• Analytical Science and Technology
• /
• v.13 no.4
• /
• pp.484-493
• /
• 2000

The simultaneous analysis of alkylphenols, chlorophenols and bisphenol A in biota samples was performed by gas chromatography-mass spectrometry-selected ion monitoring mode. The phenols were extracted from sample with organic solvent and Forisil and Silica columns for clean-up procedure were compared. Recovery studies were performed at 1-ppm level of phenols added to each biota sample. Their recoveries ranged between 83 and 116% with coefficient of variations of 2.4-11.9%. To improve the detection limits of phenols, trimethylsilyl (TMS) derivatization was applied. The gas chromatographic properties of free phenols and TMS derivatized phenols were also investigated.

• Analytical Science and Technology
• /
• v.17 no.1
• /
• pp.29-36
• /
• 2004

An analytical method of polybrominated diphenyl ethers in soil samples by isotope dilution method using gas chromatography/mass spectrometry (GC/MS)-selected ion monitoring (SIM) was described. PBDEs in soil were extracted with soxhlet extractor and then silica and florisil solid phase extraction (SPE) methods as purification of extract were compared. After clean-up, the extractions were analyzed by GC/MS with SIM mode. Quantitation was performed isotope dilution method using four $^{13}C$ isotopically labeled PBDEs as internal standards. This developed method was validated for eight congeners of PBDEs in the concentration range 0.04~4 ng/g in soil and the average recovery of the analytes ranged 30.8~110.8% for florisil and 44.4~110.7% for silica, respectively. The method detection limits of PBDEs were 0.04~0.3 ng/g.

• Composites Research
• /
• v.32 no.4
• /
• pp.185-190
• /
• 2019

This work investigates the elastic buckling characteristics of laminated composite trapezoidal corrugated plates with simply supported edges using the analytical method. In the analysis, three types of in-plane loading conditions: uniaxial, biaxial and shear loads are considered. Because it is very difficult to determine the mechanical behavior of 3-dimensional corrugated structures analytically, the equivalent homogenization model is adapted to investigate the overall mechanical behavior of corrugated plates. The corrugated element is homogenized as an orthotropic material. The previous formulae for bending rigidities of corrugated plate are adapted in this paper. The comparisons of the proposed analytical results with those of FEA based on the shell element are made to verify the proposed analytical method. In the comparison study both the critical buckling loads and the buckling mode shapes are presented. Some numerical results are presented to check the effect of the geometric properties.

• Smart Structures and Systems
• /
• v.24 no.3
• /
• pp.333-343
• /
• 2019

The possibility of adopting vibration-powered wireless nodes has been largely investigated in the last years. Among the available technologies based on the piezoelectric effect, the most common ones consist of a vibrating beam covered by electroactive layers. Another energy harvesting strategy is based on the use of piezoelectric strips attached to a hosting structure subjected to dynamic loads. The hosting structure, for example, can be the system to be equipped with wireless nodes. Such strategy has received few attentions so far and no analytical studies have been presented yet. Hence, the original contribution of the present paper is concerned with the development of analytical solutions for the electrodynamic analysis and design of piezoelectric polymeric strips attached to relatively large linear elastic structural systems subjected to random vibrations at the base. Specifically, it is assumed that the dynamics of the hosting structure is dominated by the fundamental vibration mode only, and thus it is reduced to a linear elastic single-degree-of-freedom system. On the other hand, the random excitation at the base of the hosting structure is simulated by filtering a white Gaussian noise through a linear second-order filter. The electromechanical force exerted by the polymeric strip is negligible compared with other forces generated by the large hosting structure to which it is attached. By assuming a simplified electrical interface, useful new exact analytical expressions are derived to assess the generated electric power and the integrity of the harvester as well as to facilitate its optimum design.

