• 콘크리트학회논문집
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• 제22권3호
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• pp.381-388
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• 2010

이 논문에서는 내진상세가 적용되지 않은 RC골조의 지진 거동 특성을 파악하였다. 해석 대상 건물은 내진 규준의 적용을 받지 않고 중력하중만을 고려하여 설계되었다. 원형철근이 주철근으로 사용되었으며, 부재는 낮은 수준의 전단력을 견딜 수 있는 최소한의 스터럽이 사용되어 코어 부분의 구속효과는 거의 없다. 평면비정형성을 가진 건물의 경우, 푸쉬오버 해석을 통해서는 비틀림으로 인한 평면상에서 연단부의 손상집중을 파악할 수 없으므로 비선형 동적해석을 사용하는 것이 바람직하다. 섬유요소를 이용한 비선형 동적해석은 양방향 지진하중과 비틀림 거동의 영향을 받는 RC골조의 거동을 성공적으로 예측할 수 있었다. 하지만, 보다 진보된 응답 예측을 위해서는 부착 미끄러짐과 같은 보-기둥 접합부의 국부거동을 정밀하게 나타내는 모델링 요소의 개발이 필요하다.

• Structural Engineering and Mechanics
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• 제73권3호
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• pp.353-365
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• 2020

In the previous studies, the authors proposed the use of laminated veneer lumber - carbon fiber reinforced polymer (LVL-CFRP) composite beams for structural application. Bond strength of the LVL-to-CFRP interface and flexural strengthening schemes to increase the bending capacity subjected to positive and negative moment were discussed in the previous works. In this article, theoretical models are proposed to predict the moment capacity when the LVL-CFRP beams are subjected to negative moment. Two common failure modes - CFRP fracture and debonding of CFRP are considered. The non-linear model proposed for positive moment is modified for negative moment to determine the section moment capacity. For the debonding based failure, previously developed bond strength model for CFRP-to-LVL interface is implemented. The theoretical models are validated against the experimental results and then use to determine the moment-rotation behaviour and rotational rigidity to compare the efficacy of various strengthening techniques. It is found that combined use of bi- and uni-directional CFRP U-wrap at the joint performs well in terms of both moment capacity and rotational rigidity.

• Advances in Computational Design
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• 제2권2호
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• pp.147-168
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• 2017

Over the past couple decades, externally bonded fiber reinforced polymer (FRP) composites have emerged as a repair and strengthening material for many concrete infrastructure applications. This paper presents an analytical investigation of the use of carbon FRP (CFRP) for a specific problem that occurs in concrete bridge girders wherein the girder ends are damaged by excessive exposure to deicing salts and numerous freezing/thawing cycles. A 3D finite element (FE) model of a full scale prestressed concrete (PC) I-girder is used to investigate the effect of damage to the cover concrete and stirrups in the end region of the girder. Parametric studies are performed using externally bonded CFRP shear laminates to determine the most effective repair schemes for the damaged end region under a short shear span-to-depth ratio. Experimental results on shear pull off tests of CFRP laminates that have undergone accelerated aging are used to calibrate a bond stress-slip model for the interface between the FRP and concrete substrate and approximate the reduced bond stress-slip properties associated with exposure to the environment that causes this type of end region damage. The results of these analyses indicate that this particular application of this material can be effective in recovering the original strength of PC bridge girders with damaged end regions, even after environmental aging.

• Structural Engineering and Mechanics
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• 제17권3_4호
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• pp.357-378
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• 2004

Nonlinear dynamic analysis of a reinforced concrete (RC) frame under earthquake loading is performed in this paper on the basis of a hysteretic moment-curvature relation. Unlike previous analytical moment-curvature relations which take into account the flexural deformation only with the perfect-bond assumption, by introducing an equivalent flexural stiffness, the proposed relation considers the rigid-body-motion due to anchorage slip at the fixed end, which accounts for more than 50% of the total deformation. The advantage of the proposed relation, compared with both the layered section approach and the multi-component model, may be the ease of its application to a complex structure composed of many elements and on the reduction in calculation time and memory space. Describing the structural response more exactly becomes possible through the use of curved unloading and reloading branches inferred from the stress-strain relation of steel and consideration of the pinching effect caused by axial force. Finally, the applicability of the proposed model to the nonlinear dynamic analysis of RC structures is established through correlation studies between analytical and experimental results.

