• Title/Summary/Keyword: Atmospheric Plasma

Search Result 600, Processing Time 0.043 seconds

Electrical property improvement of ZnO:Al transparent conducting oxide thin film as surface treatment of polymer substrate (폴리머 기판의 표면개질을 통한 ZnO:Al 투명전도막의 전기적 특성 개선)

  • Paeng, Sung-Hwan;Jung, Ki-Young;Park, Byung-Wook;Kwak, Dong-Joo
    • Proceedings of the KIEE Conference
    • /
    • 2008.07a
    • /
    • pp.1352-1353
    • /
    • 2008
  • In this study, aluminium - doped zinc oxide (ZnO:Al) transparent conducting film was deposited on PET(polyethylen terephthalate) substrate by r.f. magnetron sputtering method. PET substrate was surface-treated in an atmospheric pressure DBD(dielectric barrier discharge) plasma to increase deposition rate and to improve electrical propesties. Morphological changes by DBD plasma were obsered using contact angle measurement. The contact angle of water on PET was reduced from 62$^{\circ}$ to 42$^{\circ}$ by DBD plasma surface treatment. The plasma treatment also increased deposition rate and electrical propesties. The electrical resistivity as low as $4.97{\times}10^{-3}[{\Omega}-cm]$ and the deposition rate of 234[${\AA}$-m/min] were obtained in ZnO:Al film with surface treatment time of 5min, and 20min., respectively.

  • PDF

Separation of VOCs from Air through Composite Membranes Prepared by Plasma Polymerization of Hexamethyldisiioxane (Hexamethyldisiioxane의 플라즈마 중합에 의하여 제조된 복합막을 통한 공기중의 휘발성 유기물질의 분리에 관한 연구)

  • 류동현;오세중;손우익;구자경
    • Proceedings of the Membrane Society of Korea Conference
    • /
    • 1998.10a
    • /
    • pp.63-65
    • /
    • 1998
  • 1. Introduction : Atmospheric discharge of VOC-contaminated streams in chemical plants and air streams from chemical processes poses a serious environmental problem and entails large financial losses. Such emissions may be reduced by i) adsorption process, ii) absorption process and iii) incineration process. These processes only forbids the air pollutions. Throughout the recent decade, another technique-membrane process has emerged. The separation and recovery of organic vapors by membrane process may have great economic potential. Most of the published research works on the separation of organic vapors from air were performed using silicon rubber membranes. However, it is very difficult to fabricate very thin membranes with less than 1 $u m thickness. Plasma polymerization could be a good technique to generate a thin polymer film. The objective of this work is to find out the optimum condition of plasma polymerization for producing VOC separation membrane. For the objective, composite membranes are prepared through plasma polymerization of hexamethyldisiloxane onto porous substrates under different conditions. The membrane is then subjected to the permeation of permanent gases and VOCs to find the correlations between the physical properties of the penetrant and permeability and selectivity.

  • PDF

Unexpected Chemical and Thermal Stability of Surface Oxynitride of Anatase TiO2 Nanocrystals Prepared in the Afterglow of N2 Plasma

  • Jeon, Byungwook;Kim, Ansoon;Kim, Yu Kwon
    • Applied Science and Convergence Technology
    • /
    • v.26 no.4
    • /
    • pp.62-65
    • /
    • 2017
  • Passivation of surface defects by the formation of chemically inert structure at the surface of $TiO_2$ nanocrystals can be potentially useful in enhancing their photocatalytic activity. In this regard, we have studied the surface chemical states of $TiO_2$ surfaces prepared by a treatment in the afterglow of $N_2$ microwave plasma using X-ray photoemission spectroscopy (XPS). We find that nitrogen is incorporated into the surface after the treatment up to a few atomic percent. Interestingly, the surface oxynitride layer is found to be chemically stable when it's in contact with water at room temperature (RT). The surface nitrogen species were also found to be thermally stable upon annealing up to $150^{\circ}C$ in the atmospheric pressure. Thus, we conclude that the treatment of oxide materials such as $TiO_2$ in the afterglow of $N_2$ plasma can be effective way to passivate the surface with nitrogen species.

