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Chemisorption and Oxidation of Methanol over V2O5 Catalyst - I. Chemisorptive Behaviors of CO and CH3OH - (V2O5 촉매상에서의 메탄올 흡탈착 및 산화반응 - I. CO와 CH3OH의 화학흡착 특성 -)

  • Kim, Eul-San;Choi, Ki-Hyouk;Lee, Ho-In
    • Applied Chemistry for Engineering
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    • v.5 no.2
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    • pp.189-198
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    • 1994
  • The adsorptive behaviors of carbon monoxide and methanol over $V_2O_5$catalyst were studied by means of thermal desorptlon spectroscopy (TDS) under ultrahigh vacuum conditions. Carbon monoxide adsorbed on oxygen-deficient V sites as well as on V=O groups of the $V_2O_5$ surface. CO adsorbed on the V sites desorbed at 380 K while CO adsorbed on the V=O groups formed carbonate species with surface oxygen of $V_2O_5$ and desorbed as $CO_2$ resulting in the reduction of the surface of she $V_2O_5$catalyst. The amount of CO adsorbed in the form of carbonate species increased by both the pre- and post-adsorbed oxygen. The adsorptive behavior of methanol over the catalyst was studied by thermal desorption experiments of $CH_3OH$, HCHO, CO, and $H_2$ upon methanol adsorption at 298 K. The results showed that methanol was adsorbed dissociatively on the $V_2O_5$catalyst as methoxy and hydroxyl groups at 298K.

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A Study on IKE v2 Analysis Method for RealTime (NIKEv2 AR : IKE v2 실시간 분석 기술 연구)

  • Park, Junghyung;Ryu, Hyungyul;Ryou, Jaecheol
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.32 no.4
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    • pp.661-671
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    • 2022
  • Due to the COVID-19 pandemic, remote working, e-learning, e-teaching and online collaboration have widely spread and become popular. Accordingly, the usage of IPsec VPN for security reasons has also dramatically increased. With the spread of VPN, VPN vulunerabilities are becoming an important target of attack for attackers, and many studies have been conducted on this. IKE v2 analysis is an essential process not only for developing and building IPsec VPN systems but also for security analysis. Network packet analysis tools such as Wireshark and Tcpdump are used for IKE v2 analysis. Wireshark is one of the most famous and widely-used network protocol analyzers and supports IKE v2 analysis. However Wireshark has many limitations, such as requiring system administrator privileges for IKE v2 analysis. In this paper, we describe Wireshark's limitations in detatil and propose a new analysis method. The proposed analysis method can analyze all encrypted IKE v2 messages in real time from the session key exchange In addition, the proposed analysis method is expected to be used for dynamic testing such as fuzzing as packet manipulation.

A Study on photoluminescience of ZnSe/GaAs epilayer

  • Park, Changsun;Kwangjoon Hong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.84-84
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    • 2003
  • The ZnSe epilayers were grown on the GaAs substrate by hot wall epitaxy. After the ZnSe epilayers treated in the vacuum-, Zn-, and Se-atmosphere, respectively, the defects of the epilayer were investigated by means of the low-temperature photoluminescence measurement. The dominant peaks at 2.7988 eV and 2.7937 eV obtained from the PL spectrum of the as-grown ZnSe epilayer were found to be consistent with the upper and the lower polariton peak of the exciton, I$_2$ (D$^{\circ}$, X), bounded to the neutral donor associated with the Se-vacancy. This donor-impurity binding energy was calculated to be 25.3meV The exciton peak, lid, at 2.7812 eV was confirmed to be bound to the neutral acceptor corresponded with the Zn-vacancy. The I$_1$$\^$d/ peak was dominantly observed in the ZnSe/GaAs:Se epilayer treated in the Se-atmosphere. This Se-atmosphere treatment may convert the ZnSe/GaAs:Se epilayer into the p-type. The SA peak was found to be related to a complex donor like a (V$\sub$se/ - V$\sub$zn/) - V$\sub$zn-/

