• Title/Summary/Keyword: Analytical parameter

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Analytical Properties of Electron Spin Resonance after Irradiation of Seasonings with Different Radiation Sources (조미료의 방사선 조사선원에 따른 전자스핀공명 분석 특성)

  • Ahn, Jae-Jun;Kim, Gui-Ran;Jin, Qiong-Wen;Kwon, Joong-Ho
    • Food Science and Preservation
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    • v.16 no.3
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    • pp.385-391
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    • 2009
  • Analytical electron spin resonance (ESR) parameters were investigated in irradiated seasonings after exposure to different radiation sources. Two commercial seasonings (SS-1 and SS-2) were irradiated with 0.20 kGy under ambient conditions using a $^{60}Co$ gamma-ray irradiator or an electron beam accelerator. Crystalline sugar-induced multi-component signals with g-values of 2.031, 2.021, 2.017, 2.009, 2.002, 1.990, and 1.980 were observed in both irradiated samples, whereas singlet signals were detected in non-irradiated materials, thereby distinguishing irradiated from control samples. Under the same analytical conditions, the ESR signal intensity of electron beam-irradiated samples was greater than that of gamma-irradiated materials. Determination coefficients (R2 values) between irradiation doses and corresponding ESR responses were 0.9916-0.9973 for all samples, and the magnetic field of specified g-values for irradiated samples remained constant. The predominant ESR signals of g2 (2.021), g4 (2.009), g5 (2.002), and g6 (1.990) showed high correlations with the corresponding irradiation doses (R2=0.8243 - 0.9929).

Analysis of Sildenafil and its Analogues by LC/MS/MS (LC/MS/MS를 이용한 sildenafil 및 그 유사체 분석)

  • Myung, Seung-Woon;Park, So-Hee;Cho, Hyun-Woo
    • Analytical Science and Technology
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    • v.16 no.6
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    • pp.488-498
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    • 2003
  • By LC/MS/MS, the analytical method of sildenafil and its analogues (homosildenafil, vardenafil and tadalafil) used as used medical treatment of impotence was established. electrosprary ionization (ESI) and atmospheric pressure chemical ionization (APCI) as a ionization method were applied. Several parameter were varied and the sensitivity and reproducibility were compared. In LC/ESI-MS method, capillary voltage, cone voltage, extractor, entrance and RF lens to create appropriate productr ions for multiple reaction monitoring (MRM) were variable parameter, but the formation of the other product ions except the precursor ion could not detect. And the value of entrance, collision energy, exit, corona voltage, cone voltage, extractor, RF lens, cone gas, and desolvation gas in APCI mode were varied, only the creation pattern of fragment ions by the change of RF lens value were detected, and the limit of detection was decreased due to the increase of S/N. Ten millimole ammonium formate (pH 4.8):acetonitrile=70:30 by isocratic elution in HPLC system was shown the maximum sensitivity in MS, the detection limit of sildenafil, homosildenafil, vardenafil and tadalafil obtained by ESI-MRM were 0.10, 0.025, 0.025, and $0.25{\mu}g/mL$ at S/N>5, respectively.

Investigation of Likelihood of Cracking in Reinforced Concrete Bridge Decks

  • ElSafty, Adel;Abdel-Mohti, Ahmed
    • International Journal of Concrete Structures and Materials
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    • v.7 no.1
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    • pp.79-93
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    • 2013
  • One of the biggest problems affecting bridges is the transverse cracking and deterioration of concrete bridge decks. The causes of early age cracking are primarily attributed to plastic shrinkage, temperature effects, autogenous shrinkage, and drying shrinkage. The cracks can be influenced by material characteristics, casting sequence, formwork, climate conditions, geometry, and time dependent factors. The cracking of bridge decks not only creates unsightly aesthetic condition but also greatly reduces durability. It leads to a loss of functionality, loss of stiffness, and ultimately loss of structural safety. This investigation consists of field, laboratory, and analytical phases. The experimental and field testing investigate the early age transverse cracking of bridge decks and evaluate the use of sealant materials. The research identifies suitable materials, for crack sealing, with an ability to span cracks of various widths and to achieve performance criteria such as penetration depth, bond strength, and elongation. This paper also analytically examines the effect of a wide range of parameters on the development of cracking such as the number of spans, the span length, girder spacing, deck thickness, concrete compressive strength, dead load, hydration, temperature, shrinkage, and creep. The importance of each parameter is identified and then evaluated. Also, the AASHTO Standard Specification limits liveload deflections to L/800 for ordinary bridges and L/1000 for bridges in urban areas that are subject to pedestrian use. The deflection is found to be an important parameter to affect cracking. A set of recommendations to limit the transverse deck cracks in bridge decks is also presented.

