• 제목/요약/키워드: Atmospheric $SO_2$

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시정의 계절적 변동성 및 대기특성과의 관련성 (Seasonality and relation to atmospheric characteristics in Visibility)

  • 안미진;윤중섭;조석주;여인학;이민환;김민영
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2000년도 추계학술대회 논문집
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    • pp.361-362
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    • 2000
  • 대기오염을 해결하기 위한 서울시의 노력에 의해 아황산가스(SO$_2$), 총먼지(TSP)등의 1차 오염물질들은 어느 정도 개선되어 왔으나, 일반 시민들의 체감대기오염도는 과거에 비해 더욱 악화되었으며, 이는 교통량의 급격한 증가로 인한 고농도 오존사례와 같은 광화학스모그와 시정악화가 가장 대표적인 것으로 우리시의 현안문제로 대두하고 있는 실정이다. 이에 본 연구에서는 시정의 시간적인 변동성과 시정 악화를 야기하는 인자들을 파악하여 이에 대한 대처방안을 모색하고자 한다. (중략)

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Temporal Variation of Atmospheric Radon-222 and Gaseous Pollutants in Background Area of Korea during 2013-2014

  • Bu, Jun-Oh;Song, Jung-Min;Kim, Won-Hyung;Kang, Chang-Hee;Song, Sang-Keun;Williams, Alastair G.;Chambers, Scott D.
    • Asian Journal of Atmospheric Environment
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    • 제11권2호
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    • pp.114-121
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    • 2017
  • Real-time monitoring of hourly concentrations of atmospheric Radon-222 ($^{222}Rn$, radon) and some gaseous pollutants ($SO_2$, CO, $O_3$) was performed throughout 2013-2014 at Gosan station of Jeju Island, one of the cleanest regions in Korea, in order to characterize their background levels and temporal variation trend. The hourly mean concentrations of radon and three gaseous pollutants ($SO_2$, CO, $O_3$) over the study period were $2216{\pm}1100mBq/m^3$, $0.6{\pm}0.7ppb$, $211.6{\pm}102.0ppb$, and $43.0{\pm}17.0ppb$, respectively. The seasonal order of radon concentrations was as fall ($2644mBq/m^3$)$${\sim_\sim}$$winter ($2612mBq/m^3$)>spring ($2022mBq/m^3$)>summer ($1666mBq/m^3$). The concentrations of $SO_2$ and CO showed similar patterns with those of radon as high in winter and low in summer, whereas the $O_3$ concentrations had a bit different trend. Based on cluster analyses of air mass back trajectories, the air mass frequencies originating from Chinese continent, North Pacific Ocean, and the Korean Peninsula routes were 30, 18, and 52%, respectively. When the air masses were moved from Chinese continent to Jeju Island, the concentrations of radon and gaseous pollutants ($SO_2$, CO, $O_3$) were relatively high: $2584mBq/m^3$, 0.76 ppb, 225.8 ppb, and 46.4 ppb. On the other hand, when the air masses were moved from North Pacific Ocean, their concentrations were much low as $1282mBq/m^3$, 0.24 ppb, 166.1 ppb, and 32.5 ppb, respectively.

목포, 여천지역 강수의 무기이온 성분농도와 거동에 관한 연구 (A Study on Ion Distribution and Behavior of Acidrain in Mokpo and Yeochon Area)

  • 오길영;양수인;이완진
    • 한국대기환경학회지
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    • 제15권4호
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    • pp.385-392
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    • 1999
  • This study was carried out to investigate the constituents of inorganic ions of precipitation in Mokpo and Yeochon area from Jan. 1996 to Dec. 1997. The volume-weighted mean pH of precipitation was 5.7(4.8~7.8) at Mokpo, and 5.6(5.1~7.4) at Yeochon area, respectively. The non-seasalt(nss) anion concentrations were found in order of $nss-SO^{2-}_4>NO^-_3>nss-Cl^-$ at two areas. The portion of $nss-SO^{2-}_4;and;NO^-_3$ was 71~84% out of anions. The the non-seasalt cation concentrations were found in order of $NH^+_4>nss-Ca^{2-}>nss-Mg^{2+}>nss-K^-$ at two areas. The portion of $NH^+_4;and; nss-Ca^{2+}$ was 85~92% out cations. Compared regionally the year concentraton of $nss-SO^{2-}_4$, the result of Yeochon was 3 times higher than that of Mokpo in 1996, while the results of two regions were almost similar in 1997. The reason was that Yeochon was restricted area of the use of 0.5% sulfur B-C oil, controlled air pollution emission area, controlled semitotal amounts of air pollution emission area and partial operating of factories in 1997. There were no ions having high correlation with $H^+,;but;nss-SO^{2-}_4,;NO^-_3,;NH^+_4;and;nss-Ca^{2+}$ showed high correlation coefficient each other. It seems that these ions have little correlation with $H^+$ because they are washed out on binding state. Factor analysis showed that the first factor was complicated factor containing anthropogenic and soil resource, the second factor was sea-salt resource and the third factor was independent behavior of hydrogen at Mokpo. While, the first factor was complicated factor containing anthropogenic and sea-salt resource, the second factor was $Ca(NO_3)_2$ salt and the third factor was $NH^+_4;and;SO^{2-}_4$ synergied by resource and combination at Yeochon.

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Evaluation of DMS Flux and Its Conversion to SO(sub)2 in Tropical ACE 1 Marine Boundary Layer

  • Shon, Zang-Ho;Taekyung Yoon;Kim, Jungkwon
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제4권3호
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    • pp.139-148
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    • 2000
  • A mass balance/photochemical modeling approach was used to evaluate the sea-to-air dimethyl sulfide (DMS) fluxes in tropical regions and part of the Southern Ocean. The flux determinations were based on 10 airborne observations by ACE 1 transit flights (i.e., Flights 4-9 and 29-32). The DMS flux values for the tropical regions ranged from 1.0 to 7.4 $\mu$mole/$m^2$/day with an average estimate of 4.2$\pm$2.3 $\mu$mole/$m^2$/day. The seasonal variations in the DMS flux predicted for the equatorial Pacific Ocean based on atmospheric DMS measurements were not entirely consistent with those derived from seawater DMS measurements were not entirely consistent with those derived from seawater DMS measurements reported in previous literature. Inhomogeneities in the DMS flux field were found to cause significant shifts in the atmospheric DMS levels even in the same sampling location. Accordingly, no definitive statement can be made at this stage regarding systematic differences or agreements in the DMS flux estimates from the two approaches. Moreover, this study strongly suggests that DMS oxidation is the most likely dominant source of SO$_2$in tropical regions, which is also supported by another set of compiled observations. Finally, these SO$_2$observations indicate that, when significant data was available for both the boundary and buffer layers, the vertical SO$_2$gradient between these two zones was primarily negative.

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