• Title/Summary/Keyword: Anthracite ash

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Utilization of Waste and Industrial Byproducts as a Raw Material in the Manufacture of Portland Cement (시멘트 원료로서 폐.부산자원의 활용)

  • 최상흘;박용완;지정식;오희갑
    • Journal of the Korean Ceramic Society
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    • v.15 no.3
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    • pp.149-156
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    • 1978
  • The utilization of waste and industrial byproduct materials, such as blast furnace slag, shales, poor coal and anthracite briquet ash, were investigated as a source of calcareous or argillaceous material in the manufacture of Portland cement. As a slag is similar to cement in chemical compoment and contains about 40∼50% of CaO, it's utilization in cement manufacture should be suitable. The burnability was increased and the heat of clinker formation was decreased by using slag. Some consideration should betaken in the use of large quantity because of sticking in suspension preheater kiln. Suitable quantities of colliery shales and poor coal should be useable in cement manufacture as a argillaceous materials and also its combustible materials should be utilized in cement manufacture. Anthracite briquet ash is also usable as a argillaceous source and it gives good burnability.

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Agglomeration of fine anthracite using oil and modified styrene (Oil과 Modified Styrene을 사용(使用)한 미립(微粒) 무연탄(無煙炭)의 응집(凝集))

  • Lee, Jae-Jang;Jang, Dong-Sung
    • Journal of Industrial Technology
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    • v.7
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    • pp.27-47
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    • 1987
  • Fine anthracite is very difficult to upgrade by conventional processes such as gravity concentration or froth flotation, because large quantities of fine coals are generated at the mining and preparation stages and a significant portion of these fine coals are mixed with gangue minerals. This study, therefore, was carried out for the purpose of improving recovery of low ash clean coal, effective beneficiation of low-grade coking coal and removal of sulphur from high-sulphur coals by employing the method of selective agglomeration using oil or polystrene flocculants, for coals which are generally hydrophobic in nature will be extracted by using flocculants. Studies were performed by varying solid concentration, concetration of bridging liquid, mixing speed and mixing time, balling speed and balling time, dispersant dosage, flocculant dosage, pulp pH, and particle size. The results were : when the methods of the oil agglomeration and selective flocculation were employ(in the two process the sample was ground to the size of -74 micron), 1) ash content of the agglomerated coal was 9.85, 7.83%, 2) combustibel recovery of it was 98.5%, 93.5%, respectively. It was observed in selective flocculation that polystyrene is an effective flocculant for coal, De-entrapment of shale from the concentrate flocculated by mechanical agitation was necessary for substantional reductions in final ash content.

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Co-combustion Characteristics of Mixed Coal with Anthracite and Bituminous in a Circulating Fluidized Bed Boiler (순환유동층 보일러에서 무연탄-유연탄의 혼합연소 특성)

  • Jeong, Eui-Dae;Moon, Seung-Jae
    • Plant Journal
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    • v.6 no.2
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    • pp.70-77
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    • 2010
  • This study investigated the characteristics of co-combustion of mixed anthracite (domestic and Vietnam) and bituminous coal (Sonoma, Australia) at circulating fluidized bed boiler in Donghae thermal power plant when mixing ratio of bituminous coal is variable. Co-combustion of bituminous coal contributes to improvement in general combustion characteristics such as moderately retaining temperature of furnace and recycle loop, reducing unburned carbon powder, and reducing discharge concentration of NOx and limestone supply owing to improvement in anthracite combustibility as the mixing ratio was increased. However, bed materials were needed to be added externally when the mixing ratio exceeded 40% because of reduction in generating bed materials based on reduction in ash production. When co-combustion was conducted in the section of 40 to 60% in the mixing ratio while the supplied particles of bituminous coal was increased from 6 mm to 10 mm, continuous operation was shown to be possible with upper differential pressure of 100 mmH2O (0.98 kPa) and more without addition of bed materials for the co-combustion of mixed anthracite and bituminous coal (to 50% or less of the ratio) and that of domestic coal and bituminous coal (to 60% of the ratio).