• Analytical Science and Technology
• /
• v.20 no.5
• /
• pp.442-447
• /
• 2007

The properties of garlic (Allium sativum L.) are attributed to organosulfur compounds. In this paper, an analytical technique with a rapid and simple sample preparation procedures for determination of diallyl disulfide (DADS) in garlic was reported. The DADS was simply extracted with various solvents (methanol, benzene or tetrahydrofuran) from garlic and prepared for HPLC analysis. From the results, the methanol was select as an optimal extraction solvent. The mobile phase was composed from methanol and water, and the gradient elution mode was applied. 0.61 mg of DADS per g garlic powder can be extracted with methanol. This work offers some advantages over the currently accepted techniques and would be useful for chemical and biological studies of garlic and its products.

• Journal of the Society of Naval Architects of Korea
• /
• v.30 no.3
• /
• pp.116-126
• /
• 1993

The finite element method(FEM) has been commonly used for structural dynamic analysis. However, the direct global application of FEM to large complex structures such as ships and offshore structures requires considerable computational efforts, and remarkably more in structural dynamic optimization problems. Adoption of the component-mode synthesis method is an efficient means to overcome the above difficulty. Among three classes of the component-mode synthesis method, the free-interface mode method is recognized to have the advantages of better computational efficiency and easier implementation of substructures' experimental results, but the disadvantage of lower accuracy in analytical results. In this paper, an advanced method to improve the accuracy in the application of the free-interface mode method for the vibration analysis of large complex structures is presented. In order to compensate the truncation effect of the higher modes of substructures in the synthesis process, both residual inertia and stiffness effects are taken into account and a frequency shifting technique is introduced in the formulation of the residual compliance of substructures. The introduction of the frequency shrift ins not only excludes cumbersome manipulation of singular matrices for semi-definite substructural systems but gives more accurate results around the specified shifting frequency. Numerical examples of typical structural models including a ship-like two dimensional finite element model show that the analysis results based on the presented method are well competitive in accuracy with those obtained by the direst global FEM analysis for the frequencies which are lower than the highest one employed in the synthesis with remarkably higher computational efficiency and that the presented method is more efficient and accurate than the fixed-interface mode method.

• Structural Engineering and Mechanics
• /
• v.78 no.1
• /
• pp.41-52
• /
• 2021

Inelastic static pushover analysis has been used in the academic-research widely for seismic analysis of structures. Nowadays, the variety pushover analysis methods have been developed, including Modal pushover, Adaptive pushover, and Cyclic pushover, in which some weaknesses of the conventional pushover method have been rectified. In the conventional pushover analysis method, the effects of cumulative growth of cracks are not considered on the reduction of strength and stiffness of RC members that occur during earthquake or cyclic loading. Therefore, the Cyclic Pushover Analysis Method (CPA) has been proposed. This method is a powerful technique for seismic evaluation of regular reinforced concrete buildings in which the first mode of them is dominant. Since the bridges have different structures than buildings, their results cannot necessarily be attributed to bridges, and more research is needed. In this study, a cyclic pushover analysis with four loading protocols (suggested by valid references) by the Opensees software was conducted for seismic evaluation of two regular reinforce concrete bridges. The modeling method was validated with the comparison of the analytical and experimental results under both cyclic and dynamic loading. The failure mode of the piers was considered in two-mode of flexural failure and also a flexural-shear failure. Along with the cyclic analysis, conventional analysis has been studied. Also, the nonlinear incremental dynamic analysis (IDA) method has been used to examine and compare the results of pushover analyses. The time history of 20 far-field earthquake records was used to conduct IDA. After analysis, the base shear vs. displacement in the middle of the deck was drawn. The obtained results show that the cyclic pushover analysis method is able to evaluate an accurate seismic behavior of the reinforced concrete piers of the bridges. Based on the results, the cyclic pushover has proper convergence with IDA. Its accuracy was much higher than the conventional pushover, in which the bridge piers failed in flexural-shear mode. But, in the flexural failure mode, the results of each two pushover methods were close approximately. Besides, the cyclic pushover method with ACI loading protocol, and ATC-24 loading protocol, can provided more accurate results for evaluating the seismic investigation of the bridges, specially if the bridge piers are failed in flexural-shear failure mode.