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Studies on the Preparation for the Simultaneous Removal of NO and $SO_2$ from Stationary Sources I.Surface properties and reactivity of $V_2O_5-MoO_3/TiO_2$ catalysts (고정원에서 배출되는 $NO_x/SO_x$의 동시제거를 위한 SCR 촉매의 제조법에 관한 연구: I. $V_2O_5-MoO_3/TiO_2$ 촉매들의 표면특성과 반응성)

  • 구미화;정석진
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.1
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    • pp.58-67
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    • 1992
  • For removing $NO_x$ and $SO_x$ from the flue gases emitted from stationary sources, $V_2O_5-MoO_3/TiO_2$ catalysts were prepared by the conventional impregnation method (aqueous solution) and a sort of surface fixation method(nonaqueous solution) as reported excellent reproducibility catalysts. And these catalysts observed their catalytic activities as well as their surface properties. V-Mo-O oxide, prepared from nonaqueous solution of $VOCl_3$ and $Mo(CO)_6$ and aqeous solution method, was supported as amorphous state by XRD and SEM measurements. The infrared spectra of fresh and used catalysts showed that in used catalysts, V=O bands decreased and new bands of vanadium oxysulfate bands were very sensitive. So the catalysts prepared from nonaqueous solution may bring about the high activity. Results from catalytic activity measurements at 350$^\circ$C, in the presence of $SO_2, NO$ conversion was more increased than in absence of $SO_2$. As the $MoO_3$ was added to $V_2O_5/TiO_2 system, SO_2$ conversion increased. It found that from the results, $V_2O-5-MoO_3/TiO_2$ catalysts prepared from an nonaqueous solution may bring about the high activity for both the reaction of NO and $SO_2$ removal.

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Properties of photoluminescience for ZnSe/GaAs epilayer grown by hot wall epitaxy

  • Hong, Kwangjoon;Baek, Seungnam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.3
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    • pp.105-110
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    • 2003
  • The ZnSe epilayers were grown on the GaAs substrate by hot wall epitaxy. After the ZnSe epilayers treated in the vacuum-, Zn-, and Se-atmosphere, respectively, the defects of the epilayer were investigated by means of the low-temperature photoluminescence measurement. The dominant peaks at 2.7988 eV and 2.7937 eV obtained from the PL spectrum of the as-grown ZnSe epilayer were found to be consistent with the upper and the lower polariton peak of the exciton, $I_{2}$ ($D^{\circ}$, X), bounded to the neutral donor associated with the Se-vacancy. This donor-impurity binding energy was calculated to be 25.3 meV, The exciton peak, $I_{1}^{d}$ at 2.7812 eV was confirmed to be bound to the neutral acceptor corresponded with the Zn-vacancy. The $I_{1}^{d}$ peak was dominantly observed in the ZnSe/GaAs : Se epilayer treated in the Se-atmosphere. This Se-atmosphere treatment may convert the ZnSe/GaAs : Se epilayer into the p-type. The SA peak was found to be related to a complex donor like a $(V_{se}-V_{zn})-V_{zn}$.

A Study point defect for thermal annealed ZnSe/GaAs epilayer

  • Hong, Kwang-Joon;Lee, Sang-Youl
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.120-123
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    • 2003
  • The ZnSe epilayers were grown on the GaAs substrate by hot wall epitaxy. After the ZnSe epilayers treated in the vacuum-, Zn-, and Se-atmosphere, respectively, the defects of the epilayer were investigated by means of the low-temperature photoluminescence measurement. The dominant peaks at 2.7988 eV and 2.7937 eV obtained from the PL spectrum of the as-grown ZnSe epilayer were found to be consistent with the upper and the lower polariton peak of the exciton, $I_2$ ($D^{\circ}$, X), bounded to the neutral donor associated with the Se-vacancy. This donor-impurity binding energy was calculated to be 25.3 meV. The exciton peak, $I_1^d$, at 2.7812 eV was confirmed to be bound to the neutral acceptor corresponded with the Zn-vacancy. The $I_1^d$ peak was dominantly observed in the ZnSe/GaAs:Se epilayer treated in the Se-atmosphere. This Se-atmosphere treatment may convert the ZnSe/GaAs:Se epilayer into the p-type. The SA peak was found to be related to a complex donor like a $(V_{Se}-V_{Zn})-V_{Zn}$.

