• Title/Summary/Keyword: Atomic Contribution Method

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A Direct Kinetic Study of Cl Atom Reactions (염소원자의 반응속도 연구)

  • Kwang Yul Choo
    • Journal of the Korean Chemical Society
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    • v.23 no.6
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    • pp.349-357
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    • 1979
  • A non-Boltzman equilibrium population of $Cl(^2P_{1/2})$ atoms has been observed in a flow discharge-atomic absorpion experiment. The rates of reactions of $Cl(^2P_{3/2})$ atoms with various substrates are in reasonable agreement with reported values determined by competition methods. The similar reactivities of both $Cl(^2P_{1/2})$ and $Cl(^2P_{3/2})$ atoms indicate that the contribution of $Cl(^2P_{1/2})$ atoms to the rate measurements in the competition experiment is small, and this negligible contribution may be the reason why the rate constants obtained by assuming single reactive species (in competition method) agree well with our direct measurement.

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Added Mass Estimation of Square Sections Coupled with a Liquid Using Finite Element Method

  • Jeong, Kyeong Hoon;Jhung, Myung Jo
    • Nuclear Engineering and Technology
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    • v.49 no.1
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    • pp.234-244
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    • 2017
  • Natural frequencies of immersed square sections decrease due to a contribution of added mass to the movement of square sections. In this study, natural frequencies of square sections are obtained as a function of gap size between the square section and a rigid square wall using the finite element method. Additionally, they are used to extract the added mass effect on translational and rotation motions. Published information and studies on the translational and torsional vibration of square beams are also examined for practical use. D coupling of a square section is also investigated for multiple square sections. The suggested added mass estimation can be applicable to the spent fuel storage design of a pressurized light water modulated nuclear power plant.

Parametric Study for Structural Reinforcement Methods of Disposal Container for NPP Decommissioning Radioactive Waste

  • Hyungoo Kang;Hoseog Dho;Jongmin Lim;Yeseul Cho;Chunhyung Cho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.3
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    • pp.329-345
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    • 2023
  • This paper described a method for analyzing the structural performance of a metal container used for disposing radioactive waste generated during the decommissioning of a nuclear power plant, and numerical analysis results of a method for reinforcing the container. The containers to be analyzed were those that can be used in near-surface and landfill disposal facilities scheduled to be operated at the Gyeongju radioactive waste disposal facility. Structural reinforcement of the container was performed by lattice reinforcement, column reinforcement, and bottom plate reinforcement. Accordingly, a total of 14 reinforcement cases were modeled. The external force causing damage to the container was set equivalent to the impact of a 9-m fall, accounting for the height of the vault at the near-surface disposal facility. The reinforcement methods with a high contribution to the structural performance of the container were concluded to be lattice and column reinforcements.

A Study on Development of a PIN Semiconductor Detector for Measuring Individual Dose (개인 선량 측정용 PIN 반도체 검출기 개발에 관한 연구)

  • Lee, B.J.;Lee, W.N.;Khang, B.O.;Chang, S.Y.;Rho, S.R.;Chae, H.S.
    • Journal of Radiation Protection and Research
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    • v.28 no.2
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    • pp.87-95
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    • 2003
  • The fabrication process and the structure of PIN semiconductor detectors have been designed optimally by simulation for doping concentration and width of p+ layer, impurities re-contribution due to annealing and the current distribution due to guard ring at the sliced edges. The characteristics to radiation response has been also simulated in terms of Monte Carlo Method. The device has been fabricated on n type, $400\;{\Omega}cm$, orientation <100>, Floating-Zone silicon wafer using the simulation results. The leakage current density of $0.7nA/cm^2/100{\mu}m$ is achieved by this process. The good linearity of radiation response to Cs-137 was kept within the exposure ranges between 5 mR/h and 25 R/h. This proposed process could be applied for fabricating a PIN semiconductor detector for measuring individual dose.

