiency due to the high compression ratio, this fuel is prone to such difficulties as a narrow limit of inflammability and a slow combustion speed in the lean burn operation domain, leading to unstable combustion and higher emissions of harmful exhaust gases. Hydrogen blended with natural gas can extend the lean burn limit while maintaining stable, efficient combustion and achieving lower NOx, hydrocarbon and green house gas emissions. In this study, the effect of hydrogen addition on an engine performance and NOx emission characteristics was investigated in a heavy duty natural gas engine. The results showed that thermal efficiency was increased and NOx emissions were reduced due to the expansion of lean operation range under stable operation. NOx emission can be significantly reduced with the retard of spark advance timing.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.3
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• pp.88-97
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• 2012

To measure the traffic pollutants with high temporal and spatial resolution under real conditions, a mobile emission laboratory (MEL) was designed. The equipment of the mini-van provides gas phase measurements of CO, NOx, CO2 and THC (Total hydrocarbon), and number density & size distribution measurements of fine and ultra-fine particles by a fast mobility particle sizer (FMPS) and a condensation particle counter (CPC). The inlet sampling port above the bumper enables the chasing of different type of vehicles. This paper introduces the technical details of the MEL and presents data from the experiment in which a MEL chases a city bus fuelled by diesel, DME and Bio-diesel. The dilution ratio was calculated by the ratio of ambient NOx and tail-pipe NOx. Most particles from the bus fuelled by diesel were counted under 300 nm and the peak concentration of the particles was located between 30 and 60 nm. However, most particles in the exhaust of the bus fuelled by DME were nano-particles (diameter: less than 50 nm). The bus fuelled by Bio-diesel shows less particle emissions compare to diesel bus due to the presence of the oxygen in the fuel.

• Transactions of the Korean Society of Automotive Engineers
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• v.18 no.5
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• pp.108-114
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• 2010

The injection nozzle of an electro-hydraulic injector is being opened and closed by movement of a injector's needle which is balanced by pressure at the nozzle seat and at the needle control chamber, at the opposite end of the needle. In this study, the effects of needle movement in a piezo-driven injector on unsteady cavitating flows behavior inside nozzle were investigated by cavitation numerical model based on the Eulerian-Lagrangian approach. Aimed at simulating the 3-D two-phase flow behavior, the three dimensional geometry model along the central cross-section regarding of one injection hole with real design data of a piezo-driven diesel injector has been used to simulate the cavitating flows for injection time by at fully transient simulation with cavitation model. The cavitation model incorporates many of the fundamental physical processes assumed to take place in cavitating flows. The simulations performed were both fully transient and 'pseudo' steady state, even if under steady state boundary conditions. As this research results, we found that it could analyze the effect the pressure drop to the sudden acceleration of fuel, which is due to the fastest response of needle, on the degree of cavitation existed in piezo-driven injector nozzle.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.5
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• pp.116-125
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• 2014

Pyrolysis oil (PO), derived from biomass through fast pyrolysis process have the potential to displace significant amounts of petroleum fuels. The PO derived from wood has been regarded as an alternative fuel to be used in diesel engines. However, the use of PO in a diesel engine is very limited due to its poor properties like low energy density, low cetane number, high acidity and high viscosity of PO. Therefore, one of the easiest way to adopt PO to diesel engine without modifications is blended with other fuels that have high centane number. However, PO that has high amount of polar chemicals is immiscible with non polar hydrocarbons of diesel or biodiesel. Thus, to stabilize a homogeneous phase of diesel/biodiesel-PO blends, a proper surfactant should be used. Nevertheless, PO which was produced from different biomass type have varied characteristics and this complicates the selection of a suitable additive for a specific PO-diesel emulsion. In this regard, a more simple approach such as the use of a co-solvent like ethanol or butanol to induce a more stable phase of the PO-diesel mixture could be a promising alternative. In this study, a diesel engine operated with diesel/biodiesel-PO-butanol blends was experimentally investigated. Performance and gaseous & particle emission characteristics of a diesel engine were examined under the engine loads of IMEP 0.2 ~ 0.8MPa.