• Bulletin of the Korean Chemical Society
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• 제30권11호
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• pp.2827-2829
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• 2009

• 한국태양에너지학회 논문집
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• 제37권3호
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• pp.13-22
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• 2017

Anti-islanding scheme of grid-connected inverter is a key function of standards compliance, since unintentional islanding results in safety hazards, reliability, and many other issues. Therefore, many anti-islanding schemes have been researched, however, most of them have problems, which deteriorate performance of islanding detection under parallel-operation. Therefore, this paper proves the reason of problems and proposes a new anti-islanding scheme that has precise islanding detection under parallel-operation in single-phase and three-phase system. Finally, both simulation and experimental result validate the proposed scheme.

• Bulletin of the Korean Chemical Society
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• 제24권7호
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• pp.975-980
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• 2003

The electrochemical properties and the mechanism of formation of anodic oxide films on Mg alloys containing 0-15 mass% Al, when anodized in NaOH solution, were investigated by focusing on the effects of anodizing potential, Al content, and anodizing time. The intensity ratio of Mg(OH)₂ in the XRD analysis decreased with increasing applied potential, while that of MgO increased. Mg(OH)₂ was barely detected at 80 V, while MgO was readily detected. The anti-corrosion properties of anodized specimens at each constant potential were better than those of non-anodized specimens. The specimen anodized at an applied potential of 3 V had the best anti-corrosion property. The intensity ratio of the β phase increased with aluminum content in Mg-Al alloys. During anodizing, the active dissolution reaction occurred preferentially in β phase until about 4 min, and then the current density increased gradually until 7 min. The dissolution reaction progressed in α phase, which had a lower Al content. In the anodic polarization test in 0.017 mol·$dm^{-3}$ NaCl and 0.1 mol·$dm^{-3}$ Na₂SO₄ at 298 K, the current density of Mg-15 mass% Al alloy anodized for 10 min increased, since the anodic film that forms on the α phase is a non-compacted film. The anodic film on the α phase at 30 min was a compact film as compared with that at 10 min.

• Bulletin of the Korean Chemical Society
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• 제34권11호
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• pp.3444-3450
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• 2013

Three phase hollow fiber-liquid phase microextraction (HF-LPME), which is faster, simpler and uses a more environmentally friendly sample-preparation technique, was developed for the analysis of Non-Steroidal Anti-Inflammatory Drugs (NSAIDs) in human urine. For the effective simultaneous extraction/concentration of NSAIDs by three phase HF-LPME, parameters (such as extraction organic solvent, pH of donor/acceptor phase, stirring speed, salting-out effect, sample temperature, and extraction time) which influence the extraction efficiency were optimized. NSAIDs were extracted and concentrated from 4 mL of aqueous solution at pH 3 (donor phase) into dihexyl ether immobilized in the wall pores of a porous hollow fiber, and then extracted into the acceptor phase at pH 13 located in the lumen of the hollow fiber. After the extraction, 5 ${\mu}L$ of the acceptor phase was directly injected into the HPLC/UV system. Simultaneous chromatographic separation of seven NSAIDs was achieved on an Eclipse XDB-C18 (4.6 mm i.d. ${\times}$ 150 mm length, 5 ${\mu}m$ particle size) column using isocratic elution with 0.1% formic acid and methanol (30:70) at a HPLC-UV/Vis system. Under optimized conditions (extraction solvent, dihexyl ether; $pH_{donor}$, 3; $pH_{acceptor}$, 13; stirring speed, 1500 rpm; NaCl salt, 10%; sample temperature, $60^{\circ}C$; and extraction time, 45 min), enrichment factors (EF) were between 59 and 260. The limit of detection (LOD) and limit of quantitation (LOQ) in the spiked urine matrix were in the concentration range of 5-15 ng/mL and 15-45 ng/mL, respectively. The relative recovery and precision obtained were between 58 and 136% and below 15.7% RSD, respectively. The calibration curve was linear within the range of 0.015-0.96 ng/mL with the square of the correlation coefficient being more than 0.997. The established method can be used to analyse of NSAIDs of low concentration (ng/mL) in urine.

• Biomolecules & Therapeutics
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• 제20권2호
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• pp.144-151
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• 2012

The molecular mechanisms by which a variety of naturally-occurring dietary compounds exert chemopreventive effects have been a subject of intense scientific investigations. Induction of phase II detoxification and anti-oxidant enzymes through activation of Nrf2/ARE-dependent gene is recognized as one of the major cellular defense mechanisms against oxidative or xenobiotic stresses and currently represents a critical chemopreventive mechanism of action. In the present review, the functional significance of Keap1/Nrf2 protein module in regulating ARE-dependent phase II detoxification and anti-oxidant gene expression is discussed. The biochemical mechanisms underlying the phosphorylation and expression of Keap1/Nrf2 proteins that are controlled by the intracellular signaling kinases and ubiquitin-mediated E3 ligase system as well as control of nucleocytoplasmic translocation of Nrf2 by its innate nuclear export signal (NES) are described.