Optical Diagnostics of Nanopowder Processed in Liquid Plasmas

  • Bratescu, M.A.;Saito, N.;Takai, O.
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.02a
    • /
    • pp.17-18
    • /
    • 2011
  • Plasma in liquid phase has attracted great attention in the last few years by the wide domain of applications in material processing, decomposition of organic and inorganic chemical compounds and sterilization of water. The plasma in liquid is characterized by three main regions which interact each - other during the plasma operation: the liquid phase, which supply the plasma gas phase with various chemical compounds and ions, the plasma in the gas phase at atmospheric pressure and the interface between these two regions. The most complex region, but extremely interesting from the fundamental, chemical and physical processes which occur here, is the boundary between the liquid phase and the plasma gas phase. In our laboratory, plasma in liquid which behaves as a glow discharge type, is generated by using a bipolar pulsed power supply, with variable pulse width, in the range of 0.5~10 ${\mu}s$ and 10 to 30 kHz repetition rate. Plasma in water and other different solutions was characterized by electrical and optical measurements. Strong emissions of OH and H radicals dominate the optical spectra. Generally water with 500 ${\mu}S/cm$ conductivity has a breakdown voltage around 2 kV, depending on the pulse width and the repetition rate of the power supply. The characteristics of the plasma initiated in ultrapure water between pairs of different materials used for electrodes (W and Ta) were investigated by the time-resolved optical emission and the broad-band absorption spectroscopy. The deexcitation processes of the reactive species formed in the water plasma depend on the electrode material, but have been independent on the polarity of the applied voltage pulses. Recently, Coherent anti-Stokes Raman Spectroscopy method was employed to investigate the chemistry in the liquid phase and at the interface between the gas and the liquid phases of the solution plasma system. The use of the solution plasma allows rapid fabrication of the metal nanoparticles without being necessary the addition of different reducing agents, because plasma in the liquid phase provides a reaction field with a highly excited energy radicals. We successfully synthesized gold nanoparticles using a glow discharge in aqueous solution. Nanoparticles with an average size of less than 10 nm were obtained using chlorauric acid solutions as the metal source. Carbon/Pt hybrid nanostructures have been obtained by treating carbon balls, synthesized in a CVD chamber, with hexachloro- platinum acid in a solution plasma system. The solution plasma was successfully used to remove the template remained after the mesoporous silica synthesis. Surface functionalization of the carbon structures and the silica surface with different chemical groups and nanoparticles, was also performed by processing these materials in the liquid plasma.

  • PDF

A Study of LCD Panel Cleaning Effect of Plasma Generation Power Source (플라즈마 발생용 전원장치의 LCD 패널 세정효과에 관한 연구)

  • Kim, Gyu-Sik
    • Journal of the Institute of Electronics Engineers of Korea SC
    • /
    • v.45 no.5
    • /
    • pp.44-51
    • /
    • 2008
  • UV lamp systems have been used for cleaning of display panels of TFT LCD or Plasma Display Panel (PDP). However, the needs for high efficient cleaning and low cost made high voltage plasma cleaning techniques to be developed and to be improved. Dielectric-Barrier Discharges (DBDs), also referred to as barrier discharges or silent discharges have been exclusively related to ozone generation for a long time. In this paper, a 6kW high voltage plasma power supply system was developed for LCD cleaning. The 3-phase input voltage is rectified and then inverter system is used to make a high frequency pulse train, which is rectified after passing through a high-power transformer. Finally, hi-directional high voltage pulse switching circuits are used to generate the high voltage plasma. Some experimental results showed the usefulness of atmospheric plasma for LCD panel cleaning.

