• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.218-224
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• 2014

In order to explore new coordination frameworks with novel designed 3-nitrophthalic acid and the same N-donor ancillary ligand, a series of novel coordination complexes, namely, $[Cd_2(3-NPA)_2(TBZ)_2(H_2O)_2]{\cdot}2H_2O$(1), $[Zn_2(3-NPA)_2(TBZ)_2]$(2), $[Zn_2O(3-NPA)(TBZ)(H_2O)]_n$(3), $[Co(3-NPA)(TBZ)(H_2O)]_n$(4) (3-$NPAH_2$ = 3-nitrophthalic acid), have been hydrothermally synthesized through the reaction of 3-nitrophthalic acid with divalent transition-metal salts in the presence of N-donor ancillary coligand (TBZ = thiabendazole). As a result of various coordination modes of the versatile 3-$NPAH_2$ and the coligand TBZ, these complexes exhibit structural diversity. X-ray structure analysis reveals that 1 and 2 are 0D molecular rings, while 3 and 4 are one-dimensional (1D) infinite chain polymers. And the weak O-H${\cdots}$O hydrogen bonds and C-H${\cdots}$O nonclassical hydrogen bonds as well as ${\pi}-{\pi}$ stacking also play important roles in affecting the final structure where complexes 1, 3 and 4 have 3D supramolecular architectures, while complex 2 has a 2D supramolecular network. Also, IR spectra, fluorescence properties and thermal decomposition process of complexes 1-4 were investigated.

• Nuclear Engineering and Technology
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• 제49권8호
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• pp.1752-1757
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• 2017

The aim of this study is to evaluate the radioactivity levels and radiological impacts of representative black sand samples collected from different locations in the Rashid area, Egypt. These samples were prepared and then analyzed using the high-resolution gamma ray spectroscopy technique with a high-purity germanium detector. The activity concentration ($A_c$), minimum detectable activity, absorbed gamma dose rate, external hazard index ($H_{ex}$), annual effective dose rate equivalent, radium equivalent, as well as external and internal hazard index ($H_{ex}$ and $H_{in}$, respectively) were estimated based on the measured radionuclide concentration of the $^{238}U$($^{226}Ra$) and $^{232}Th$ decay chains and $^{40}K$. The activity concentrations of the $^{238}U$, $^{232}Th$ decay series and $^{40}K$ of these samples varied from $45.11{\pm}3.1Bq/kg$ to $252.38{\pm}34.3Bq/kg$, from $64.65{\pm}6.1Bq/kg$ to $579.84{\pm}53.1Bq/kg$, and from $403.36{\pm}20.8Bq/kg$ to $527.47{\pm}23.1Bq/kg$, respectively. The activity concentration of $^{232}Th$ in Sample 1 has the highest value compared to the other samples; this value is also higher than the worldwide mean range as reported by UNSCEAR 2000. The total absorbed gamma dose rate and the annual effective dose for these samples were found to vary from 81.19 nGy/h to 497.81 nGy/h and from $99.86{\mu}Sv/y$ to $612.31{\mu}Sv/y$, which are higher than the world average values of 59 nGy/h and $70{\mu}Sv/y$, respectively. The $H_{ex}$ values were also calculated to be 3.02, 0.47, 0.63, 0.87, 0.87, 0.51 and 0.91. It was found that the calculated value of $H_{ex}$ for Sample 1 is significantly higher than the international acceptable limit of <1. The results are tabulated, depicted, and discussed within national and international frameworks, levels, and approaches.

• 한국콘텐츠학회논문지
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• 제13권7호
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• pp.440-451
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• 2013

영어마을은 한국 고유의 영어교육 모델로서, 2004년 최초 설립이래로 지금까지 전국적으로 설립 운영되어지고 있다. 이에 영어교육관계자들은 영어를 자연스럽게 사용할 수 있다는 점에서 영어마을에 많은 관심을 보이고 있다. 하지만, 영어마을 프로그램에 대한 효과성을 입증할만한 영어마을 프로그램 개발에 관한 논문은 아직 미비하다. 본 연구는 효과적인 영어마을 프로그램으로 과업중심 프로그램을 개발하고 실행하는데 목적이 있다. 연구현장으로 'A' 영어마을이 선정되었고, Brown[17]과 Long과 Crookes[36]가 제안한 모형을 바탕으로 영어마을 프로그램을 개발하였다. 본 연구는 프로그램 개발 7단계를 제시하고, 각각의 단계에 대한 설명과 활동을 소개하였다. 마지막으로 실제 적용 사례를 바탕으로 운영시 고려해야 될 점을 논의 하였고, 본 연구가 과업중심 어린이영어교육에 시사하는 바를 제시하였다.

