• Title/Summary/Keyword: Atomic absorption analysis

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The Blood Cadmium and Lead Levels in Students

  • Lee, Mi-Hwa
    • Biomedical Science Letters
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    • v.12 no.4
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    • pp.371-374
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    • 2006
  • This study was carried out to investigate the relationship of the cadmium and lead levels in blood by age, gender and smoking status among 181 students in Gyeongnam province from June 2005 to July 2006. The cadmium and lead levels in blood was analyzed by atomic absorption spectrophotometer. Subjects were classified for the investigation according to smoking status as smokers and nonsmokers, age and gender. Mean blood cadmium level in male and female was $1.65{\mu}g/dl,\;1.10{\mu}g/dl$ respectively. Male was significantly higher than that of female. Blood cadmium levels in heavy smokers ($11{\sim}20\;ea/day$) and light smokers ($1{\sim}10\;ea/day$) were $2.34{\mu}g/dl,\;1.10{\mu}g/dl$ respectively. Heavy smokers were significantly higher than those of light smokers. In the comparison of age, gender and smoking status in blood Lead levels were no significant differences. In conclusion, heavy smoking was the most significant risk factor to increase blood cadmium levels. The further study will need analysis of the other factors related to the elevation of the cadmium and lead levels.

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Characteristics of Sewage sludge, Its Incineration Ash, and Sintering Pellet

  • Lee, Ki-Hwan;Lee, Tae-Ho;Cho, Heon-Young;Han, Ki-Suk
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.4
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    • pp.215-220
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    • 2000
  • This study on the incineration ash and sintering pellet from sewage sludge was carried out to evaluate the possibility of recycling in sewage sludge disposal. The samples used in this experiment were raw sewage sludge, its incineration ash, and sintering pellet. The characteristics of the three sample types were identified using X-ray diffraction(XRD), X-ray fluorescence(XRF), atomic absorption spectroscopy(AAS), and inductively coupled plasma spectroscopy(ICP). The chemical compositions of all three sample types were similar in their clay component, however, the sewage sludge had a high content of organic materials. From an analysis of the mineral content of the three sample types, the conversion of their compositions was found to be relative to temperature. Accordingly, incineration ash and sintering pellet both have potential for use as a functional construction material.

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Hydrogen Generation from Water Using CdS-ZnS Photocatalysts (CdS-ZnS 광촉매를 이용한 물의 광전기 분해에 의한 수소 발생)

  • Heo, Gwi Suk
    • Journal of Hydrogen and New Energy
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    • v.1 no.1
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    • pp.9-14
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    • 1989
  • Mixed photocatalyst containing cadmium sulfide and zinc sulfide was prepared on silica gel powder and Nafion film. Photo-irradiation of aqueous mixture containing the photocatalysis generated hydrogen by water cleavage reaction. Use of sodium sulfide as sacrificial reagent help the photo-reaction. Evolution of the hydrogen was measured by gas chromatographic analysis. Composition of the catalyst was determined by atomic absorption spectrophotometer. 0.2 mL of of hydrogen was generated per hour. The maximun catalytic activity was obtained after 8-12 hours later. Hydrogen generation efficiency by the two different catalytic system was compared and showed that the Nafion-based catalyst is more efficient than the silicagel-based catalyst for the photoreaction.

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Studies on the Synthesis of Aluminum Chloride Polymeric Catalysts and Its Catalytic Effect for the Esterification (염화알루미늄·고분자촉매의 합성과 에스테르화 반응촉매로서의 효과에 관한 연구)

  • Kyu Ja Whang;Yong Keun Lee
    • Journal of the Korean Chemical Society
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    • v.22 no.3
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    • pp.184-193
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    • 1978
  • Various aluminum chloride polymeric catalysts have been prepared by the reaction of anhydrous aluminum chloride with styrene-divinylbenzene copolymer bead in the carbon disulfide solvent. The shapes of aluminum chloride polymeric catalysts have been investigated by the use of optical microscope, scanning electron microscope and analysis of atomic absorption and electron microprobe X-ray. The catalytic effect of aluminurn chloride polymeric catalysts in the process of esterification of various organic acids with several aliphatic and aromatic alcohols have been studied.

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The Study on Concentration of Serum Copper and Zinc in Stomach Cancer Patients (위암 환자의 혈청내 구리 및 아연 농도에 관한 연구)

  • 정유덕
    • Journal of Nutrition and Health
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    • v.24 no.6
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    • pp.516-525
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    • 1991
  • In order to investigate whether serum Cu, Zn and Cu/Zn ratio are the useful indicater for the diagnosis of cancer. serum Cu and Zn levels were determined from 35 normal subjects and 33 stomach cancer patients by Atomic absorption spectrophotometer. The following results are obtained : Serum copper levels of stomach cancer patients were significantly increased than the those of the normal controls. whereas serum Zn levels significantly decreased than those of the normal contros(P<0.01) Therefore the copper to zinc ratio revealed a significant in the serum Cu and Zn levels. The serum protein and albumin levels were significantly lower in cancer patients(P<0.01) And the correlation analysis indicated that there was no significant correlation between serum Cu/Zn ratio and protein or albumin. These data suggest that the serum Cu. Zn and Cu/Zn ratio may be used as a diagnostic test in stomach cancer patients.