• Steel and Composite Structures
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• 제3권6호
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• pp.421-438
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• 2003

Aging and deterioration of existing steel structures necessitate the development of simple and efficient rehabilitation techniques. The current study investigates a methodology to enhance the flexural capacity of steel beams by bonding Glass Fibre Reinforced Plastic (GFRP) sheets to their flanges. A heavy duty adhesive, tested in a previous study is used to bond the steel and the GFRP sheet. In addition to its ease of application, the GFRP sheet provides a protective layer that prevents future corrosion of the steel section. The study reports the results of bending tests conducted on a W-shaped steel beam before and after rehabilitation using GFRP sheets. Enhancement in the moment capacity of the beam due to bonding GFRP sheet is determined from the test results. A closed form analytical model that can predict the yield moment as well as the stresses induced in the adhesive and the GFRP sheets of rehabilitated steel beam is developed. A detailed finite element analysis for the tested specimens is also conducted in this paper. The steel web and flanges as well as the GFRP sheets are simulated using three-dimensional brick elements. The shear and peel stiffness of the adhesive are modeled as equivalent linear spring systems. The analytical and experimental results indicate that a significant enhancement in the ultimate capacity of the steel beam is achieved using the proposed technique. The finite element analysis is employed to describe in detail the profile of stresses and strains that develop in the rehabilitated steel beam.

• Journal of Electrochemical Science and Technology
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• 제11권3호
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• pp.291-309
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• 2020

Chromium was electrodeposited from deep eutectic solvents-based Cr³⁺ electrolytes on HB-pencil graphite electrode. Factors influencing the electrochemical behavior and the processes of Cr nucleation and growth were explored using cyclic voltammetry and chronoamperometry techniques, respectively. Cr³⁺ reduction was found to occur through an irreversible diffusion-controlled step followed by another irreversible one of impure diffusional behaviour. The reduction behavior was found to be greatly affected by Cr³⁺ concentration, temperature, and type of hydrogen bond donor used in deep eutectic solvents (DESs) preparation. A more comprehensive model was suggested and successfully applied to extract a consistent data relevant to Cr nucleation kinetics from the experimental current density transients. The potential, the temperature, and the hydrogen bond donor type were estimated to be critical factors controlling Cr nucleation. The nucleation and growth processes of Cr from either choline chloride/ethylene glycol (EG-DES) or choline chloride/urea (U-DES) deep eutectic solvents were evaluated at 70℃ to be three-dimensional (3D) instantaneous and diffusion-controlled, respectively. However, the kinetics of Cr nucleation from EG-DES was found to be faster than that from U-DES. Cr nucleation was tending to be instantaneous at higher temperature, potential, and Cr³⁺ concentration. Cr nuclei electrodeposited from EG-DES were characterized at different conditions using scanning electron microscope (SEM). SEM images show that high number density of fine spherical nuclei of almost same sizes was nearly obtained at higher temperature and more negative potential. Energy dispersive spectroscopy (EDS) analysis confirms that Cr deposits were obtained.

• 분석과학
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• 제28권3호
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• pp.187-195
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• 2015

승화열은 대기 유기 오염물질의 확산에 관련된 환경적인 문제를 해결하거나, 위험한 화학 물질의 위해성을 평가하는 데에 중요한 변수이다. 하지만 실험적으로 승화열을 측정하려면 많은 시간과 비용이 소모 되며, 그 실험자체도 복잡하고 위험하다. 따라서 본 연구에서는 유기화합물의 승화열을 간단하게 예측하는 모델을 개발하기 위하여 정량적 구조-물성 상관관계 연구를 이용하였다. 군기반 전진선택방법을 적용하여 다중선형회귀방법과 서포트 벡터 머신과 같은 학습방법에 적합한 분자표현자들을 선택하도록 하였다. 개별 모델과 복합모델들은 부스트래핑 방법과 y-임의추출법에 의해 내부검증이 되었다. 외부 테스트 데이터의 예측 성능은 적용범위를 고려하므로서 개선되었다. 다중선형회귀모델에 따르면, 승화열은 분자간의 분산력, 수소결합, 정전기적 상호작용, 쌍극자-쌍극자 상호작용과 관련이 있는 것을 나타낼 수 있었다.

