• Analytical Science and Technology
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• v.24 no.3
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• pp.219-224
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• 2011

Voltammetric analysis of Cl(I) ion was performed using a metal gold (Au) electrode (AE) and a carbon nanotube electrode (CNTE). After the examination, the AE was found to have more sensitively detected Cl(I) than CNTE. The optimum analytical conditions for the cyclic voltammetry (CV) and the square wave (SW) stripping voltammetry were performed using AE. The detection limit of $6.5\;{\mu}g/L$ Cl(I) was attained. The developed techniques were compared with the common Cl meter and applied to water systems.

• Analytical Science and Technology
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• v.25 no.4
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• pp.214-222
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• 2012

ASTM (American Society for Testing and Materials) D6751-10 suggests analytical methods as well as specifications for biodiesel quality. However, it is expensive and time-consuming to follow the ASTM testing methods to analyze biodiesel and various impurities. This paper develops a quantitative analysis system for biodiesel and impurities based on Infrared spectroscopy and a multivariate statistical method, PLS (partial least squares). In addition, four different pre-processing techniques were compared for spectrum correction and noise reduction. Savitzky-Golay pre-processing showed the best performance.

• Analytical Science and Technology
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• v.33 no.2
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• pp.86-97
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• 2020

Reconstruction and separation of explosive-contaminated overlapping fingerprints constitutes an analytical challenge of high significance in forensic sciences. Laser-induced breakdown spectroscopy (LIBS) allows real-time chemical mapping by detecting the light emissions from laser-induced plasma and can offer powerful means of fingerprint classification based on the chemical components of the sample. During recent years LIBS has been studied one of the spectroscopic techniques with larger capability for forensic sciences. However, despite of the great sensitivity, LIBS suffers from a limited detection due to difficulties in reconstruction of overlapping fingerprints. Here, the authors propose a simple, yet effective, method of using chemical mapping to separate and reconstruct the explosive-contaminated, overlapping fingerprints. A Q-switched Nd:YAG laser system (1064 nm), which allows the laser beam diameter and the area of the ablated crater to be controlled, was used to analyze the chemical compositions of eight samples of explosive-contaminated fingerprints (featuring two sample explosive and four individuals) via the LIBS. Then, the chemical validations were further performed by applying the Raman spectroscopy. The results were subjected to principal component and partial least-squares multivariate analyses, and showed the classification of contaminated fingerprints at higher than 91% accuracy. Robustness and sensitivity tests indicate that the novel method used here is effective for separating and reconstructing the overlapping fingerprints with explosive trace.

• Structural Engineering and Mechanics
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• v.40 no.1
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• pp.105-120
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• 2011

The strengthening and rehabilitation of reinforced concrete structures with externally bonded carbon fibre reinforced polymer (FRP) laminates has shown excellent performance and, as a result, this technology is rapidly replacing steel plate bonding techniques. This paper addresses this issue, and presents results deals with the influence of external bonded CFRP-reinforcement on the time-dependent behavior of reinforced concrete beams. A total of eight reinforced concrete beams with cracked and un-cracked section, with and without externally bonded CFRP laminates, were investigated for their creep and shrinkage behavior. All the beams considered in this paper were simply supported and subjected to a uniform sustained loading for the period of six months. The main parameters of this study are two types of sustained load and different degrees of strengthening scheme for both cracked and un-cracked sections of beams. Both analytical and experimental work has been carried out on strengthened beams to investigate the cracking and deflection performance. The applied sustained load was 56% and 38% of the ultimate static capacities of the un-strengthened beams for cracked and un-cracked section respectively. The analytical values based on effective modulus method (EMM) are compared to the experimental results and it is found that the analytical values are in general give conservative estimates of the experimental results. It was concluded that the attachment of CFRP composite laminates has a positive influence on the long term performance of strengthened beams.

• Steel and Composite Structures
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• v.22 no.6
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• pp.1337-1358
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• 2016

The current study focuses on the assessment and interface response of reinforced concrete elements with composite materials (carbon fiber reinforced polymers-CFRPs, glass fiber reinforced polymers-GFRPs, textile reinforced mortars-TRM's, near surface mounted bars-NSMs). A description of the transfer mechanisms from concrete elements to the strengthening materials is conducted through analytical models based on failure modes: plate end interfacial debonding and intermediate flexural crack induced interfacial debonding. A database of 55 in total reinforced concrete columns (scale 1:1) is assembled containing elements rehabilitated with various techniques (29 wrapped with CFRP's, 5 wrapped with GFRP's, 4 containing NSM and 4 strengthened with TRM). The failure modes are discussed together with the performance level of each technique as well as the efficiency level in terms of ductility and bearing/ bending capacity. The analytical models' results are in acceptable agreement with the experimental data and can predict the failure modes. Despite the heterogeneity of the elements contained in the aforementioned database the results are of high interest and point out the need to incorporate the analytical expressions in design codes in order to predict the failure mechanisms and the limit states of bearing capacities of each technique.