The Sliding Mode Control with a Time Delay Estimation (SMCTE) for an SMA Actuator

  • Lee, Hyo-Jik;Yoon, Ji-Sup;Lee, Jung-Ju
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.5-10
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    • 2005
  • We deal with the sliding mode control using the time delay estimation. The time delay estimation is able to weaken the need for obtaining a quantitative plant model analogous to the real plant so the sliding mode control with a time delay estimation (SMCTE) is very suitable for plant such as SMA actuators whose quantitative model is difficult to obtain. We have already studied the application of the time delay control (TDC) to SMA actuators in other literature. Based on the previous study on the TDC, we developed the gain tuning method for the SMCTE, which results were nearly the same as the TDC. With respect to the step response, the SMCTE proved its predominance in a comparison with other control schemes such as the PID control and the relay control. As well as the contribution of the above control methodology, the model identification for SMA actuators has also been studied. The dynamics for an SMA actuator was newly derived using the modified Liang's model. The derived dynamics showed a continuity at the change of the phase transformation process but the original Liang's model could not.

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Effect of Exchangeable Cation on Radionuclide Diffusion In Compacted Bentonite

  • Park, Jong-Won;Park, Hyun-Soo;Dennis W. Oscarson
    • Nuclear Engineering and Technology
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    • v.28 no.3
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    • pp.274-279
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    • 1996
  • Diffusion coefficient is a critical parameter for predicting radiological source term(migration rate and flux of radionuclide) through given near field conditions in spent fuel or high level waste repository. The effect of exchangeable cation-$Na^+$ and $Ca^{2+} - on the diffusion of $I^- \;and^3H$ (as HTO) in compacted bentonite was examined using a through-diffusion method. Bentonite material used here was compacted to a density of 1.3 Mg/m$^3$, and Na-bentonite was saturated with a solution of 100 mol NaCl/m$^3$ and Ca-bentonite with 50 $mol\;CaCl_2$/m$^3$. The results show that effective diffusion coefficients are generally higher by a factor of two to five in Ca-than Na-clay. This is attributed to the larger particle size of Ca-compared to Na-bentonite; hence, Ca-bentonite has a greater proportion of relatively large pores, which make a greater contribution to mass transport than small pores. Although the nature of the exchangeable cation affects mass diffusion in compacted bentonite, the effect is small and not likely to influence performance assessment modeling of compacted bentonite-based barriers.

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INTERNATIONAL STANDARD PROBLEM 50: THE UNIVERSITY OF PISA CONTRIBUTION

  • Cherubini, Marco;Lazzerini, Davide;Giannotti, Walter;D'auria, Francesco
    • Nuclear Engineering and Technology
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    • v.44 no.6
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    • pp.587-596
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    • 2012
  • The present paper deals with the participation of the University of Pisa in the last International Standard Problem (ISP) focused on system thermal hydraulic, which was led by the Korean Atomic Energy Research Institution (KAERI). The selected test was a Direct Vessel Injection (DVI) line break carried out at the ATLAS facility. University of Pisa participated, together with other eighteen institutions, in both blind and open phase of the analytical exercise pursuing its methodology for developing and qualifying a nodalization. Qualitative and quantitative analysis of the code results have been performed for both ISP-50 phases, the latter adopting the Fast Fourier Transfer Based Method (FFTBM). The experiment has been characterized by three-dimensional behavior in downcomer and core region. Even though an attempt to reproduce these phenomena, by developing a fictitious three-dimensional nodalization has been realized, the obtained results were generally acceptable but not fully satisfactory in replicating 3D behavior.

Quantification of Arsenic Species in Some Seafood by HPLC-AFS (HPLC-AFS를 이용한 해산물 중 비소 화학종 분리정량)

