• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.218-222
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• 2004

Batch slurry experiments were conducted to develop cement/slag/Fe(II) system that could treat hazardous liquid wastes containing halogenated organic solvents. Portland cement in combination with Fe(II) was reported to reductively dechlorinate chlorinated organics in a modified solidification/stabilization process. TCE (trichloroethylene) was used a model halogenated organic solvent. The objectives of this study were to assess the feasibility of using cement and steel converter slag amended with Fe(II) as a low cost abiotic reductive dechlorination and to investigate the kinetics of TCE dechlorination over a wide range of TCE concentration. From the result of screening experiments, cement/slag/Fe(II) system was identified as a potentially effective system to treat halogenated organic solvent. Kinetic studies were carried out to further investigate degradation reaction of TCE NAPL (Non Aqueous Phase Liquids) in cement/slag/Fe(II) systems by using batch slurry reactors. Degradation rate of TCE solution in this system can be explained by pseudo-first-order rate law because the prediction with the rate law is in good agreement with the observed data.

• Membrane and Water Treatment
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• v.9 no.1
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• pp.63-68
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• 2018

Molecular dynamics simulations were used to study the removal of Cd(II) as a heavy metal from wastewater using armchair carbon nanotube, boron nitride nanotube and silicon carbide nanotubes under applied electric field. The system contains an aqueous solution of $CdCl_2$ as a heavy metal and a (7,7) nanotube as a nanostructured membrane, embedded in a silicon nitride membrane. An external electric field was applied to the considered system for the removal of $Cd^{2+}$ through nanotubes. The simulation results show that in the same conditions, considered armchair nanotubes were capable to remove $Cd^{2+}$ from wastewater with different ratios. Our results reveal that the removal of heavy metals ions through armchair carbon, boron nitride and silicon carbide nanotubes was attributed to the applied electric field. The selective removal phenomenon is explained with the calculation of potential of mean force. Therefore, the investigated systems can be recommended as a model for the water treatment.

• Journal of Institute of Control, Robotics and Systems
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• v.10 no.11
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• pp.981-990
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• 2004

Specialized propulsors for naval applications have numerous opportunities in terms of research, design and fabrication of an appropriate propulsor. One of the most important components of any propulsor is the actuator that provides the mode of locomotion. Ionomeric electro-active polymer may offer an attractive solution for locomotion of small propulsors. A common ionomeric electro-active polymer, ionic Polymer-Metal Composites (IPHCs) give large true bending deformations under low driving voltages, operate in aqueous environments, are capable of transduction and are relatively well understood. IPMC fabrication and operation are presented to further elucidate the use of the material for a propulsor. Various materials, including IPMCs, are investigated and a simplified propulsor model is explored.

• Archives of Pharmacal Research
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• v.13 no.1
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• pp.43-50
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• 1990

Conformational free energy calculations using an empirical potential function (ECEPP/2) and hydration shell model were carried out on the four-4-aminodiphenyl sulfone analogues of 4, 4'-diamino-2' methyldiphenyl sulfone, 4, 2', 4-triaminodiphenyl sulfone, 4, 4'-diaminodiphenyl sulfone, and 4-aminodiphenyl sulfone as antibacterial agents on Mycobacterium lufu. The conformational energy was minimized from starting conformations which included possible combinations of torsion angles in the molecule. The conformational entropy change of each conformation was computed using a harmonic approximation. To understand the hydration effect on the conformation of the molecule in aqueous solution, the contributions of water-accessible volume and the hydration free energy of each group or atom in the lowest-free-energy conformation was calculated and compared each other. From comparison of the computed lowest-free-energy conformations of four analogues with their antibacterial activities, it is known that the conformation and the hydrophobicity of sulfonyl group and its adjacent carbon atom in each compound are the essential factors to show the strong antibacterial activity.

• KSBB Journal
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• v.4 no.2
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• pp.150-156
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• 1989

The chaacterisitics of a commercial membrance-coverd electrode in air-saturated saline solution were investigated in terms of a steadystate one-dimensional model. The electrode system miiersed in an aqueous medium consists of three layers: an external concentration boundary layer, a membrance, and an inner electrolyte layer. The membrance can be permeabld to the water and impermeable to the ionic species. In stationary midium, the water migrates from the external medium to the inner electrolyte layer until a thermodynamic equilibrium is reached. In a following midium, however, there is a reverse direction of water movement due to the hyrodynamic pressure differential until both thickness of the electrolyte layer and the membrance are equal.

