• Journal of Advanced Marine Engineering and Technology
• /
• v.40 no.10
• /
• pp.883-887
• /
• 2016

This study aims to evaluate the corrosion behavior of a newly developed high-strength steel in marine environments. Metals used in seawater are easily deteriorated because of the presence of corrosive species such as chloride ions in it. Seawater causes much higher corrosion than fresh water. Thus, the corrosion of steel in marine environment has been recognized as a crucial problem in designing structures which cannot be cathodically protected. In this study, the corrosion resistance of a newly developed high-strength steel was evaluated. Four different specimens were tested to confirm the corrosion resistance. The exposure corrosion test was carried out by exposing the specimens to different marine environments such as atmospheric, tidal, splash, and submerged zones for two years. The specimens taken out from each location were cleaned ultrasonically and chemically prior to the evaluation of their corrosion resistance by the weight loss method. Finally, the pitting depth of the specimens was also measured to evaluate their pitting corrosion. The conditions used for the corrosion test were similar to the environmental conditions. The corrosion test results revealed that the corrosion rate and pitting corrosion of the newly developed high-strength steel was lower than that of the other carbon steels.

• Corrosion Science and Technology
• /
• v.19 no.6
• /
• pp.281-287
• /
• 2020

Chloride ion is one of the most important corrosive agents in atmospheric corrosion, especially in marine environments. It has high adsorption rate and increases the conductivity of electrolytes. Since chloride ions affect the protective properties and the surface composition of the corrosion product, they increase the corrosion rate. A low level of chloride ions leads to uniform corrosion, whereas a high level of chloride ions may induce localized corrosion. However, higher solution temperatures tend to increase the corrosion rate by enhancing the migration of oxygen in the solution. This work focused on the effect of NaCl concentration and temperature on galvanic corrosion between A516Gr.55 carbon steel and AA7075T6 aluminum alloys. When AA7075T6 aluminum alloy was galvanically coupled to A516Gr.55 carbon steel, AA7075T6 was severely corroded regardless of NaCl concentration and solution temperature, unlike the corrosion properties of single specimen. The combined effect of surface treatment involving carbon steel and aluminum alloy on corrosion behavior was also discussed.

• Journal of the Korean Chemical Society
• /
• v.56 no.6
• /
• pp.673-678
• /
• 2012

Using potentiodynamic and linear polarization method, the atmospheric effect on the corrosion of iron in borate buffer solution was investigated. The corrosion of iron was heavily influenced by the degree of oxygen concentration. The supply of reduction current was increased by the reduction of dissolved oxygen, and the corrosion potential of iron was shifted to the positive side. The $OH^-$ ion, which was produced through the reduction of either water or oxygen, significantly increased the $OH^-$ ion concentration inside of the electrical double layers of iron electrode, and facilitated the adsorption of $OH^-$ ion on the surface of the iron electrode. The adsorption of $OH^-$ ion on the iron electrode can be explained either by Langmuir isotherm or by Temkin logarithmic isotherm.

• Corrosion Science and Technology
• /
• v.2 no.5
• /
• pp.207-211
• /
• 2003

The weather resistance of five coatings systems based on alkyd, chlorinated rubber, epoxy, polyurethane and fluoropolymer were studied by natural exposure test and accelerated test. The coatings were exposed at Hanoi station with urban industry atmosphere and at Baichay station with marine atmosphere. The degradation of coatings was evaluated by gloss measurement and surface analysis by scanning electronic microscopy. The results obtained show that among coatings tested the gloss of polyurethane and fluoropolymer coatings remained highly and those of alkyd, chlorinated rubber and epoxy coatings were very low after two years of atmospheric exposure. Under accelerating conditions the gloss of fluoropolymer coatings remained highly after 80 cycles of testing. By comparison with accelerating test in UV-condensation chamber the conditions at atmospheric stations are more aggressive.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 1998.05a
• /
• pp.131-132
• /
• 1998

