• Title/Summary/Keyword: Aqueous

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Evaluation of Water Softening with the Removal of Calcium Ion by Ion Flotation Approach

  • Mafi, Azadeh;Khayati, Gholam
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.219-224
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    • 2021
  • Ion flotation is an efficient method to remove metal ions from aqueous solution. In this work, ion flotation was applied to calcium removal from aqueous solution. The parameters used included sodium stearate (SS) and sodium dodecyl sulfate (SDS) as collectors, 1-butanol and 1-propanol as frothers, pH, and air-flow rate. An L16 orthogonal array was chosen according to the mentioned factors and levels, and experimental tests were conducted according to the Taguchi orthogonal array. The results showed that all of the factors except one had significant effect on the flotation performance. The percentage contribution of parameters showed that type of frother and type of collector made the greatest (43.14%) and the lowest (9.86%) contribution, respectively. In optimal conditions, the recovery of Ca (II) ion was 45.67%. Also, the results illustrated that the Taguchi method could predict calcium removal from aqueous solution by ion flotation with 2.63%. This study showed that the use of ion flotation was an effective method for Ca (II) ion removal from aqueous solution.

Strength Property of Concrete Mixed Blast Furnace Slag Using Electrolysis Alkaline Aqueous as Mixed Water (전기분해 알칼리수를 배합수로 활용한 고로슬래그 혼입 콘크리트의 강도 특성)

  • Jeong, Su-Mi;Kim, Ju-Sung;Park, Sun-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.135-136
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    • 2023
  • In this study, a concrete was prepared using an alkaline aqueous solution produced by electrolyzing potassium carbonate in order to improve the low initial strength of concrete using blast furnace slag. In order to confirm the increase in initial strength, the compressive strength of specimens was measured on the age of 7, 28 days. As a result, the blast furnace slag concrete using the electrolysis alkaline aqueous solution as the mixed water show high strength more than the blast furnace slag concrete using the general mixed water.

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In Vitro Antibacterial Effects of Tunong-san and Kwaruwoobang-tang Aqueous Extracts against Staphylococcus aureus (투농산(透膿散) 및 과루우방탕(瓜蔞牛蒡湯)의 Staphylococcus aureus에 대한 In Vitro 항균력 평가)

  • Jang, Se-Ran;Park, Young-Sun;Kim, Dong-Chul
    • The Journal of Korean Obstetrics and Gynecology
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    • v.25 no.3
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    • pp.27-39
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    • 2012
  • Objectives: Recently Ciprofloxacin, used in the treatment of mastitis, showed many serious side effects. The object of this study was to recognize whether TNS and KWT can be used in the treatment of mastitis by observing the in vitro antibacterial effects of TNS and KWT aqueous herbal extracts against S. aureus. Methods: Antibacterial activities of TNS and KWT aqueous extracts against S. aureus ATCC 25923 were detected using standard agar microdilution methods. In addition, the effects on the bacterial growth curve were monitored at MIC and $MIC{\times}2$ levels. The effects on the intracellular killing and bacterial invasion of individual test materials were also observed using Raw 264.6 and MCF-7. The results were compared with Ciprofloxacin, a second generation of quinolone antibiotics in the present study. Results: MIC of aqueous extracts of TNS and KWT against S. aureus were detected as ($0.313{\pm}0.107$) and ($0.137{\pm}0.053$) mg/ml, respectively. MIC of Ciprofloxacin was detected as ($0.469{\pm}0.297$) ${\mu}g/ml$ at same conditions. In addition, TNS, KWT aqueous herbal extracts and Ciprofloxacin were also showed marked dosage-dependent inhibition of bacterial growth, and dramatical inhibitions on the both intracellular killing assays and bacterial invasion using Raw 264.6 and MCF-7 cells were detected. Conclusions: The results obtained in this study suggest that TNS and KWT aqueous herbal extracts showed antibacterial effects against S. aureus, and they also showed dosage-dependent inhibitory effects on the bacterial growth. And they showed the significant intracellular killing and bacterial invasion effects. It means, KWT and TNS may show more potent anti-infectious effects against S. aureus in vivo.