• Journal of the Korean Ceramic Society
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• v.31 no.6
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• pp.678-684
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• 1994

The surface of alumina is capable of acquiring a change when it is in an aqueous solution. This surface change will have a strong influence on the surrounding ions, particularly those of opposite change known as the counter ions. A site-binding model of the {{{{ gamma }}-alumina/KCl(aq) interface was used to calculated theoretical surface ionization constants and P.Z.C.(Point of zero change) of {{{{ gamma }}-alumina. This paper was carried out to investigate the effect of calcination temperature on the acidic and electrical properties of pure {{{{ gamma }}-alumina prepared by the precipitation method from the Al(NO3)3.9H2O and NH4OH. From the experimental data it was shown that {{{{ gamma }}-alumina have a mainly Br nsted acid site. However, the acidity of {{{{ gamma }}-alumina decreased with increasing calcination temperature at strength Ho +9.3. The surface charge density of {{{{ gamma }}-alumina was increased with electrolyte ionic strength and calcination temperature.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.2
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• pp.399-406
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• 1990

This paper is studied to know corrosive wear mechanism of STS304 steel on atmospherical temperature against mating material as the same. The corrosive test was carried out by rubbing the annular surface of two test pieces in distilled water and NaCl aqueous solution. The corrosive wear mechanism was investigated by S.E.M. The experimental results show that there is one Lcr transferring from severe wear to mild wear on change of NaCl concentration and atmospherical temperature, and which is the other still remaining in server wear state. It was found that the critical sliding distance Lcr shorten with increasing NaCl concentration but it is longer with ascending atmospherical temperature and the mild wear state still continues under the condition of high generation rate and elimination rate of the corrosive product. Considering upon the result, the model of corrosive wear mechanism is proposed.

• Elastomers and Composites
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• v.52 no.2
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• pp.131-135
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• 2017

Zinc nitrate hexahydrate [$Zn(NO_3){\cdot}6H_2O$] and sodium hydroxide [NaOH] were used as source reagents in the preparation of ZnO nanoparticles in an aqueous solution containing deionized water and ethanol in a ratio of 2:5 (v/v). ZnO nanoparticles were heated in an electric furnace at $700^{\circ}C$ for 2 h under an atmosphere of inert argon gas. The morphological and structural properties of the nanoparticles were characterized by scanning electron microscopy (SEM) and powder X-ray diffractometry (XRD). UV-vis spectrophotometry was used to analyze the photocatalytic degradation of 3-nitrophenol with ZnO nanoparticles as photocatalyst under ultraviolet irradiation at 254 nm. Evaluation of the kinetic of the photo-catalytic degradation of 3-nitrophenol indicated that the degradation of 3-nitrophenol with ZnO nanoparticles obeyed the pseudo-first order reaction rate model.

• Journal of Korean Society on Water Environment
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• v.25 no.3
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• pp.370-374
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• 2009

Adsorption characteristics of glass fibers, obtained from the spent lithium primary batteries recycling process, were investigated for the removal of Acid Red 27 dye from aqueous solution. The batch data clearly showed that increasing the initial sorptive concentration apparently enhanced the amount adsorbed and the uptake process followed the pseudo-second order rate model. The equilibrium adsorption data at different initial sorptive concentrations were fitted well to Freundlich and Langmuir adsorption isotherms. Moreover, the increase in temperature, favored the uptake of dye on this solid, indicated the process was endothermic in nature. Further, using the temperature dependence sorption data obtained at different temperatures was used to estimate various thermodynamic parameters.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1992.11a
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• pp.128-131
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• 1992

In this paper, the skewness properties of partial discharge at interface layer in mica-epoxy composite material were investigated and studied on interface specimens which has internal electrodes. As a result, it has been confirmed that the interface exists as abnormal resin layer and the contact condition at the interface is depended upon the density of si lane aqueous solution. The Pulse frequency of discharge at abnormal interface has been shown a linear increasing with enlargement of discharge quantity according to rising of the applied voltage. Whereas, in case of normal interface, pulse frequency represented exponential increasing at the saturating point of discharge quantity. The aging model can be represented from the variable characteristics of skewness.