• Title/Summary/Keyword: Atomic Contribution Method

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Prediction of the Net Heats of Combustion of Organic Halogenated Compounds based on the Atomic Contribution Method (원자기여법에 근거한 유기 할로겐 화합물의 순연소열 예측)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Fire Science and Engineering
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    • v.17 no.4
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    • pp.7-12
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    • 2003
  • The heat of combustion is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. Empirical equations have been developed to pre-dict the net heats of combustion of organic halogenated compounds based on the atomic contribution method. The method developed in this study was compared with Cardozo's method and Hanley's method. As can be seen from the average absolute deviation(A.A.D.), the proposed equation was found to be best. The proposed equation may serve as an estimation scheme for the heats of combustion of the other organic halogenated compounds.

Analysis of Radiation-Induced Cancer Mortality for Korean Using the BEIR V Method

  • Hwang, Won-Tae;Han, Moon-Hee;Kim, Eun-Han;Suh, Kyung-Suk;Gyuseong Cho
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11b
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    • pp.629-635
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    • 1996
  • The lifetime radiation-induced cancer mortality for Korean has been estimated for both single and continuous radiation exposure using the BEIR V method. In case of single exposure, a dominant cancer site for young and old ages was digestive and respiratory cancer, respectively. For Korean population, digestive cancer was the most dominant radiation-induced cancer site. In case of 1 mGy/yr continuous exposure from birth to death, the contribution of total radiation-induced cancer mortality was negligible as within 3% in comparison with total natural cancer mortality.

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Correlations between Zirconium Isotopes and Burnup Parameters in PWR Spent Nuclear Fuels

  • Kim, Jung-Suk;Chun, Young-Shin;Lee, Chang heon;Kim, Won-Ho;Eom, Tae-Yun
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.551-556
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    • 1998
  • The correlation of isotope composition of Zr with the turnup and some heavy isotopes in PWR uranium dioxide fuel has been investigated. The total and partial ($^{235}$ U) burnup were determined by $^{148Nd}$ and by U and Pu mass spectrometric method, respectively. After separating Zr from the fuel samples, its isotope composition was measured by mass spectrometry. In addition, the quantities of the U and Pu in the spent fuel were determined by isotope di lution mass spectrometric method using $^{233}$ U and $^{242}$ Pu as spikes. The content of some heavy isotopes, $^{235}$ U, $^{239}$ Pu and $^{241}$ Pu, and the Pu Contribution to total turnup were expressed by the correlation with Zr isotope ratios, $^{91}$ Zr/$^{96}$ Zr and $^{93}$ Zr/$^{96}$ Zr The correlations by isotope compositions measured were compared wi th those calculated from ORIGEN2 code.

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A short study of uncertainty for post column isotope dilution method in HPLC-ICP/MS (HPLC-ICP/MS에서 후 컬럼 동위원소 희석법의 기초적인 불확도 연구)

  • Joo, Mingyu;Pak, Yong-Nam
    • Analytical Science and Technology
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    • v.27 no.6
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    • pp.269-276
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    • 2014
  • A short study for the uncertainty of post column isotope dilution method has been performed for the analysis of Selenomethionine in HPLC-ICP/MS. Major error sources studied were concentration and the flow rate of Se isotope solution, atomic weights of Se in spike and sample, and isotope ratio measured for the spiked sample. Uncertainties were obtained for each factor and the contribution for the total concentration uncertainty was 54.4% and 0.61%, 0.0072% and 0.018%, and 45.0%, respectively. The biggest contribution factor was concentration of the spike solution and the second was the isotopic ratio measured for the spiked sample solution. The mass flow rate of spike and atomic weights did not show much contribution. The calculated total uncertainty was $1.46ng{\cdot}g^{-1}$ for the standard SeMet ($126.30ng{\cdot}g^{-1}$). The experimental result was $127.09{\pm}1.46ng{\cdot}g^{-1}$ and the relative uncertainty was 1.20%.

Interfacing between MAAP and MACCS to perform radiological consequence analysis

  • Kim, Sung-yeop;Lee, Keo-hyoung;Park, Soo-Yong;Han, Seok-Jung;Ahn, Kwang-Il;Hwang, Seok-Won
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1516-1525
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    • 2022
  • Interfacing the output of severe accident analysis with the input of radiological consequence analysis is an important and mandatory procedure at the beginning of Level 3 PSA. Such interfacing between the severe accident analysis code MELCOR and MACCS, one of the most commonly used consequence analysis codes, is relatively tractable since they share the same chemical groups, and the related interfacing software, MelMACCS, has already been developed. However, the linking between MAAP, another frequently used code for severe accident analyses, and MACCS has difficulties because MAAP employs a different chemical grouping method than MACCS historically did. More specifically, MAAP groups by chemical compound, while MACCS groups by chemical element. An appropriate interfacing method between MAAP and MACCS has therefore long been requested by users. This study suggests a way of extracting relevant information from MAAP results and providing proper source term information to MACCS by an appropriate treatment. Various parameters are covered in terms of magnitude and manner of release in this study, and special treatment is made for a bypass scenario. It is expected that the suggested approach will provide an important contribution as a guide to interface MAAP and MACCS when performing radiological consequence analyses.