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Purification and Glycosylation Pattern of Human L-Ferritin in Pichia pastoris

  • Lee, Jong-Lim;Yang, Seung-Nam;Park, Cheon-Seok;Jeoung, Doo-Il;Kim, Hae-Yeong
    • Journal of Microbiology and Biotechnology
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    • v.14 no.1
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    • pp.68-73
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    • 2004
  • Ferritin is an iron storage protein found in most living organisms. For expression and industrial use, human light chain ferritin (L-ferritin) was cloned from human liver cDNA library and expressed in Pichia pastoris strain GS115. The recombinant L-ferritin in Pichia pastoris was glycosylated. In a fed-batch culture, the cell mass reached about 57 g/l of dry cell weight, and the L-ferritin in the cell was increased to about 95 mg/l after 150 h. In an atomic absorption spectrometry analysis, the intracellular content of iron in the L-ferritin transformant was measured as $1,694{\pm}85\;\mu\textrm{g}g/g$, which is 5.4-fold more than that of the control strain. This L-ferritin transformant could serve as iron-fortified nutrients in animal feed stock.

Studies on the Constituents of Polygonum sp. (호장(虎杖)의 성분(成分)에 관(關)한 연구(硏究))

  • Kim, Tae-Hee;Lee, Jong-Hee;Yang, Ki-Sook;Kim, Myung-Ja;Yoo, Yon-Hee
    • Korean Journal of Pharmacognosy
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    • v.9 no.2
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    • pp.89-91
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    • 1978
  • Free amino acids and mineral substance in radix of Polygonum cuspidatum, Polygonum elliptica, and Polygonum sachalinense were analyzed by amino acid autoanalyzer and atomic absorption spectrophotometer. Gross contents of free amino acids in root of P. cuspidatum and P. elliptica are 12.99mg/g and 9.58mg/g respectively. The analysis of inorganic constituents of Polygonum sp. showed that it generally contains copper, iron, manganese, zinc, potassium and potassium salt.

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Studies on Trace Metal Levels of Korean Scalp Hair (한국인 모발중의 미량금속 함량에 관한 연구)

  • Cho Yun-Syng;Kim Dae-Seon;Cho Jae-Hong
    • Journal of environmental and Sanitary engineering
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    • v.3 no.1 s.4
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    • pp.75-85
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    • 1988
  • An atomic absorption spectrophotometry analysis study of zinc, cadimium, lead, copper and mercury in human scalp hair samples of 699 subjects in 3 urban and 4 rural communities gave mean values of 170.33/187.00 ppm, 0.18/0.22 ppm, 8.43/8.62 ppm, 9.81/10.24 ppm and 2.13/1.20 ppm for male and female, respectively. The concentration did not differ significantly regardless ages. However, female was higher than male in overall concentration except that of mercury. The percentile methods was partially applied for a reference values of metals in Korean scalp hair to provide more appropriate data for further comparisons.

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Comparison of the chlorophyll content analysis methods of micro-algal oil (미세조류의 엽록소 분석법에 따른 함량 비교)

  • Choi, Byoungyun;Kim, Deogkeun
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.113.1-113.1
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    • 2011
  • 미세조류 내의 엽록소는 바이오디젤 전환 반응에서 산 촉매의 활성을 억제 할 뿐만 아니라, 짙은 색상을 띄게하여 바이오디젤 품질규격으로부터 벗어나게 한다. 미세조류의 엽록소 분석은 용매에 의해 엽록소를 추출한 후, 흡광도를 측정하여 그 함량을 계산하는 방법을 널리 사용하고 있다. 건조된 미세조류의 분석은 선택되는 용매에 따라 최대 추출량이 달라지는 것을 제외하고 큰 문제가 없지만 미세조류를 lipid 오일로 변환하면, 용매에 녹지 않아 추출이 되지않는 문제가 발생하여 흡광도 측정을 어렵게 한다. 따라서 미세조류의 형태가 powder일 때와 오일인 경우를 구분하여 용매를 선택해야 하며, 오일 또는 powder 형태 구분 없이 사용할 수 있는 분석법을 적용하여 서로 다른 엽록소 함량을 비교한 후 분석법 간의 상호 장단점을 파악해야한다. 본 연구에서는 메탄올을 용매로 사용하는 분석법(porra et al.)과 아세톤을 용매로 사용하는 분석법(Humphrey and Jeffrey)을 적용하여 엽록소 함량을 비교하였고, AAS(Atomic Absorption Spectrometer)를 통한 Mg 함량 측정을 통해 엽록소 함량을 계산하는 분석법간의 차이를 확인하였다.

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A Preliminary Study on the Chemical Compositions of Precipitation in the Rural Area of Kyunggi Province near Demilitarized Zone (비무장지대에 인접한 경기도 농촌지역 강수의 화학적 성분에 관한 기초 연구)

  • 박국태;김창호
    • Journal of Environmental Science International
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    • v.7 no.2
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    • pp.157-164
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    • 1998
  • preliminary study on the chemical compositions of forty seven precipitations from March 1994 to May 1995 In Yeoncheon-gun, which Is adjacent to the southern boundary of demilitarized zone (DMZ) in the northernmost tip of Kyunggi Province has been Performed. The metal cation and anion concentrations were measured by atomic absorption spectrometer and ion chromatography, respectively. pH/lon meter and direct nesslerization method were used for the concentration measurements of $H^+$ ion and $NH_46+$ ions, respectively Based on the data, the quantitative orders of the cation and anion average concentrations were $Ca^{2+}>NH_4^+>Na^+>K^+>Mg^{2+}>H^+ and SO_4^{2+}>Cl^-> NO_3^-$, respectively..The ratio of average total anion concentration to average total cation concentration was 0.97. The average pH value of the precipitations was 5.60. These results, correlation coefficients between the ion concentrations, and monthly variations of pH value and precipitation amount are used for chemical analysis on the environmental Pollution and Pollutant sources In Yeoncheon-gun of Kyunggi province near DMZ.

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