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A Study on the Engineering Characteristics of Power Plant Coal Ash (화력발전소 부산물인 석탄회의 공학적 특성에 관한 연구)

  • Kuk, Kilkeun;Kim, Hyeyang;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.5
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    • pp.25-34
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    • 2010
  • In this study characteristics for reclaimed ash was studied to enlarge the usage of reclaimed ash which is reaching to 72 million ton producted from whole thermal power plants in South Korea. Fly ash and bottom ash are reclaimed separately at some of thermal power plants. However, typically bottom ash and fly ash are mixed when they are buried at most of the thermal power plant, as a result the engineering characteristics of ponded ash are not investigated properly. In order to investigate the engineering characteristics of the ponded ash, laboratory tests were performed with ponded ash and fly ash from youngheung and samcheonpo thermal power plants. Specific gravity, unit weight, and grain size analysis test were fulfilled to evaluate the physical characteristics and triaxial permeability test, direct shear test, unconfined compressive strength test, compaction test were performed to evaluate the mechanical characteristics. And also engineering characteristics of coal ash from anthracite and Bituminous thermal power plants were compared and studied respectively. As a result of the study, it was confirmed that using coal ash from Bituminous thermal power plants can be effective in the place where lightweight materials are required and using coal ash from anthracite thermal power plants can be effective as backfill material which require higher permeability. Finally, it was confirmed that fly ash from youngheung thermal power plants which has the lowest permeability among the tested material is suitable for a field requiring impermeable material.

Effect of Fly ash Application on the Yield of Rice and Silicate Availability in Paddy Soil (Fly ash 시용(施用)이 수도(水稻)의 수량(收量)과 논 토양(土壤)의 유효규산(有效珪酸) 함량(含量)에 미치는 영향(影響))

  • Kim, Yong-Woong;Yun, Chong-Hee;Kim, Kwang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.4
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    • pp.275-283
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    • 1994
  • The effects of anthracite and bituminous fly ash application on rice yield were investigated and the available silicate in paddy soil with ash application was analyzed. The obtained results are as follow : The yield of rice gradually decreased as the amount of anthracite ash increased. On the contrary, the rice yield gradually increased as the amount of bituminous ash increased. At harvesting stage the chemical properties in soil such as pH, organic content, and inorganic content($P_2O_5$, K. Ca, Mg and available $SiO_2$) were higher in bituminous ash treated soil than in anthracite treated soil. The amount of inorganic components in rice plant such as T-N, $P_2O_5$, $K_2O$, CaO, and MgO gradually decreased with the growing stage of rice. However, the amount of available silicate increased with the growing stage of rice. The silicate content in soil was determined by two different methods ; 1N-NaOAc extracted method and submerging setting method. In bituminous ash treated soil, the correlation between the silicate content in plant and in soil was found when the silicate content in soil was determined by the soil submerging method. In anthracite ash treated soil, however no correlation was found between the silicate content in plant and in soil determined by either method.

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Physical and Mechanical Efficiency of Plowable Fill Applied Bottom Ash(Anthracite Coal) (Bottom-ash(무연탄)를 적용한 고유동 충전재의 물리$\cdot$역학적 성능 비교)

  • 김성수;김동현;박광필
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.263-268
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    • 2001
  • In this study, the physical and mechanical characteristics of Bottom-ash exhausted from each of steam power plant was considered. The comparative objects were Bottom-ash in which a lot of powder contained and that in which less than that relatively contained. The difference in quantity of powder showed different effect on the character of flow. This study was undertaken on the use of Bottom-ash as a fine aggregate, and showed the optimum mixing and the character of flow according to each rate. And this study showed the quantity of water and binder added in different Bottom-ash was differently used.

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A Study of Co-Combustion Characteristics of North Korean Anthracite and Bituminous Coal in 2 MWe CFBC Power Plant (2 MWe 순환유동층 발전 플랜트에서 유연탄과 북한 무연탄 혼소시험 특성 연구)

