• Title/Summary/Keyword: Anti-Porosity

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Methodological approach of evaluation on prefabrication primers for steel structures

  • Chung, Sung-Wook;Hyun, Jeong-Hun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.13 no.1
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    • pp.707-717
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    • 2021
  • To the date, shipbuilding companies have applied shop primer coating which protects the steel surface from global oxidization in environment. Proper shop primer requires either anti-corrosion ability during construction or anti-porosity ability during welding, and those properties contradict to each other. This report tried to derive an optimizing parameter on these conflicting properties to select a proper shop primer. First, sufficient amounts of the natural salt spray tests were carried out to achieve a series of data for the anti-corrosion ability. Second, lots of T-joint fillet welding test were performed to evaluate the trapped porosity formed in the weld pool. According to the experimental data, we could achieve either the rust-formation rate or the porosity-formation rate, then, each rate was generalized as formulae. Then, we tried to combine these conflicting properties to decide an optimum shop primer.

Minimization of Porosity in Ceramic Coating on a Hydraulic Cylinder (유압실린더 세라믹코팅 기공률 최소화 방안)

  • Jung, Youngho;Moon, Seung-Jae;Yoo, Hoseon
    • Plant Journal
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    • v.6 no.4
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    • pp.63-71
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    • 2010
  • The best way to prevent the corrosion of piston rod is a selection of quality of the material and method of construction which minimize the porosity. The high velocity oxy fuel(HVOF) method, which generates lower porosity than existing plasma spray, was applied to ceramic laminated bond layer. Porosity percentage fell to bellow 2%, lower than that of plasma spray at 7%. Coating material of ceramic-coated main layer was selected as the $Cr_2O_3$ affiliation material, which is more dense than $Al_2O_3$ affiliation. To fill up the pores formed after the coating process, we sealed the bond layer and main layer. Sealing process was performed twice, once after the coating and once after the grinding. Upon the anti-corrosion test on the sealed sample and on the non-sealed sample, it is confirmed that the sealed sample was not corroded for 1,000 hours while the non-sealed sample was corroded within 48 hours.

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Fabrication of porous titanium oxide-manganese oxide ceramics with enhanced anti-static and mechanical properties (우수한 대전방지 및 기계적 성질을 가지는 다공성 산화티탄-산화망간 세라믹스 제조)

  • Yu, Dongsu;Hwang, Kwang-Taek;Kim, Jong-Young;Jung, Jong-Yeol;Baik, Seung-Woo;Shim, Wooyoung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.6
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    • pp.263-270
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    • 2018
  • Recently, porous ceramic materials with anti-static performance are urgently needed for semiconductor and OLED/LCD display manufacturing industry. In this work, we fabricated porous titanium manganese oxide ceramics having the surface resistivity of $10^8-10^{10}$ ohm and enhanced mechanical strength by partial sintering method using nanosized titanium oxide. By addition of nano-sized titanium oxide in the matrix, neck formation between grains was strengthened, which remarkably increased flexural strength up to 170 MPa (@porosity: 15 %), 110 MPa (@porosity: 31 %), compared to 80 MPa (@porosity: 26 %) for pristine titanium manganese oxide ceramics. We evaluated the performances of our ceramics as air-floating module for OLED flexible display manufacturing devices.

Evaluation of anti-viral efficiency of TiO2 coated air filter for airborn virus (공간 내 부유한 바이러스에 대한 광촉매 TiO2가 코팅된 에어 필터의 항바이러스 효율 평가)

  • Park, Geunyoung;Park, Sungjae;Koo, Hyun-Bon;Kim, Seongjun;Hwang, Jungho
    • Particle and aerosol research
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    • v.15 no.4
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    • pp.173-182
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    • 2019
  • Since airborne viruses have been known to aggravate indoor air quality, studies on the development of anti-viral air filter increase recently. In this study, the pressure drop and anti-viral efficiency of TiO2 coated ceramic ball filter were evaluated. After the filter being inserted into a commercial room air cleaner, chamber test with aerosolized bacteriophage MS2 was performed. The porosity of TiO2 coated ceramic ball filter was 0.85, and pressure drop was about 13 Pa for 1 m/s of air velocity. The anti-viral efficiency was about 93% when the reaction time was 25 minutes in a 1 ㎥ chamber.