Allelopathic Effect of Aqueous Extract of Ganghwa Mugwort (Artemisia spp.) Vegetables and HPLC Aanalysis of Allelochemicals (강화약쑥 수용성 추출물의 식물 타감효과 및 HPLC에 의한 타감물질 분석 연구)

  • Lee, Joo-Hwa;Byeon, Ji-Hui;Kim, Moung-Su;Park, Chun-Geon;Park, Chung-Berm;Cha, Sun-Woo;Lee, Jeong-Hoon;Cho, Joon-Hyeong
    • Korean Journal of Organic Agriculture
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    • v.21 no.4
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    • pp.737-752
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    • 2013
  • This study was conducted to evaluate the allelopathic effect of aqueous extract of Ganghwa domestic mugwort (Artemisia spp.) on vegetables and its related allelo-chemicals. When the receptor vegetables, such as Chinese cabbage, lettuce, and red radish, were treated with aqueous extract obtained from Sajabalssuk (A. $sp^*I$), Ssajuarissuk (A. $sp^*II$) or Ssajarissuk (A. $sp^*III$), their germination rate, leaf number, plant height, and root length were restricted with increasing concentration of aqueous extract. Allelopathic effect was the highest in radish, than lettuce and Chinese cabbage in order. The growth of topplant were more inhibited then root growth observing in restriction of plant height, root length, and chlorophyll contents. The plant height, the root length of red radish were 53.3 and 61.2% and their fresh weights were 19.8 and 26.4% compared to those of controls, respectively. A. $sp^*III$ showed the highest allelopathic effect among the donor plants. In HPLC analysis, 7 phenol compounds were identified in A. $sp^*I$ and A. $sp^*II$, and, in A. $sp^*III$, and hydroxybenzoic acid and phenylacetic acid were further identified as allelochemicals. It is considered that their plant growths were variously inhibited by the amounts and types of allelochemicals in aqueous extracts. To increase the productivity of farm land after cultivation of mugwort, these results can be useful to select the following field crops.

Dispersion Stability of Rutile TiO2Powder Obtained by Homogeneous Precipitation Process at Low Temperature (저온균일침전법으로 제조된 루틸상 TiO2분말의 분산 안정성)

  • 배현숙;박순동;김흥희;이창규;김선재
    • Journal of the Korean Ceramic Society
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    • v.39 no.1
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    • pp.38-44
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    • 2002
  • Dispersion stability of nano-sized rutile TiO$_2$powder with acicular typed primary particle produced by homogeneous precipitation process at low temperatures was studied in aqueous and non-aqueous media in the presence of various electrolytes. The zeta potential measurements have shown that the addition of electrolytes to aqueous and non-aqueous dispersion media leads to charge reversal on TiO$_2$particle surface. The electrostatic repulsive forces acting on between TiO$_2$particles dispersed in non-aqueous media were found to be significantly greater than that in aqueous media, which relate closely to the physical properties of the organic solvents, such as viscosities and dielectric constants. The pH values, the concentration of electrolytes and the valence of the ions have changed greatly the surface potential of TiO$_2$ particles and have governed the dispersion behavior of TiO$_2$particles virtually.

Hydration Properties of High Volume Cement Matrix Using Blast Furnace Slag and Alkaline Aqueous by Electrolysis (고로슬래그 및 전기분해한 알칼리 수용액을 사용한 하이볼륨 시멘트 경화체의 수화특성)

  • Kim, Sun-A;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.1
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    • pp.8-13
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    • 2017
  • This experimental study is purposed to analyze the effect of alkaline aqueous solution by electrolysis on strength development in order to develop high volume cement matrix using industrial by-products. Blast furnace slag was used a binder, and an alkaline aqueous solution obtained by electrolyzing pure water was used as an alkali activator. The hydration properties of these specimens were then investigated by compressive strength test, XRD and observation of micro-structures using SEM. As a result, we found that compressive strength increased with the addition of alkaline aqueous solution which cement matrix incorporating blast furnace slag. But those strength decreased reversely when replacing ratio of blast furnace slag was increased. It is judged that results of engineering properties evaluation on the binder and alkaline aqueous solution are useful as a basic data for mixtures design and evaluation properties of high volume cement matrix using by-products.