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Electrical and Photoluminescence Characteristics of Nanocrystalline Silicon-Oxygen Superlattice for Silicon on Insulator Application

  • Seo, Yong-Jin
    • KIEE International Transactions on Electrophysics and Applications
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    • v.2C no.5
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    • pp.258-261
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    • 2002
  • Electrical forming dependent current-voltage (I-V) and numerically derived differential conductance(dI/dV) characteristics have been presented in the multi-layer nano-crystalline silicon/oxygen (no-Si/O) superlattice. Distinct staircase-like features, indicating the presence of resonant tunnel barriers, are clearly observed in the dc I-V characteristics. Also, all samples showed a continuous change in current and zero conductivity around OV corresponding to the Coulomb blockade in the calculated dI/dV-V curve. Also, Ra-man scattering measurement showed the presence of a nano-crystalline Si structure. This result becomes a step in the right direction for the fabrication of silicon-based optoelectronic and quantum devices as well as for the replacement of silicon-on-insulator (SOI) in high speed and low power silicon MOSFET devices of the future.

Axial Force of a V-Belt CVT -Experimental Study- (V-벨트 CVT의 축력해석 II -실험적 연구-)

  • 김광원;김현수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.847-854
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    • 1989
  • Axial force of a V-belt CVT is investigated experimentally. The experimental results on speed ratio-torque-axial force show good agreement with the theoretical results that were obtained in the previous work. It is also found that torque capacity of the V-belt CVT increases as the axial force and the speed ratio increase. Impending slip which occurs at the maximum torque is determined via experiments for various speed ratios. Based on the impending slip region, and the theoretical curves for the speed ratio-torque-axial force relationship, an actual operating criteria for the V-belt CVT is obtained. It is suggested to use the actual operating criteria with the theoretical equations as a basic design formula for the V-belt CVT.

The Software Verification and Validation Tasks for a Safety Critical System in Nuclear Power Plants

  • Cheon Se Woo;Cha Kyung Ho;Kwon Kee Choon
    • International Journal of Safety
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    • v.3 no.1
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    • pp.38-46
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    • 2004
  • This paper introduces the software life-cycle V&V (verification and validation) tasks for the KNICS (Korea nuclear instrumentation and control system) project. The objectives of the V&V tasks are mainly to develop a programmable logic controller (PLC) for safety critical instrumentation and control (I&C) systems, and then to apply the PLC to developing the prototype of an engineered safety features-component control system (ESF-CCS) in nuclear power plants. As preparative works for the software V&V, various kinds of software plans and V&V task procedures have been developed according to the software life-cycle management. A number of software V&V tools have been adopted or developed to efficiently support the V&V tasks. The V&V techniques employed in this work include a checklist-based review and inspection, a requirement traceability analysis, formal verification, and life-cycle based software testing.

Analysis of the electrostatic induction voltage and electromagnetic induction current on the Parallel Circuit in 765kV Double Circuit Transmission Line (765kV 2회선 송전선로를 765kV 및 345kV로 병행운전시 유도현상 예측)

  • Woo, J.W.;Shim, E.B.;Kwak, J.S.;Jeon, M.R.;Kim, K.I.;Kim, T.O.
    • Proceedings of the KIEE Conference
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    • 2002.07a
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    • pp.169-171
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    • 2002
  • The western route of KEPCO's 765kV transmission line has been tentatively operating as 345kV voltage before commercial operation. After finishing the test operation of 765kV substation in 2002. KEPCO decided to operate the 765kV line for commercial operation. During the applying of 765kV voltage to the transmission line, double circuit transmission line will be operated with two voltage grades of 765kV and 345kV. Because the earthing switch is installed on both end of transmission line, we had estimated the electrostatic induction voltage and electromagnetic induction current before the line energizing in order to confirm the ratings of earthing switch. The induced voltage and current is very important for the maintenance of parallel circuit. This paper describes the simulation study of electrical phenomena such as electrostatic induction voltage from the parallel line and electromagnetic induction current from the parallel circuit. The transmission line model was developed by EMTP (Electro-Magnetic Transient Program).

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