Anti-slosh effect of a horizontal porous baffle in a swaying/rolling rectangular tank: Analytical and experimental approaches

  • George, Arun;Cho, Il-Hyoung
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.13 no.1
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    • pp.833-847
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    • 2021
  • The horizontal porous baffle and its effect as an anti-slosh device have been investigated intensively in a swaying and rolling rectangular tank. To accurately assess the level at which porous baffles reduce liquid sloshing, the Matched Eigenfunction Expansion Method (MEEM) has been utilized as an analytical tool. The velocity potentials in the horizontal baffle-covered fluid region are expressed by the sum of the homogeneous and particular solutions to avoid solving the complex dispersion equation. By applying an equivalent linearized quadratic loss model, the nonlinear algebraic equation is derived and solved by implementing the Newton-Raphson iterative scheme. To prove the validity of the present theoretical model, a series of experiments have been conducted with different centered horizontal porous baffles with varying porosities and submerged depths in a swaying and rolling rectangular tank. Reasonably good agreements are obtained regarding the analytical solutions and the experiment's findings. The influence of porosity, submerged depth, and length of a centered horizontal porous baffle on anti-slosh performance have been analyzed, especially at resonance modes. The developed predictive tool can potentially provide guidelines for optimal design of the horizontal porous baffle.

Fabrication and separation performance of polyethersulfone/sulfonated TiO2 (PES-STiO2) ultrafiltration membranes for fouling mitigation

  • Ayyaru, Sivasankaran;Ahn, Young-Ho
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.199-209
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    • 2018
  • Polyethersulfone (PES)/sulfonated $TiO_2$ ($STiO_2$) nanoparticles (NPs) UF blended membranes were fabricated with different loadings of $STiO_2$. The modified membranes exhibited significant improvement in surface roughness, porosity, and pore size when compared to the PES membrane. The $P-STiO_2$ 1 and $P-TiO_2$ 1 blended membranes exhibited higher water flux, approximately 102.4% and 62.6%, respectively, compared to PES. SPP-$STiO_2$ and $P-STiO_2$ showed lower Rir fouling resistance than the $P-TiO_2$ blended membrane. Overall, the $STiO_2$-blended membranes provide high hydrophilicity permeability, anti-fouling performance, and improved BSA rejection attributed to the hydrogen bonding force and more electrostatic repulsion properties of $STiO_2$.

Development of Macro-Porous Silicon Based Dye-Sensitized Solar Cells with Improved Light Trapping

  • Aliaghayee, Mehdi;Fard, Hassan Ghafoori;Zandi, Ashkan
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.218-227
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    • 2016
  • The light harvesting efficiency is counted as an important factor in the power conversion efficiency of DSSCs. There are two measures to improve this parameter, including enhancing the dye-loading capacity and increasing the light trapping in the photoanode structure. In this paper, these tasks are addressed by introducing a macro-porous silicon (PSi) substrate as photoanode. The effects of the novel photoanode structure on the DSSC performance have been investigated by using energy dispersive X-ray spectroscopy, photocurrent-voltage, UV-visible spectroscopy, reflectance spectroscopy, and electrochemical impedance spectroscopy measurements. The results indicated that bigger porosity percentage of the PSi structure improved the both anti-reflective/light-trapping and dye-loading capacity properties. PSi based DSSCs own higher power conversion efficiency due to its remarkable higher photocurrent, open circuit voltage, and fill factor. Percent porosity of 64%, PSi(III), resulted in nearly 50 percent increment in power conversion efficiency compared with conventional DSSC. This paper showed that PSi can be a good candidate for the improvement of light harvesting efficiency in DSSCs. Furthermore, this study can be considered a valuable reference for more investigations in the design of multifunctional devices which will profit from integrated on-chip solar power.