• 한국산학기술학회논문지
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• 제15권5호
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• pp.3251-3259
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• 2014

본 논문에서는 철근의 부식을 고려한 철근콘크리트(RC)보의 휨파괴거동을 규명하기 위하여 수행한 일련의 3점휨 파괴시험 및 해석적 연구 결과를 제시하였다. 실험적 연구를 위하여 총12개의 시편보를 제작하였으며, 염수분무시험 챔버를 이용하여 10개월간 촉진부식토록 하였다. 철근부식에 미치는 균열의 영향을 분석하기 위하여 일부 시험체를 공칭휨강도의 30% 와 60%에 해당하는 최대하중으로 미리 하중을 가한 후 염소분무 시험챔버에 보관하였다. 재령 5개월 및 10월에 각각 휨파괴시험을 실시하였으며 최대하중과 하중-처짐곡선을 측정하였다. 실험결과 철근의 부식정도에 따라 철근과 콘크리트간의 부착력 손실이 발생하고 그에 기인하여 휨강도는 최대 5.4%, 연성도는 최대 43%의 저하가 발생하여 철근의 부식이 최대 하중 보다 연성도에 미치는 영향이 큰 것으로 나타났다. 한편, Maaddawy의 해석적 모델을 이용한 수치해석결과 철근의 부식을 고려한 RC보의 휨파괴거동을 상당부분 잘 묘사할 수 있는 것으로 나타났다.

• 전산구조공학
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• 제8권4호
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• pp.117-127
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• 1995

이 연구의 목적은 단조하중과 반복하중을 받는 철근콘크리트 면부재 해석에 대한 이방향성 회전 직교축 모델의 성능을 검토하기 위함이다. 여기서 다루는 구조부재는 철근에 의하여 적절히 보강된 보, 기둥, 보-기둥 접합부, 그리고 전단벽등으로 부재의 파괴가 인장균열후 압축파괴에 의하여 일어나는 부재이다. 보통 단조하중에 대하여 사용도는 이방향성 회전 직교축 모델을 반복하중에 대하여 확장하며, 철근과 부착의 기존 재료모델과 함꼐 유한요소해석에 사용한다. 단조하중에 대하여 이방향성 회전 직교축 모델을 사용한 해석 결과는 취성파괴를 나타내는 철근콘크리트보의 실험결과와 비교된다. 또한 반복하중을 받는 전단벽의 극한하중, 비선형 변형, 핀칭 현상 등에 대하여 실험결과와 비교된다.

• Bulletin of the Korean Chemical Society
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• 제30권11호
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• pp.2749-2753
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• 2009

Structural characteristics that influence on the insecticidal activity ($pI_{50}$) of 2-(n-octyl)isothiourea analogues (1-45) against the diamondback moth (Plutella xylostella, L.) based on three dimensional quantitative structure activity relationships (3D-QSARs) were discussed quantitatively using a comparative molecular field analysis (CoMFA) and a comparative molecular similarity indeces analysis (CoMSIA) methods. The statistical values of the CoMFA 2 model were better than those of the CoMSIA 1 model. The CoMFA 2 model was the optimized model with the correlativity (the training set: Ave. = 0.104 & PRESS = 0.613) and the predictability (the test set: Ave. = 0.086 & PRESS = 0.096). Insecticidal activities with the optimized CoMFA 2 model were dependent upon steric factors (79.4%) of $R_1-R_3$ substituents. From the analytical results of CoMFA contour maps, it is predicted that the R1 substituent of 1-45 which has a steric favor in a broad space, $R_2\;and\;R_3$ groups with a steric favor in a narrow space and a H-bond donor favor would have better the insecticidal activity.