• Analytical Science and Technology
• /
• v.21 no.6
• /
• pp.543-552
• /
• 2008

This paper described the relatively sensitive and simultaneous analytical method for 3-monochloropropane-1,2-diol (3-MCDP, $C_3H_7ClO_2$, MW. 110) as well as 1,3-dichloropropan-2-ol (1,3-DCP, $C_3H_6Cl_2O$, MW. 128) in various foods. Food samples were homogenized in 5M NaCl solution, mixed with aluminum oxide and eluted with dichloromethane. The extracted chloropropanols were concentrated by rotary evaporator and $N_2$ blow serially were derivatized with HFBA (Heptafluorobutyric anhydride, $C_8F_{14}O_3$, MW. 410) and were determined by GC/MS using isotope dilution method. The characteristic molecular ions at m/z 253, 275, 289, 291, and 453 for HFBA derivatives of 3-MCPD (MW. 502) and 110, 275, and 277 for HFBA derivatives of 1,3-DCP (MW. 325) were chosen in selected ion mode. The method validation data showed sufficiently good properties of LOD (0.003 mg/kg), LOQ (0.010 mg/kg), linearity ($R^2{\geq}0.999$ at 0.010~1.000 mg/kg), and recovery rate (${\approx}97%$). The levels of chloropropanols in soy sauce, sauces, processed meat products, fishery products, and seasonings (n=56/157) determined by the presented method were 0.0~0.3 mg/kg.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• v.7 no.1
• /
• pp.1-21
• /
• 2013

The release of IEEE 802.15.4e specification significantly develops IEEE 802.15.4. The most inspiring improvement is the enhancement for medium access control (MAC) sublayer. To study the performance of IEEE 802.15.4e MAC, in this paper we first present an overview of IEEE 802.15.4e and introduce three MAC mechanisms in IEEE 802.15.4e. And the major concern here is the Time Slotted Channel Hopping (TSCH) mode that provides deterministic access and increases network capacity. Then a detailed analytical Markov chain model for TSCH carrier sense multiple access with collision avoidance (CSMA-CA) is presented. Expressions which cover most of the crucial issues in performance analysis such as the packet loss rate, energy consumption, normalized throughput, and average access delay are presented. Finally the performance evaluation for the TSCH mode is given and we make a comprehensive comparison with unslotted CSMA-CA in non-beacon enabled mode of IEEE 802.15.4. It can validate IEEE 802.15.4e network can provide low energy consumption, deterministic access and increase network capacity.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• v.11 no.6
• /
• pp.2831-2847
• /
• 2017

In this paper, a joint destination-relay selection and antenna mode selection scheme for full-duplex (FD) relay network is investigated, which consists of one source node, N FD amplify-and-forward (AF) relays and M destination nodes. Multiple antennas are configured at the source node, and beamforming technique is adopted. Two antennas are employed at each relay, one for receiving and the other for transmitting. Only one antenna is equipped at each destination node. In the proposed scheme, the best destination node is firstly selected according to the direct links between the source node and destination nodes. Then the transmit and receive mode of two antennas at each relay is adaptively selected based on the relaying link condition. Meanwhile, the best relay with the optimal Tx/Rx antenna configuration is selected to forward the signals. To characterize the performance of the proposed scheme, the closed-form expression of the outage probability is derived; meanwhile, the simple asymptotic expressions are also obtained. Our analysis shows that the proposed scheme obtains the benefits of multi-relay diversity and multi-destination diversity. Moreover, extra space diversity in the medium SNR region can be achieved due to the antenna selection at the relay. Finally, Monte-Carlo simulations are provided to consolidate the analytical results, and show the effectiveness of the proposed scheme.