Effectiveness study of a cement mortar coating based on dune sand on the carbonation of concrete

  • Korichi, Youssef;Merah, Ahmed;Khenfer, Med Mouldi;Krobba, Benharzallah
    • Advances in concrete construction
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    • v.13 no.4
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    • pp.315-325
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    • 2022
  • Reinforced concrete structures are exposed throughout their lifetime to the phenomenon of carbonation, which considerably influences their durability by causing corrosion of the reinforcements. The fight against this phenomenon is usually ensured by anti-carbonation coatings which have the possibility of limiting the permeability to carbon dioxide or with coatings which absorb the CO2 present in the air. A coating with good crack-bridging (sealing) capacity will prevent water from entering through existing cracks in concrete. Despite the beneficial effect of these coatings, their durability decreases considerably over time with temperature and humidity. In order to use coatings made from local materials, not presenting any danger, available in abundance in our country, very economical and easy to operate is the main objective of this work. This paper aim is to contribute to the formulation of a corrected dune sand-based mortar as an anti-carbonation coating for concrete. The results obtained show that the cement mortar based on dune sand formulated has a very satisfactory compressive strength, a very low water porosity compared to ordinary cement mortar and that this mortar allows an improvement in the protection of the concrete against the carbonation of 60% compared to ordinary cement mortar based on alluvial sand. Moreover, the formulated cement mortars based on dune sand have good adhesion to the concrete support, their adhesion strengths are greater than 1.5MPa recommended by the standards.

Anti Corrosive Performance of Al and Zn Coatings Deposited by Plasma Arc Thermal Spray Process in Artificial Ocean Water (인공해양환경에서 플라즈마 아크 용사 공법이 적용된 Al 및 Zn 코팅의 부식 방지 성능 평가)

  • Adnin, Raihana Jannat;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.52-53
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    • 2020
  • The thermal spray coating process is being used to protect the metals and alloys from wear, abrasion, fatigue, tribology, and corrosion failure. Therefore, in the present study, Al and Zn was deposited by plasma arc thermal spray process onto the steel substrate and their performance was assessed. The bond adhesion result shows that Al coating has higher value attributed to compact, dense, and less porous compared to Zn coating which contain defects/pores and uneven morphology assessed by scanning electron microscopy (SEM). Electrochemical results show that the Al coating exhibited higher impedance value compared to Zn in artificial ocean water solution at prolonged exposure periods. However, both coatings show the increment in polarization resistance with exposure periods which reveal that porosity of coatings is filled by the corrosion products.

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Influence of Oxidation Inhibitor on Carbon-Carbon Composites: 5. Studies on Anti-oxidation Properties of the Composites (산화억제제 첨가에 의한 탄소/탄소 복합재료의 물성에 관한 연구: 5. 탄소/탄소 복합재료의 내산화성 연구)

  • 박수진;서민강;조민석;이재락
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.237-244
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    • 2000
  • Phenolic resin used as a precursor of carbonized matrix for carbon-carbon composites was modified by addition of molybdenum disilicide (MoSi$_2$) in various concentrations of 0, 4, 12 and 20% by weight to improve the anti-oxidation properties of the composites. The green body was manufactured by a prepreg method and was submitted to carbonization up to 110$0^{\circ}C$. In this work, the oxidation behavior of carbon-carbon composites with MoSi$_2$ as an oxidation inhibitor was investigated at the temperature range of 600-100$0^{\circ}C$ in an air environment. The carbon-carbon composites with MoSi$_2$ showed a significantly improved oxidation resistance due to both the reduction of the porosity formation and the formation of mobile diffusion barrier for oxygen when compared to those without MoSi$_2$. Carbon active sites should be blocked, decreasing the oxidation rate of carbon. This is probably due to the effect of the inherent MoSi$_2$ properties, resulted from a formation of the protective layer against oxygen attack in the composites studied.

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