Combined Aqueous Ammonia-Dilute Sulfuric Acid Pretreatment of Miscanthus for Bioethanol Production (바이오에탄올 제조를 위한 억새의 암모니아-희황산 복합 전처리)

  • Bark, Surn-Teh;Koo, Bon-Cheol;Choi, Yong-Hwan;Moon, Youn-Ho;Ahn, Seung-Hyun;Cha, Young-Lok;Kim, Jung Kon;An, Gi Hong;Suh, Sae-Jung;Park, Don-Hee
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.179.1-179.1
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    • 2011
  • Pretreatment of cellulosic biomass is necessary before enzymatic saccharification and fermentation. The objective of this study was to evaluate the effect of combined aqueous ammonia-dilute sulfuric acid treatment on cellulosic biomass. Miscanthus was pretreated using aqueous ammonia and dilute sulfuric acid solution under high temperature and pressure conditions to be converted into bioethanol. Aqueous ammonia treatment was performed with 15 %(w/w) ammonia solution at $150^{\circ}C$ of reaction temperature and 20 minutes of reaction time. And then, dilute sulfuric acid treatment was performed with 1.0 %(w/w) sulfuric acid solution at $150^{\circ}C$ of reaction temperature and 10 minutes of reaction time. The compositional variations of this combined aqueous ammonia-dilute sulfuric acid treatment resulted in 68.0 % of cellulose recovery and 95.7 % of hemicellulose, 81.3 % of lignin, 89.1 % of ash removal respectively. The enzymatic digestibility of 90.5 % was recorded in the combined pretreated Miscanthus sample and it was 14.7 times higher than the untreated sample. The ethanol yield in the Simultaneous Saccharification and Fermentation was 90.4 % of maximum theoretical yield based on cellulose content of the combined pretreated sample and it was about 98 % compared to the ${\alpha}$-cellulose ethanol yield.

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Concentration and Environmental Loading of Veterinary Antibiotics in Agricultural Irrigation Ditches

  • Kim, Sung-Chul;Chung, Doug Young;Kim, Kye Hoon;Lee, Ja Hyun;Kim, Hyo Kyung;Yang, Jae E.;Ok, Yong Sik;Almarwei, Yaser A.O.
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.867-876
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    • 2012
  • The concentration of veterinary antibiotics in aqueous and sediment matrices was measured in agricultural irrigation ditches bordering several animal-feeding operations (AFOs) and then compared to its concentration in the watershed. Analytical determination in aqueous samples was based on solid phase extraction (SPE) and appropriate buffer solutions were used to extract residuals in sediment samples. Separation and detection of extracted veterinary antibiotics were performed with high performance liquid chromatograph tandem mass spectrometry (HPLC/MS/MS). In general, higher concentrations of antibiotic were observed in the aqueous phase of irrigation ditches, with the highest concentration of erythromycin hydrochloride (ETM-$H_2O$) of $0.53{\mu}g\;L^{-1}$, than in aqueous watershed samples. In contrast, higher concentrations were measured in river sediment than in irrigation ditch sediment with the highest concentration of oxytetracycline of $110.9{\mu}g\;kg^{-1}$. There was a high calculated correlation ( > 0.95) between precipitation and measured concentration in aqueous samples from the irrigation ditches for five of the ten targeted veterinary antibiotics, indicating that surface runoff could be an important transport mechanism of veterinary antibiotics from field to environment. Further, environmental loading calculation based on measured concentrations in aqueous samples and flow information clearly showed that irrigation ditches were 18 times greater than river. This result suggests the likelihood that veterinary antibiotics can be transported via irrigation ditches to the watershed. The transport via surface runoff and likely environmental loading via irrigation ditches examined in this study helps identify the pathway of veterinary antibiotics residuals in the environment.

Absorption Characteristics of Aqueous Sodium Glycinate Solution with Carbon Dioxide and Its Mechanistic Analysis (Sodium Glycinate 수용액의 CO$_2$ 흡수특성 및 반응 메커니즘 해석)

  • Shim, Jae-Goo;Kim, Jun-Han;Jang, Kyung-Ryong
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.4
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    • pp.430-438
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    • 2008
  • The experiments for separation and recovery of CO$_2$ were conducted by aqueous sodium glycinate solution, which is one of the amino acid salts, as an absorbent of CO$_2$ in this study. Absorption capacities of aqueous MEA and sodium glycinate solution according to partial pressure of CO$_2$ were evaluated by vapor-liquid equilibrium tests of 20 wt% and 30 wt% above-mentioned absorbents, respectively. In addition, the pilot scale(2 t-CO$_2$/day) experiments based on prior results were carried out. As a result, CO$_2$ removal efficiency of aqueous sodium glycinate solution was lower than that of aqueous MEA solution. This phenomenon means that CO$_2$ removal efficiency of aqueous sodium glycinate solution mainly depends on its molecular structure. Consequently, the first application of certain amino acid salt, as an absorbent of CO$_2$, to pilot plant of 2 t-CO$_2$/day scale was carried out in our country.