Wave dispersion characteristics of nonlocal strain gradient double-layered graphene sheets in hygro-thermal environments

  • Ebrahimi, Farzad;Dabbagh, Ali
    • Structural Engineering and Mechanics
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    • v.65 no.6
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    • pp.645-656
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    • 2018
  • Importance of procuring adequate knowledge about the mechanical behavior of double-layered graphene sheets (DLGSs) incensed the authors to investigate wave propagation responses of mentioned element while rested on a visco-Pasternak medium under hygro-thermal loading. A nonlocal strain gradient theory (NSGT) is exploited to present a more reliable size-dependent mechanical analysis by capturing both softening and hardening effects of small scale. Furthermore, in the framework of a classical plate theory the kinematic relations are developed. Incorporating kinematic relations with the definition of Hamilton's principle, the Euler-Lagrange equations of each of the layers are derived separately. Afterwards, combining Euler-Lagrange equations with those of the NSGT the nonlocal governing equations are written in terms of displacement fields. Interaction of the each of the graphene sheets with another one is regarded by the means of vdW model. Then, a widespread analytical solution is employed to solve the derived equations and obtain wave frequency values. Subsequently, influence of each participant variable containing nonlocal parameter, length scale parameter, foundation parameters, temperature gradient and moisture concentration is studied by plotting various figures.

Dynamic analysis of higher order shear-deformable nanobeams resting on elastic foundation based on nonlocal strain gradient theory

  • Bensaid, Ismail;Bekhadda, Ahmed;Kerboua, Bachir
    • Advances in nano research
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    • v.6 no.3
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    • pp.279-298
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    • 2018
  • Present investigation deals with the free vibration characteristics of nanoscale-beams resting on elastic Pasternak's foundation based on nonlocal strain-gradient theory and a higher order hyperbolic beam model which captures shear deformation effect without using any shear correction factor. The nanobeam is lying on two-parameters elastic foundation consist of lower spring layers as well as a shear layer. Nonlocal strain gradient theory takes into account two scale parameters for modeling the small size effects of nanostructures more accurately. Hamilton's principal is utilized to derive the governing equations of embedded strain gradient nanobeam and, after that, analytical solutions are provided for simply supported conditions to solve the governing equations. The obtained results are compared with those predicted by the previous articles available in literature. Finally, the impacts of nonlocal parameter, length scale parameter, slenderness ratio, elastic medium, on vibration frequencies of nanosize beams are all evaluated.

Dynamic response of a Timoshenko beam on a tensionless Pasternak foundation

  • Coskun, Irfan;Engin, Hasan;Tekin, Ayfer
    • Structural Engineering and Mechanics
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    • v.37 no.5
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    • pp.489-507
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    • 2011
  • The dynamic response of a Timoshenko beam on a tensionless Pasternak foundation is investigated by assuming that the beam is subjected to a concentrated harmonic load at its middle. This action results in the creation of lift-off regions between the beam and the foundation that effect the character of the response. Although small displacements for the beam and the foundation are assumed, the problem becomes nonlinear since the contact/lift-off regions are not known at the outset. The governing equations of the beam, which are coupled in deflection and rotation, are obtained in both the contact and lift-off regions. After removing the coupling, the essentials of the problem (the contact regions) are determined by using an analytical-numerical method. The results are presented in figures to demonstrate the effects of some parameters on the extent of the contact lengths and displacements. The results are also compared with those of Bernoulli-Euler, shear, and Rayleigh beams. It is observed that the solution is not unique; for a fixed value of the frequency parameter, more than one solution (contact length) exists. The contact length of the beam increases with the increase of the frequency and rotary-inertia parameters, whereas it decreases with increasing shear foundation parameter.