Research on Flow Analysis Program Development Considering Equilibrium Plasma Flow and Impulse Characterization of Sparkjet Actuator (플라즈마에 의한 평형 유동을 고려한 스파크제트 액츄에이터 유동 해석 프로그램 개발과 추력 특성 연구)

  • Kim, Hyung-Jin;Shin, Jin Young;Chae, Jeongheon;Ahn, Sangjun;Kim, Kyu Hong
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.47 no.2
    • /
    • pp.90-97
    • /
    • 2019
  • Sparkjet actuator, also known as plasma synthetic jet actuator (PSJA), is an active flow control device that has possibility of controling supersonic flow. This actuator utilizes arc plasma to deposit energy onto the gas inside the cavity to raise temperature and pressure. A change in the state of the fluid inside the cavity generates pressure waves and momentum jet, and they are exhausted through out the orifice exit and disturb external flow field. Since the cavity flow is affected by arc plasma, which is an equilibrium plasma and have generated equilibrium flow, the equilibrium state of air should be considered in order to analyze the flow of sparkjet actuator. In this study, numerical program for equilibrium flow was developed for the use of sparkjet actuator analysis. The developed program was validated by comparing the time - accurate jet front positions with the reference result. Then, impulse characteristics of the actuator in the atmospheric quiescent air were explained.

Evaluation of Nonthermal Plasma Treatment by Measurement of Stored Citrus Properties

  • Seo, Youngwook;Park, Jong-Ryul;Park, Hoe Man
    • Journal of Biosystems Engineering
    • /
    • v.43 no.4
    • /
    • pp.401-409
    • /
    • 2018
  • Decay of fruit is one of the greatest issues in fruit storage. Purpose: In this study, citrus sterilization was performed to evaluate a dry sterilization method using an atmospheric-pressure nonthermal plasma treatment based on a dielectric-barrier discharge technique. Methods: Citrus samples were stored under four different environmental conditions as follows: group A had cold storage with plasma treatment with a temperature of $6.2{\pm}1.0^{\circ}C$ and relative humidity (RH) of $93.4{\pm}8.2%$, group B had ambient-temperature storage with $22.9{\pm}2.3^{\circ}C$ and $82.1{\pm}4.5%$ RH, group C ambient-temperature storage with plasma treatment with $25.3{\pm}2.2^{\circ}C$ and $90.0{\pm}2.8%$ RH, and group D had cold storage with $5.7{\pm}1.0^{\circ}C$ and $93.4{\pm}6.5%$ RH. Results: As a result of citrus surface sterilization by plasma treatment, treatment groups A and C together showed an average of 16.1 CFU/mL of mold colonies, while control groups B and D showed an average of $2.2{\times}10^2CFU/mL$ or approximately 13 times greater than the treatment groups. Regarding the mean concentration of aerobic bacteria colonies, the treatment groups (A and C) and control groups (B and D) showed an average of 7.1 CFU/mL and $1.9{\times}10^3CFU/mL$, respectively. This is approximately a 270-fold difference in the concentration of pathogen colonies between treatment and control groups. Conclusions: The results showed the potential of nonthermal plasma treatment for citrus storage in enhancing storage duration and quality preservation.

Application of a non-equilibrium ionization model to rapidly heated solar plasmas

  • Lee, Jin-Yi;Raymond, John C.;Reeves, Katharine K.;Shen, Chengcai;Moon, Yong-Jae;Kim, Yeon-Han
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.44 no.1
    • /
    • pp.53.1-53.1
    • /
    • 2019
  • We apply a non-equilibrium ionization (NEI) model to a supra-arcade plasma sheet, shocked plasma, and current sheet. The model assumes that the plasma is initially in ionization equilibrium at low temperature, and it is heated rapidly by a shock or magnetic reconnection. The model presents the temperature and characteristic timescale responses of the Atmospheric Imaging Assembly (AIA) on board Solar Dynamic Observatory and X-ray Telescope (XRT) on board Hinode. We compare the model ratios of the responses between different passbands with the observed ratios of a supra-arcade plasma sheet on 2012 January 27. We find that most of observations are able to be described by using a combination of temperatures in equilibrium and the plasma closer to the arcade may be close to equilibrium ionization. We also utilize the set of responses to estimate the temperature and density for shocked plasma associated with a coronal mass ejection on 2010 June 13. The temperature, density, and the line of sight depth ranges we obtain are in reasonable agreement with previous works. However, a detailed model of the spherical shock is needed to fit the observations. We also compare the model ratios with the observations of a current sheet feature on 2017 September 10. The long extended current sheet above the solar limb makes it easy to analyze the sheet without background corona. We find that the sheet feature is far from equilibrium ionization while the background plasma is close to equilibrium. We discuss our results with the previous studies assuming equilibrium ionization.

