• Proceedings of the Korean Society of Potoscience Conference
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• spring
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• pp.33-33
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• 1996

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.4
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• pp.497-508
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• 2020

In the geochemical field, the chemical speciation of hexavalent uranium (U(VI)) has been widely investigated by performing measurements to determine its luminescence properties, namely the excitation, emission, and lifetime. Of these properties, the excitation has been relatively overlooked in most time-resolved laser fluorescence spectroscopy (TRLFS) studies. In this study, TRLFS and continuous-wave excitation-emission matrix spectroscopy are adopted to characterize the excitation properties of U(VI) surface species that interact with amorphous silica. The luminescence spectra of U(VI) measured from a silica suspension and silica sediment showed very similar spectral shapes with similar lifetime values. In contrast, the excitation spectra of U(VI) measured from these samples were significantly different. The results show that distinctive excitation maxima appeared at approximately 220 and 280 nm for the silica suspension and silica sediment, respectively.

• Current Optics and Photonics
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• v.7 no.6
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• pp.761-765
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• 2023

We analyzed the absorption spectra of acetone in the 3.37 ㎛ mid-infrared range using the off-axis integrated cavity output spectroscopy technique to develop a real-time, in-line breath analysis device. The linear relationship between acetone concentration and absorption increase was confirmed as 0.32%/ppm, indicating that the developed device allows for a quantitative analysis of acetone concentration in exhaled breath. To further confirm the feasibility of using our device for breath analysis, we measured the acetone concentration of human breath samples at the sub-ppm level.

• Current Optics and Photonics
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• v.7 no.4
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• pp.457-462
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• 2023

Quantitative measurement of trace ethane is important in environmental science and biomedical applications. For these applications, we typically require a few tens of part-per-trillion level measurement sensitivity. To measure trace-level ethane, we constructed a cavity ring-down spectroscopy setup in the 3.37 ㎛ mid-infrared wavelength range, which is applicable to multi-species chemical analysis. We demonstrated that the detection limit of ethane is approximately 300 parts per trillion, and the measured concentration is in agreement with the amounts of the injected sample. We expect that these results can be applied to the chemical analysis of ethane and applications such as breath test equipment.

• Journal of Radiation Protection and Research
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• v.35 no.2
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• pp.77-80
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• 2010

The spectroscopy toolkit has been developed and tested. The toolkit consists of a CsI(Tl)/PIN diode detector, integrated electronics, and a multi.channel.analyzer and its size was 40 cm(width) by 20 cm(length) by 6 cm(high). It is compact, very portable and simpler and cheaper compared to the conventional spectroscopy system. The gamma energy resolutions of the toolkit were 7.9% for the 660 keV of $^{137}Cs$ and 4.9% for 1,332 keV of $^{60}Co$ respectively. The linearity for gamma energies was good. When the energy spectrum of a ceramic sample containing $^{232}Th$ was measured with the spectroscopy toolkit for 20 minutes, there were significant peaks of the heavy metal. These results show that the resolution of the spectroscopy toolkit is sufficient to accumulate a quality spectrum in a few minutes by using weak, encapsulated commercial sources. Furthermore a toolkit experiment that how to measure energy spectra using the toolkit, and how to identify specific isotopes in a pottery piece, could be widely adopted for education and even for more sophisticated and higher level experiments.

• Bulletin of the Korean Chemical Society
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• v.27 no.12
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• pp.2101-2103
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• 2006

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2018.11a
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• pp.452-453
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• 2018

• Analytical Science and Technology
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• v.22 no.2
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• pp.141-147
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• 2009

A laser induced breakdown spectroscopy (LIBS) measurement was carried out to derive an optimized measurement condition with a high reproducibility and to grow a plasma sphere to 20 mm high under a 600 mtorr vacuum in order to improve an accuracy of measurement. The measurement of the plasma was taken at a 6.0 mm distance, in the direction of a plasma sphere, from a sample. This location belongs to the outer sphere region in the plasma. The calibration curve of 'Ni' and 'Cu' was acquired by the signal intensity ratio and the atomic ratio for the samples, and linear regression of 'Cu' was $R^2$=0.9886, and the linear regression of 'Ni' was $R^2$=0.9988. The accuracy of LIBS was improved pre-existence as the measurement error of 'Ni' was 0.78%.

• Journal of the Optical Society of Korea
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• v.7 no.3
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• pp.174-179
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• 2003

We construct a four-level system where a metastable state is included in an $Er^{3＋}$ Doped Yttrium aluminum garnet (YAG) crystal. Because of the action of the coherent field, the traditional light amplification with inversion can be exhibited with remarkable variation. As a result, we propose a method to achieve the gain equalization by atomic coherence. At the same time, we find that the high index of refraction accompanied by vanishing absorption can also be reached in this model. We also find that a higher index of refraction with zero absorption can be easily obtained when the coherent field is off resonance.

• Nuclear Engineering and Technology
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• v.55 no.6
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• pp.2158-2165
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• 2023

Marine radioactivity monitoring is critical for taking immediate action in case of unexpected nuclear accidents at nuclear facilities located near coastal areas. Especially when the level of contamination is not predictable, mobile monitoring systems will be useful for wide-area ocean radiation survey and for determination of the level of radioactivity. Here, we used a silicon photomultiplier and a high-efficiency GAGG crystal to fabricate a compact, battery-powered gamma spectroscopy that can be used in an ocean environment. The developed spectroscopy has compact dimensions of 6.5 × 6.5× 8 cm³ and weighs 560 g. We used LoRa, a low-power wireless protocol for communication. Successful data transmission was achieved within 1.4 m water depth. The developed gamma spectroscopy was able to detect radioactivity from a ¹³⁷Cs point source (3.7 kBq) at a distance of 20 cm in water. Moreover, we demonstrated an unmanned radioactivity monitoring system in a real sea by combining unmanned surface vehicle with the developed gamma spectroscopy. A hidden ¹³⁷Cs source (3.07 MBq) was detected by the unmanned system at a distance of 3 m. After successfully testing the developed mobile spectroscopy in an ocean environment, we believe that our proposed system will be an effective solution for mobile real-time marine radioactivity monitoring.