• Corrosion Science and Technology
• /
• v.10 no.2
• /
• pp.52-59
• /
• 2011

Corrosion of metallic materials occurs by the reaction with corrosive environment such as atmosphere, marine, soil, urban, high temperature etc. In general, reduction of thickness and cracking and degradation are resulted from corrosion. Corrosion in all industrial facilities and infrastructure causes large economic losses as well as a large number of accidents. Economic loss by corrosion has been reported to be nearly 1-6% of GNP or GDP. In order to reduce corrosion damage of industrial facilities, corrosion map as well as a systematic investigation of the loss of corrosion in each industrial sector is needed. The Corrosion Science Society of Korea in collaboration with 15 universities and institutes has started to survey on the cost of corrosion and corrosion map of Korea since 2005. This work presents the results of the survey on cost of corrosion by Uhlig, Hoar, and input-output methods, and the evaluation of atmospheric corrosion rate of carbon steel, weathering steel, galvanized steel, copper, and aluminum in Korea. The total corrosion cost was estimated in terms of the percentage of the GDP of industry sectors and the total GDP of Korea. According to the result of Input/output method, corrosion cost of Korea was calculated as 2.9% to GDP (2005). Time of wetness was shown to be categories 3 to 4 in all exposure areas. A definite seasonal difference was observed in Korea. In summer and fall, time of wetness was higher than in other seasons. Because of short exposure period (12 months), significant corrosion trends depending upon materials and exposure corrosion environments were not revealed even though increased mass loss and decreased corrosion rate by exposure time.

• Corrosion Science and Technology
• /
• v.10 no.6
• /
• pp.199-204
• /
• 2011

Hot dip metallic coated steels like as galvanized (GI), zinc-aluminium (GL) and aluminium coated steels are mostly used where corrosion resistance is needed. There are two kinds (type 1 and type 2) of aluminium coated steel being commercially used among them. Type 1 aluminium coated steel is coated with an Al-5~11 wt%Si alloy and Type 2 aluminium coated steel consists of commercially pure aluminium. Type 1 Al coated steel is generally used in automotive components and electrical appliances while type 2 aluminium coated steel is mainly used in construction applications such as building cladding panels, air conditioning and ventilation system. In this study, Type 1 aluminium coated steels have tested by accelerated conditions (salt spray or corrosive gas) and outdoor exposure condition in order to understand their corrosion behaviour. Due to the distinct corrosion mechanism of Al which exposes to the severe chloric condition, Salt Spray Test cannot predict the ordinary atmospheric corrosion of Al based coated materials. In addition, the test results and their corrosion feature of Al coated steel sheets will be discussed comparing with other metallic coated steel sheets of GI and GL.

• Proceedings of the KSR Conference
• /
• 2002.10b
• /
• pp.981-986
• /
• 2002

ACSR of the catenary wires is corrosion degradation progressed by the effect of atmospheric pollution. ACSR which consists of galvanized steel stranded aluminum. The inside of Steel Reinforced is hot-dipped zinc coating steel wire and it takes charge of tension. If ACSR is exposed in atmosphere, the galvanic corrosion is occurred because it is contacted with aluminum. It is occurred the chemical reaction rapidly so that the local a defect is also occurred. If the catenary wires are exposed in atmosphere of pollution conditions, it may cause to reduce the mechanical strength by corrosion degradation and may cause to damage the wires by micro cracks. Accordingly, this study presents the effects of mechanical properties through the corrosion of ACSR.

• Journal of the Korean Chemical Society
• /
• v.55 no.4
• /
• pp.575-580
• /
• 2011

It was investigated into the effects on zinc corrosion of the rotation speed of Zn-RDE and the oxygen concentration in borate buffer solution. Zinc corrosion was heavily influenced on the rotation speed of electrode and the oxygen concentration. We have suggested the disproportion reaction following the reversible one electron transfer as the corrosion mechanism of zinc.

• Journal of Surface Science and Engineering
• /
• v.53 no.5
• /
• pp.201-206
• /
• 2020

A SiOxCy(-H) thin film was synthesized by atmospheric pressure dielectric barrier discharge(APDBD), and a SiO₂-like layer was formed on the surface of the film by oxidation treatment using oxygen plasma. Hexamethylcyclotrisiloxane was used as a precursor for the SiOxCy(-H) synthesis, and He gas was used for stabilizing APDBD. Oxygen permeability was evaluated by forming an oxidized SiOxCy(-H) thin film on a PET film. When the single-layer oxidized SiOxCy(-H) film was coated on the PET, the oxygen gas permeability decreased by 46% compared with bare PET. In case of three-layer oxidized SiOxCy(-H) film, the oxygen gas permeability decreased by 73%. The oxygen permeability was affected by the thickness of the SiO₂-like layer formed by oxidation treatment rather than the thickness of the SiOxCy(-H) film. The excellent corrosion resistance was demonstrated by coating an oxidized SiOxCy(-H) thin film on the silver-coated aluminum PCB for light emitting diode (LED).