  • Jeong, Seung-Woo;Lee, Chae-Hyeok;Lee, Jong-Wha;Jang, Bong-Ki
    • Journal of Environmental Health Sciences
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    • v.47 no.5
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    • pp.496-503
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    • 2021
  • Background: Considering the expenses of and difficulties in arsenic speciation by high performance liquid chromatography-inductively coupled plasma-mass spectrometry (HPLC-ICP-MS), alternative measurement methods should be useful, especially for large-scale research and projects. Objectives: A measurement method was developed for arsenic speciation using HPLC-atomic fluorescence spectrometry (HPLC-AFS) as an alternative to HPLC-ICP-MS. Methods: Total arsenic and toxic arsenic species in some seafoods were determined by atomic absorption spectrometry coupled with hydride vapor generation (AAS-HVG) and HPLC-AFS, respectively. Recovery rate of arsenic species in seafood was evaluated by ultra sonication, microwave and enzyme (pepsin) for the optimal extraction method. Results: Limits of detection of HPLC-AFS for As3+, dimethylarsinate (DMA), monomethylarsonate (MMA) and As5+ were 0.39, 0.53, 0.60 and 0.64 ㎍/L, respectively. The average accuracy ranged from 97.5 to 108.7%, and the coefficient of variation was in the range of 1.2~16.7%. As3+, DMA, MMA and As5+ were detected in kelp, the sum of toxic arsenic in kelp was 40.4 mg/kg. As3+, DMA, MMA and As5+ were not detected in shrimp and squid, but total arsenic (iAS and oAS) content in shrimp and squid analyzed by AAS-HVG were 18.1 and 24.7 mg/kg, respectively. Conclusions: HPLC-AFS was recommendable for the quantitative analysis method of arsenic species. As toxic arsenic species are detected in seaweeds, further researches are needed for the contribution degree of seafood in arsenic exposure.

Pin Power Distribution Determined by Analyzing the Rotational Gamma Scanning Data of HANARO Fuel Bundle

  • Lee, Jae-Yun;Park, Hee-Dong
    • Nuclear Engineering and Technology
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    • v.30 no.5
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    • pp.452-461
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    • 1998
  • The pin power distribution is determined by analyzing the rotational gamma scanning data for 36 element fuel bundle of HANARO. A fission monitor of Nb$^{95}$ is chosen by considering the criteria of the half-life, fission yield, emitting ${\gamma}$-ray energy and probability. The ${\gamma}$-ray spectra were measured in Korea Atomic Energy Research Institute(KAERI) by using a HPGe detector and by rotating the fuel bundle at steps of 10$^{\circ}$. The counting rates of Nb$^{95}$ 766 keV ${\gamma}$-rays are determined by analyzing the full absorption peak in the spectra. A 36$\times$36 response matrix is obtained from calculating the contribution of each rod at every scanning angle by assuming 2-dimensional and parallel beam approximations for the measuring geometry. In terms of the measured counting rates and the calculated response matrix, an inverse problem is set up for the unknown distribution of activity concentrations of pins. To select a suitable solving method, the performances of three direct methods and the iterative least-square method are tested by solving simulation examples. The final solution is obtained by using the iterative least-square method that shows a good stability. The influences of detection error, step size of rotation and the collimator width are discussed on the accuracy of the numerical solution. Hence an improvement in the accuracy of the solution is proposed by reducing the collimator width of the scanning arrangement.

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A Study for Rule Integration in Vulnerability Assessment and Intrusion Detection using Meaning Based Vulnerability Identification Method (의미기반 취약점 식별자 부여 기법을 사용한 취약점 점검 및 공격 탐지 규칙 통합 방법 연구)

  • Kim, Hyung-Jong;Jung, Tae-In
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.18 no.3
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    • pp.121-129
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    • 2008
  • This paper presents vulnerability identification method based on meaning which is making use of the concept of atomic vulnerability. Also, we are making use of decomposition and specialization processes which were used in DEVS/SES to get identifiers. This vulnerability representation method is useful for managing and removing vulnerability in organized way. It is helpful to make a relation between vulnerability assessing and intrusion detection rules in lower level. The relation enables security manager to response more quickly and conveniently. Especially, this paper shows a mapping between Nessus plugins and Snort rules using meaning based vulnerability identification method and lists usages based on three goals that security officer keeps in mind about vulnerability. The contribution of this work is in suggestion of meaning based vulnerability identification method and showing the cases of its usage for the rule integration of vulnerability assessment and intrusion detection.