• Title/Summary/Keyword: Anodes

Search Result 260, Processing Time 0.041 seconds

Theoretical and Practical Aspects of Pb-Sn Alloy Plating (Pb-Sn 합금도금의 이론 및 실제적 경향)

  • Paik, Young-Nam
    • Journal of the Korean institute of surface engineering
    • /
    • v.12 no.3
    • /
    • pp.161-166
    • /
    • 1979
  • Theoretical and practical aspects are investigated for electrochemical behavious, plating processes and the structures of electrodeposit of Pb-Sn binary alloy plating through numerous literatures in this report. The anodic and cathodic electrode reaction mechanisms of Pb and Sn could co-deposit and make Pb-Sn alloy deposit from the results of cathode current density-cathode potential curves of Pb, Sn and Pb-Sn alloys in fluoborate solutions. The compositions of the best alloy plating solutions are obtained for the purpose of bearing, anticorrosion and solder plating. In general, the casting anodes of Pb-Sn alloys are used, but separated anodes of Pb and Sn pure metal are used in order to obtain the fine compositions of Pb-Sn alloy deposits. The electrodeposits of Pb-Sn alloy are in nonequilibrium state and saturated solid solutions. Thus, ${\beta}$-phase (Sn-phase) is precipitated by heat treatment. The texture and structure of the electrodeposit are associated with the surface energies of deposit lattice planes and with the cathode polarization. The electrodeposit of Pb-Sn alloy is shown as lamellar structure.

  • PDF

Thermal Stability of Lithiated Silicon Anodes with Electrolyte

  • Park, Yoon-Soo;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
    • /
    • v.32 no.1
    • /
    • pp.145-148
    • /
    • 2011
  • The thermal behavior of lithiated Si anodes has been investigated using differential scanning calorimetry (DSC). In particular, the effect of Si particle size on the thermal stability of a fully lithiated Si electrode was investigated. For DSC measurements, a lithiated Si anode was heated in a hermetically sealed high-pressure pan with a polyvinylidene fluoride (PVDF) binder and a 1 M $LiPF_6$ solution in an ethylene carbonate (EC)-diethyl carbonate (DEC) mixture. The thermal evolution around $140^{\circ}C$ increases with lithiation and with decreasing particle size; this phenomenon is attributed to the thermal decomposition of the solid electrolyte interface (SEI) film. Exothermic peaks, following a broad peak at around $140^{\circ}C$, shift to a lower temperature with a decrease in particle size, indicating that the thermal stability of the lithiated Si electrode strongly depends on the Si particle size.

Patterning of Conductive Polymer Anodes Using a Peel-off Method

  • Park, Jong-Woon;Yim, Youn-Chan;Heo, Gi-Seok;Lee, Jong-Ho;Kim, Tae-Won;Kim, Gwang-Young
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2009.10a
    • /
    • pp.868-870
    • /
    • 2009
  • Here we report another soft lithography, peel-off method, for patterning conductive polymer anodes in the fabrication of flexible ITO-free organic light-emitting diodes. This method doesn't require any heating process and UV light. We have demonstrated that such a peel-off technique enables the formation of a very sharp edge and the enhancement of edge roughness.

  • PDF

The Electrochemical properties of Lithium ion Secondary Battery using Ag-deposited graphite anode (은 담지한 혹연을 부극 활물질로 이용한 Li ion 2차전지의 전기화학적 특성 연구)

  • 김상필;조정수;박정후;윤문수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1998.06a
    • /
    • pp.387-390
    • /
    • 1998
  • New Ag-deposited graphite anodes were developed using wet chemical reduction methods for depositing Ag metal onto graphite particles. In this paper, we investigated X-ray diffraction pattern and charge-discharge behavior for Ag-deposited graphite anode. The Lithium ion cello using Ag-deposited graphite anode showed a high average discharge voltage of 3.6∼3.W and a excellent cycle ability than that of conventional graphite. Little capacity loss in this battery may be due to the highly durable Ag-deposited graphite anodes.

  • PDF

Charge/Discharge Characteristics of Lithium ion Secondary Battery Using Ag-deposited Graphite as Anode Active Material (은 담지한 흑연을 부극 활물질로 이용한 Lithium ion 2차전지의 충방전 특성)

  • 김상필;조정수;박정후;윤문수
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.11 no.9
    • /
    • pp.727-732
    • /
    • 1998
  • Ag-deposited graphite powder was prepared by a chemical reduction method of metal particles onto graphite powder. X-ray diffraction observation of Ag-deposited graphite powder revealed that silver existed in a metallic state, but not in an oxidized one. From SEM measurement, ultrafine silver particles were highly dispersed on the surface of graphite particles. Cylindrical lithium ion secondary battery was manufactured using Ag-deposited graphite anodes and $LiCoO_2$ cathodes. The cycleability of lithium ion secondary battery using Ag-deposited graphite anodes was superior to that of original graphite powder. The improved cycleability may be due to both the reduction of electric resistance between electrodes and the highly durable Ag-graphite anode.

  • PDF

Electron Beam Behaviors by the Electrostatic Lens in Triode Field Emission Gun (3극 전계방출 전자총의 정전기 렌즈에 의한 전자빔 거동)

  • Kim, Chung-Soo;Kim, Dong-Hwan;Park, Man-Jin;Jang, Dong-Young;Han, Dong-Chul
    • Transactions of the Korean Society of Machine Tool Engineers
    • /
    • v.16 no.6
    • /
    • pp.163-167
    • /
    • 2007
  • A field emission electron gun including 3 electrodes including one cathode and two anodes is very important for high resolution electron microscope. To have functions to control the initially-emitted electron beam, two anodes act as an electrostatic lens according to equipotential lines by adjusting the spot size, intensity, and working distance. To verify the action of the electron beam by the electrostatic lens by changing several parameters such as electrode shape, displacement and applied voltage to the electrodes, the two lenses were design and simulated and then their performances were analyzed with angular beam intensity(distribution), electrical optic axis variation and their stability.

Distribution of Cathodic Protection Potential for Concrete Slab Specimens at Diverse Environmental Conditions

  • Jin, Chung-Kuk;Jeong, Jin-A
    • International Journal of Ocean System Engineering
    • /
    • v.3 no.2
    • /
    • pp.90-94
    • /
    • 2013
  • This study represents the recent laboratory results from cathodic protection (CP) system with the use of sacrificial anodes at different environmental conditions (temperature of $10^{\circ}C$ and $40^{\circ}C$). Specimens were slab type with a dimension of $500mm{\times}50mm{\times}100mm$, and concrete cover thickness were 25mm. Zinc mesh and/or bulk type anodes were installed at the center of specimen to confirm the distance that CP system has influences on the specimen to distribute uniform CP current to rebar. Two different kinds of temperature condition were applied to verify the effect of temperature. Experiments were conducted for 60 days, and the distribution of potential and current that supplied from anode to rebar was measured. From the results, CP potential was varied with time, and temperature played an important role in CP potential variations. Current was also changed with time, and current distribution could be improved by installing additional bulk type anode.