Buckling analysis of tapered BDFGM nano-beam under variable axial compression resting on elastic medium

  • Heydari, Abbas;Shariati, Mahdi
    • Structural Engineering and Mechanics
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    • v.66 no.6
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    • pp.737-748
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    • 2018
  • The current study presents a new technique in the framework of the nonlocal elasticity theory for a comprehensive buckling analysis of Euler-Bernoulli nano-beams made up of bidirectional functionally graded material (BDFGM). The mechanical properties are considered by exponential and arbitrary variations for axial and transverse directions, respectively. The various circumstances including tapering, resting on two-parameter elastic foundation, step-wise or continuous variations of axial loading, various shapes of sections with various distribution laws of mechanical properties and various boundary conditions like the multi-span beams are taken into account. As far as we know, for the first time in the current work, the buckling analyses of BDFGM nano-beams are carried out under mentioned circumstances. The critical buckling loads and mode shapes are calculated by using energy method and a new technique based on calculus of variations and collocation method. Fast convergence and excellent agreement with the known data in literature, wherever possible, presents the efficiency of proposed technique. The effects of boundary conditions, material and taper constants, foundation moduli, variable axial compression and small-scale of nano-beam on the buckling loads and mode shapes are investigated. Moreover the analytical solutions, for the simpler cases are provided in appendices.

Bending analysis of bi-directional functionally graded Euler-Bernoulli nano-beams using integral form of Eringen's non-local elasticity theory

  • Nejad, Mohammad Zamani;Hadi, Amin;Omidvari, Arash;Rastgoo, Abbas
    • Structural Engineering and Mechanics
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    • v.67 no.4
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    • pp.417-425
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    • 2018
  • The main aim of this paper is to investigate the bending of Euler-Bernouilli nano-beams made of bi-directional functionally graded materials (BDFGMs) using Eringen's non-local elasticity theory in the integral form with compare the differential form. To the best of the researchers' knowledge, in the literature, there is no study carried out into integral form of Eringen's non-local elasticity theory for bending analysis of BDFGM Euler-Bernoulli nano-beams with arbitrary functions. Material properties of nano-beam are assumed to change along the thickness and length directions according to arbitrary function. The approximate analytical solutions to the bending analysis of the BDFG nano-beam are derived by using the Rayleigh-Ritz method. The differential form of Eringen's non-local elasticity theory reveals with increasing size effect parameter, the flexibility of the nano-beam decreases, that this is unreasonable. This problem has been resolved in the integral form of the Eringen's model. For all boundary conditions, it is clearly seen that the integral form of Eringen's model predicts the softening effect of the non-local parameter as expected. Finally, the effects of changes of some important parameters such as material length scale, BDFG index on the values of deflection of nano-beam are studied.

Analysis of Flat-Band-Voltage Dependent Breakdown Voltage for 10 nm Double Gate MOSFET

  • Jung, Hakkee;Dimitrijev, Sima
    • Journal of information and communication convergence engineering
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    • v.16 no.1
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    • pp.43-47
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    • 2018
  • The existing modeling of avalanche dominated breakdown in double gate MOSFETs (DGMOSFETs) is not relevant for 10 nm gate lengths, because the avalanche mechanism does not occur when the channel length approaches the carrier scattering length. This paper focuses on the punch through mechanism to analyze the breakdown characteristics in 10 nm DGMOSFETs. The analysis is based on an analytical model for the thermionic-emission and tunneling currents, which is based on two-dimensional distributions of the electric potential, obtained from the Poisson equation, and the Wentzel-Kramers-Brillouin (WKB) approximation for the tunneling probability. The analysis shows that corresponding flat-band-voltage for fixed threshold voltage has a significant impact on the breakdown voltage. To investigate ambiguousness of number of dopants in channel, we compared breakdown voltages of high doping and undoped DGMOSFET and show undoped DGMOSFET is more realistic due to simple flat-band-voltage shift. Given that the flat-band-voltage is a process dependent parameter, the new model can be used to quantify the impact of process-parameter fluctuations on the breakdown voltage.

Model Validation for the CBS Ku-Band Transponder Panel Using Launch Environmental Test (발사환경시험을 이용한 통신방송위성 Ku대역 중계기 패널의 모델 검증)

  • Seo Hyun Suk;Choi Jang Sub;Park Jong Heung;Woo Hyung Je
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.3 s.234
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    • pp.387-394
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    • 2005
  • Accurate predictions and simulations of the behavior of space structures based on analytical models become more important. In order to perform analysis to support the design of Ku-band transponder panel for the Communications and Broadcasting Satellite(CBS), mathematical models of the panel were generated in the form of finite element models. Test verification of these models is required before the transponder panel can be certified for launch environments. A modal identification was performed to obtain modal parameters which can be compared with the test results using correlation techniques. This paper approaches the sensor placement from the standpoint of the structural dynamicist who uses the modal parameter obtained during launch environmental test. The models were validated by performing a test-analysis correlation and updating analysis. It was proved that the Ku-band transponder panel satisfies the environmental test requirements.