A study on automation of AV(Atomic Vulnerability) ID assignment (단위 취약점 식별자 부여 자동화에 대한 연구)

  • Kim, Hyung-Jong
    • Journal of Internet Computing and Services
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    • v.9 no.6
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    • pp.49-62
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    • 2008
  • AV (Atomic Vulnerability) is a conceptual definition representing a vulnerability in a systematic way, AVs are defined with respect to its type, location, and result. It is important information for meaning based vulnerability analysis method. Therefore the existing vulnerability can be expressed using multiple AVs, CVE (common vulnerability exposures) which is the most well-known vulnerability information describes the vulnerability exploiting mechanism using natural language. Therefore, for the AV-based analysis, it is necessary to search specific keyword from CVE's description and classify it using keyword and determination method. This paper introduces software design and implementation result, which can be used for atomic vulnerability analysis. The contribution of this work is in design and implementation of software which converts informal vulnerability description into formal AV based vulnerability definition.

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Prediction of Fatal Radiation-Induced Cancer for Korean Using the BEIR V Method (BEIR V 방법을 이용한 한국인의 방사선에 의한 암사망 예측)

  • Hwang, Won-Tae;Han, Moon-Hee;Cho, Gyu-Seong
    • Journal of Radiation Protection and Research
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    • v.21 no.3
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    • pp.175-182
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    • 1996
  • The lifetime fatal radiation-induced cancer for Korean has been estimated for both single and continuous radiation exposure using the BEIR V method. In case of single exposure, the major radiation-induced cancer type for young and old age is digestive and respiratory cancer, respectively. For the whole population of Korean, the major radiation-induced cancer type is digestive cancer. In case of 1mGy/yr continuous exposure from birth to death, the contribution of total radiation-induced cancer mortality to natural cancer mortality is about 3%.

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Calibration-free real-time organic film thickness monitoring technique by reflected X-Ray fluorescence and compton scattering measurement

  • Park, Junghwan;Choi, Yong Suk;Kim, Junhyuck;Lee, Jeongmook;Kim, Tae Jun;Youn, Young-Sang;Lim, Sang Ho;Kim, Jong-Yun
    • Nuclear Engineering and Technology
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    • v.53 no.4
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    • pp.1297-1303
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    • 2021
  • Most thickness measurement techniques using X-ray radiation are unsuitable in field processes involving fast-moving organic films. Herein, we propose a Compton scattering X-ray radiation method, which probes the light elements in organic materials, and a new simple, non-destructive, and non-contact calibration-free real-time film thickness measurement technique by setting up a bench-top X-ray thickness measurement system simulating a field process dealing with thin flexible organic films. The use of X-ray fluorescence and Compton scattering X-ray radiation reflectance signals from films in close contact with a roller produced accurate thickness measurements. In a high-thickness range, the contribution of X-ray fluorescence is negligible, whereas that of Compton scattering is negligible in a low-thickness range. X-ray fluorescence and Compton scattering show good correlations with the organic film thickness (R2 = 0.997 and 0.999 for X-ray fluorescence and Compton scattering, respectively, in the thickness range 0-0.5 mm). Although the sensitivity of X-ray fluorescence is approximately 4.6 times higher than that of Compton scattering, Compton scattering signals are useful for thick films (e.g., thicker than ca. 1-5 mm under our present experiment conditions). Thus, successful calibration-free thickness monitoring is possible for fast-moving films, as demonstrated in our experiments.

Further Applications of Molecular Orbital Calculations for Solid HF According to Pseudolattic Method

  • Kim, Jin-Seog;No, Kyoung-Tai;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.5 no.2
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    • pp.61-64
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    • 1984
  • The molecular orbital calculations for solid HF are performed by using the pseudolattice method considering the coulomb lattice sum. In order to obtain the reliable net atomic charges and lattice energy of one dimensional chains, the limited counting of interactions terms up to second neighbours for zig-zag chain and third neighbours for linear chain are sufficient in this calculation. In three dimensional solid HF, the contribution of interaction energy between non-hydrogen bonded neighbours to lattice energy is about 3.5% and the lattice energy of nonpolar structure is stablized by 2.05 kcal/mole compared with that of polar structure. And, this method is further tested and compared with the other methods.