• 반도체디스플레이기술학회지
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• 제14권4호
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• pp.72-77
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• 2015

Three-level diode clamped multilevel inverter, generally known as neutral point clamped (NPC) inverter, has an inherent problem causing neutral point (NP) potential variation. Until now, the NP potential problem of variation has been investigated and lots of solutions have also been proposed. This paper presents a neutral point voltage control technology using the anti-windup PI controller and offset technology of PWM (Pulse Width Modulation) to control the variation of NPC 3-phase three-level inverter neutral point voltage. And the proposed algorithm is tested and verified using a PLL (Phase Locked Loop) in order to synchronize the phase voltage from the line voltage of grid. It significantly improves the voltage balancing under a solar fluctuation conditions of the inverter. Experimental results show the good performance and effectiveness of the proposed method.

• 제어로봇시스템학회논문지
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• 제7권11호
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• pp.891-895
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• 2001

An alternative inverse feedback structure for adaptive active control of periodic noise is introduced for systems with nonminimum phase cancellation path. To obtain the inverse model of the nonminimum phase cancellation path, the cancellation path model can be factorized into a minimum phase term and a maximum phase term. The maximum phase term containing unstable zeros makes the inverse model unstable. To avoid the instability, we alter the inverse model of the maximum phase system into an anti-causal FIR one. An LMS predictor estimates the future samples of the noise, which are necessary for causality of both anti-causal FIR approximation for the stable inverse of the maximum phase system and time-delay existing in the cancellation path. The proposed method has a faster convergence behavior and a better transient response than the conventional filtered-x LMS algorithms with the same internal model control structure since a filtered reference signal is not required. We compare the proposed methods with the conventional methods through simulation studies.

• 한국산학기술학회논문지
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• 제7권6호
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• pp.1086-1091
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• 2006

본 논문에서는 정상분을 추출하여 이용하는 기존의 PLL 방식을 무정전전원장치에 적합한 형태로 개선한 PLL 방식을 제안하였다. 제안된 PLL 방식은 기존의 PI 제어기에 주파수 제한기(limiter)와 안티 와인드업(anti-windup)을 추가하였다. 이것의 기본적인 동작 원리는 기존의 방법들과 같지만, 차이점은 주파수 제한기의 삽입으로 인하여 주파수 변동률을 일정한 범위 내에서 제한할 수 있다는 것이다. 기존의 PLL 방법과 제안된 주파수를 제한한 PLL 방법의 차이를 알아보기 위하여 동적 전압 보상기로 전압을 보상하는 컴퓨터 시뮬레이션을 하였고, 결과적으로 제안된 주파수를 제한한 PLL 방법이 무정전전원장치에 적합함을 입증하였다.

• Natural Product Sciences
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• 제21권1호
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• pp.30-33
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• 2015

Anthocyanins are water soluble plant pigments which are responsible for the blue, red, pink, violet colors in several plant organs such as flowers, fruits, leaves and roots. In recent years, anthocyanin-rich foods have been favored as dietary supplements and health care products due to diverse biological activities of anthocyanins including antioxidant, anti-allergic, anti-diabetic, anti-microbial, anti-cancer and preventing cardiovascular disease. High-performance countercurrent chromatography (HPCCC) coupled with reversed-phase medium pressure liquid chromatography (RP MPLC) method was applied for the rapid and efficient isolation of cyanidin 3-glucoside (C3G) and peonidin 3-glucoside (P3G) from black rice (Oryza sativa L., Poaceae). The crude black rice extract (500 mg) was subjected to HPCCC using two-phase solvent system composed of tert-butyl methyl ether/n-butanol/ acetonitrile/0.01% trifluoroacetic acid (TBME/B/A/0.01% TFA, 1 : 3 : 1 : 5, v/v, flow rate - 4.5 mL/min, reversed phase mode) to give enriched anthocyanin extract (37.4 mg), and enriched anthocyanin extract was sequentially chromatographed on RP-MPLC to yield C3G (16.5 mg) and P3G (8.7 mg). The recovery rate and purity of isolated C3G were 76.0% and 98.2%, respectively, and those of P3G were 58.3% and 96.3%, respectively. The present study indicates that HPCCC coupled with RP-MPLC method is more rapid and efficient than multi-step conventional column chromatography for the separation of anthocyanins.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2006년도 제37회 하계학술대회 논문집 B
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• pp.1153-1154
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• 2006

This paper proposes the optimal design method based on NDZ analysis to secure the islanding defection ability and to maintain the stability and power quality when the grid is connected. A PSiM-based model and analysis of the system is presented, specialty aimed at improving the effectiveness of phase shift anti-islanding method with frequency feedback, which causes the inverter current to be generated slightly lower or higher in frequency than the frequency of the terminal voltage. The proposed method can cause frequency jump with leading and lagging phase of output current in two line cycles. As a result, the proposed algorithm is more sensitive and reliable than the conventional phase shift method. Experimental results, on a 3 kW inverter connected to 220 V, 60 Hz utility, are discussed.