  • PDF

Nano-size Study of Surface-modified Ag Anode for OLEDs (표면처리에 의한 유기발광소자(OLED)용 Ag 전극의 Nano-size 효과 연구)

  • Kim, Joo-Young;Kim, Soo-In;Lee, Kyu-Young;Kim, Hyeong-Keun;Jun, Jae-Hyeok;Jeong, Yun-Jong;Kim, Mu-Chan;Lee, Jong-Rim;Lee, Chang-Woo
    • Journal of the Korean Vacuum Society
    • /
    • v.21 no.1
    • /
    • pp.12-16
    • /
    • 2012
  • Although silver is used for T-OLED (Top emitting organic Light-Emitting Diode) as reflective anode, it is not an ideal material due to its low work function. Thus, we study the effect of annealing and atmospheric pressure plasma treatment on Ag film that increases its work function by forming the thin silver oxide layer on its surface. In this study, we deposited silver on glass substrate using RF sputtering. Then we treated the Ag samples annealing at $300^{\circ}C$ for 30 minutes in atmosphere or treating the atmospheric plasma treatment for 30, 60, 90, 120s, respectively. We measured the change of the mechanical properties and the potential value of surface with each one at a different treatment type and time. We used nano-indenter system and KPFM (Kelvin Probe Force Microscopy). KPFM method can be measured the change of surface potential. The nanoindenter results showed that the plasma treatment samples for 30s, 120s had very low elastic modulus, hardness and Weibull modulus. However, annealed sample and plasma treated samples for 60s and 90s had better mechanical properties. Therefore, plasma treatment increases the uniformity thin film and the surface potential that is very effective for the performace of T-OLED.

Safety evaluation of atmospheric pressure plasma jets in in vitro and in vivo experiments

  • Lee, Ji-Yoon;Park, Shin-Young;Kim, Kyoung-Hwa;Yoon, Sung-Young;Kim, Gon-Ho;Lee, Yong-Moo;Seol, Yang-Jo
    • Journal of Periodontal and Implant Science
    • /
    • v.51 no.3
    • /
    • pp.213-223
    • /
    • 2021
  • Purpose: The atmospheric pressure plasma jet (APPJ) has been introduced as an effective disinfection method for titanium surfaces due to their massive radical generation at low temperatures. Helium (He) has been widely applied as a discharge gas in APPJ due to its bactericidal effects and was proven to be effective in our previous study. This study aimed to evaluate the safety and effects of He-APPJ application at both the cell and tissue levels. Methods: Cellular-level responses were examined using human gingival fibroblasts and osteoblasts (MC3T3-E1 cells). He-APPJ was administered to the cells in the experimental group, while the control group received only He-gas treatment. Immediate cell responses and recovery after He-APPJ treatment were examined in both cell groups. The effect of He-APPJ on osteogenic differentiation was evaluated via an alkaline phosphatase activity assay. In vivo, He-APPJ treatment was administered to rat calvarial bone and the adjacent periosteum, and samples were harvested for histological examination. Results: He-APPJ treatment for 5 minutes induced irreversible effects in both human gingival fibroblasts and osteoblasts in vitro. Immediate cell detachment of human gingival fibroblasts and osteoblasts was shown regardless of treatment time. However, the detached areas in the groups treated for 1 or 3 minutes were completely repopulated within 7 days. Alkaline phosphatase activity was not influenced by 1 or 3 minutes of plasma treatment, but was significantly lower in the 5 minute-treated group (P=0.002). In vivo, He-APPJ treatment was administered to rat calvaria and periosteum for 1 or 3 minutes. No pathogenic changes occurred at 7 days after He-APPJ treatment in the He-APPJ-treated group compared to the control group (He gas only). Conclusions: Direct He-APPJ treatment for up to 3 minutes showed no harmful effects at either the cell or tissue level.