  • Han, Keun-hee;Hyun, Ju-soo;Choi, Won-kil;Lee, Jong-seop
    • Korean Chemical Engineering Research
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    • v.47 no.5
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    • pp.580-586
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    • 2009
  • In this study, co-combustion characteristics of Chinese bituminous coal and North Korean anthracite were investigated using a 2 MWe scale circulating fluidized bed power plant. At first, the combustion efficiency of bituminous coal of China and Australia as a function of excess air ratio and temperature were observed. The results showed that the combustion efficiency was influenced by particle size and volatile content of coal, the combustion efficiency of Chinese bituminous coal was over 99.5%. The unburned carbon particles from fly ash and bottom ash were a content 5~7% and 0.3%, respectively. The combustion efficiency with the mixture ratio 20% of bituminous coal and anthracite decreased over 5% because of the increase of entrained particles by a small average particle size of anthracite in the combustor. However, the outlet concentration of $SO_2$ and $NO_x$ was not changed remarkably. The concentrations of the typical air pollutants such as $NO_x$ and $SO_2$ were 200~250 ppm($O_2$ 6%), 100~320 ppm($O_2$ 6%) respectively. The outlet concentration of $NO_x$ was decreased to 30~65% with $NH_3$ supplying rate of 2~13 l/min in SCR process. The $SO_x$ removal efficiency was up to 70% by in-furnace desulfurization using limestone with Ca/S molar of approximately 6.5. With wet scrubbing using $Mg(OH)_2$ as absorbent, the $SO_x$ removal efficiency reached 100% under near pH 5.0 of scrubbing liquid.

The influence of factors on the strength of formed coke made with anthracite and phenolic resin (무연탄(無煙炭)과 페놀수지(樹脂)의 혼합(混合)소성에 의해 제조(製造)된 함형(咸形)코크스의 강도(强度))

  • Lee, Gye-Seung;Song, Young-Jun
    • Resources Recycling
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    • v.17 no.6
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    • pp.57-61
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    • 2008
  • The aim of this study is to produce the coke which can be used for the production of ferroalloy, by mixing phenolic resin and anthracite and sintering it. The influence of factors on the strength of coke were investigated. The results of this study are as follows: It is found that the anthracite coke of $100{\sim}150\;kgf/cm^2$ strength for ferroalloy can be made by a series of process as follows; Mixing homogeneously 6% liquefied phenolic resin and 6% water with $35{\sim}325$ mesh anthracite of low ash content. Making pellet by press the mixture in $10-50\;kgf/cm^2$ pressure. Dehydrating the pellet for 6 hrs at $50^{\circ}C$, and hardening it for 180 min at $200^{\circ}C$. Sinter the mixture for 6 hrs at $1,200^{\circ}C$.

A Study of Chemical Properties and Fusibility of Korean Anthracite Coal Ash (국내 무연탄회의 화학조성 및 용융특성에 관한 연구)

  • Park, Cheol-Woo;Lee, See-Hoon;Shon, Eung-Kwon
    • Analytical Science and Technology
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    • v.5 no.4
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    • pp.433-441
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    • 1992
  • Chemical composition and fusibility of coal ash were measured for 23 Korean anthracite coals. The relationship between chemical properties and fusion temperature of coal ash was investigated. The slagging and fouling in firing the pulverized coal for boiler was assessed for the coal samples. It was found that most ashes contained more than 80% of $SiO_2$ and $Al_2O_3$ whereas less than 1% of $Na_2O$. And also fusion temperature of ashes occured relatively higher for Korean coals. Therefore it can be predictable that the slagging and fouling formation has a little problem in a pulverized coal firing system. A base/acid ratio did show a good correlation with fusion temperature for these coal ashes.

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A Study of Desulfation Characteristics of Circulating Fluidized Bed Combustion for Domestic Anthracite (국내 무연탄의 순환류동층 보일러에서 탈황 특성 연구)

  • 정진도;김장우;하준호
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.4
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    • pp.429-436
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    • 2004
  • Circulating fluidized bed combustion (hereafter CFBC) technology enables an efficient combustion for the materials with low heating values such as high ash coal and sludges. It also has desulfation function by adding limestone directly to combustor. The CFBC has been considered as one of the best processes for low grade coal containing with large contents of ash and sulfur. In this paper, in order to various tests were performed to find the optimum desulfation condition for CFBC using Korean Anthracite. We surveyed possible parameters and conducted desulfation efficiency test in D Thermal Power Plant. In addition, the result of some fundamental theoretical consideration was discussed with CFBC. Optimum limestone size could be considered to be 0.1-0.3mm irrespective of combustion temperature and Ca/S molar ratio variation. Desulfation efficiency increased as the molar ratio increased. Because desulfation process occurs at the surface at higher temperature, inner side of limestone can't be utilized. When surface area is not appropriate, some SO$_2$ emit without reaction. Optimum molar ratio should be decided after considering chemical and physical properties of limestone and coal thoroughly such as particle size, pore size and HGI. Commercial CFBC is operated at Ca/S 1.6. Combustor temperature 840-87$0^{\circ}C$ shows good desulfation efficiency.