• International Journal of Aeronautical and Space Sciences
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• v.3 no.1
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• pp.74-85
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• 2002

The numerical experiment has been conducted to investigate the unsteady shock wave reflecting phenomena. The cell-vertex finite-volume, Roe's upwind flux difference splitting method with unstructured grid is implemented to solve unsteady Euler equations. The $4^{th}$-order Runge-Kutta method is applied for time integration. A linear reconstruction of the flux vector using the least-square method is applied to obtain the $2^{nd}$-order accuracy for the spatial derivatives. For a better resolution of the shock wave and slipline, the dynamic grid adaptation technique is adopted. The new concept of grid adaptation technique, which is much simpler than that of conventional techniques, is introduced for the current study. Three error indicators (divergence and curl of velocity, and gradient of density) are used for the grid adaptation procedure. Considering the quality of the solution and the numerical efficiency, the grid adaptation procedure was updated up to $2^{nd}$ level at every 20 time steps. For the convenience of comparison with other experimental and analytical results, the case of interaction between the straight incoming shock wave and a sharp wedge is simulated for various flow conditions. The numerical results show good agreement with other experimental and analytical results, in the shock wave reflecting structure, slipline, and the trajectory of the triple points. Some critical cases show disagreement with the analytical results, but these cases also have been proven to show hysteresis phenomena.

• Steel and Composite Structures
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• v.44 no.3
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• pp.371-388
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• 2022

The present study tackles the problem of forced vibration of imperfect axially functionally graded shell structure with truncated conical geometry. The linear and nonlinear large-deflection of the structure are considered in the mathematical formulation using von-Kármán models. Modified coupled stress method and principle of minimum virtual work are employed in the modeling to obtain the final governing equations. In addition, formulations of classical elasticity theory are also presented. Different functions, including the linear, convex, and exponential cross-section shapes, are considered in the grading material modeling along the thickness direction. The grading properties of the material are a direct result of the porosity change in the thickness direction. Vibration responses of the structure are calculated using the semi-analytical method of a couple of homotopy perturbation methods (HPM) and the generalized differential quadrature method (GDQM). Contradicting effects of small-scale, porosity, and volume fraction parameters on the nonlinear amplitude, frequency ratio, dynamic deflection, resonance frequency, and natural frequency are observed for shell structure under various boundary conditions.

• Structural Engineering and Mechanics
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• v.7 no.2
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• pp.159-180
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• 1999

The present paper shows a new non-tensorial approach to derive basic equations for various structural analyses. It can be used directly in numerical computation procedures. The aim of the paper is, however, to show that the approach serves as an excellent tool for analytical purposes also, working as a link between analytical and numerical techniques. The paper gives a method to derive, at first, expressions for strains in general beam and shell analyses, and secondly, the governing equilibrium equations. The approach is based on the utilization of local fixed Cartesian coordinate systems. Applying these, all the definitions required are the simple basic ones, well-known from the analyses in common global coordinates. In addition, the familiar principle of virtual work has been adopted. The method will be, apparently, most powerful in teaching the theories of curved beam and shell structures for students not familiar with tensor analysis. The final results obtained have no novelty value in themselves, but the procedure developed opens through its systematic and graphic progress a new standpoint to theoretical considerations.

• Journal of international Conference on Electrical Machines and Systems
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• v.1 no.4
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• pp.517-524
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• 2012

The operation of linear oscillating system is complicated, involving system nonlinearities of both actuator and load, and variations of driving frequency in order to track the mechanical resonance. In this paper, both analytical and state-variable modeling techniques are used to investigate the influence of actuator parameters, such as back-emf/thrust force coefficient and cogging force, on the performance of linear oscillating systems. Analytical derivations are validated by simulations, and good agreements are achieved. The findings of the paper can greatly facilitate the design and evaluation processes of permanent magnet linear actuators.

• Analytical Science and Technology
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• v.6 no.4
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• pp.391-394
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• 1993

Aegiceradienol (28-noroleana-12, 17-dien-$3{\beta}$-ol) was isolated from the roasted Sanguisorbae radix and its structure was elucidated by various spectroscopic techniques. Aegiceradienol was an artifact produced by heat treatment of the herbal drug. Its content was increase as the time of heat treatment increased.