• 한국CDE학회논문집
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• 제10권6호
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• pp.444-454
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• 2005

Recently, the requirements of multi-resolution models of a solid model, which represent an object at multiple levels of feature detail, are increasing for engineering tasks such as analysis, network-based collaborative design, and virtual prototyping and manufacturing. The research on this area has focused on several topics: topological frameworks for representing multi-resolution solid models, criteria for the level of detail (LOD), and generation of valid models after rearrangement of features. As a solution to the feature rearrangement problem, the new concept of the effective zone of a feature is introduced in the former part of the paper. In this paper, we propose a feature-based non-manifold modeling system to provide multi-resolution models of a feature-based solid or non-manifold model on the basis of the effective feature zones. To facilitate the implementation, we introduce the class of the multi-resolution feature whose attributes contain all necessary information to build a multi-resolution solid model and extract LOD models from it. In addition, two methods are introduced to accelerate the extraction of LOD models from the multi-resolution modeling database: the one is using an NMT model, known as a merged set, to represent multi-resolution models, and the other is storing differences between adjacent LOD models to accelerate the transition to the other LOD. We also suggest the volume of the feature, regardless of feature type, as a criterion for the LOD. This criterion can be used in a wide range of applications, since there is no distinction between additive and subtractive features unlike the previous method.

• 한국실내디자인학회논문집
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• 제26권6호
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• pp.53-61
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• 2017

Cityschumers experience the urban with the visual perception while walking an average speed of 4km per hour. At this time, recognition of the color field accounts for more than 70%. Therefore, in this paper the environmental color of urban street is examined by dividing the pedestrian visual field area. In the urban street, the area of the visual field area of the pedestrian is divided into Ground Plane, Roadside, Canopy and Building Wall. In addition, we observe and color survey the environmental color of Exhibition Road, which is the northern side space of South Kensington in London, which adopted the world's first shared space. The color of the visual filed area was dominated as YR, GY, Y, PB. The Ground Pland was dominated by the YR. The reason for this is that the color of the floor has changed due to the shadows of surrounding architecture and facilities. Roadside was dominated in various ways such as GY, BG, PB, B and P. Canopy was mainly composed of PB, GY, etc. It was found that the material color of the lower part of the architecture was reflected. The architecture wall was affected by the reflectance and absorption rate of the transparent material. The first image that comes to mind when thinking about the urban is the street where pedestrians walk, feel and enjoy themselves. Therefore, it is suggested that various policy frameworks for managing and managing urban planning professionals may be different from the perceptions of pedestrians active in mega cities.

• 서비스연구
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• 제5권2호
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• pp.199-216
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• 2015

서비스의 역사는 오래지만, 서비스연구의 역사는 길지 않다. 서비스기업이 증가하면서 1970년대부터 서비스마케팅 등의 학문이 활성화되었고, 21세기 들어 서비스경제가 본격 도래하면서 서비스사이언스로 확장되었다. 본 연구는 본질적인 차원에서 서비스 관련 연구를 종합적으로 리뷰하고 서비스연구의 프레임워크를 제안한다. 새로운 학제적인 융합학문으로서 서비스학이 정립되고, 이를 통해 서비스산업이 발전되고, 그리고 서비스학이 활성화되는 선순환 구조가 정착될 수 있도록 그 기본 프레임워크를 제시한다. 먼저 서비스연구의 발전 과정을 시간축으로 분석하고, 기존의 서비스 관련 연구 프레임워크를 조사하였다. 아울러 서비스연구의 주요 주제들을 프레임워크의 세부 구성 요소 차원에서 검토하였다. 기존 연구 주제들 및 초안 프레임워크들이 각 시대의 필요성을 반영하고 있지만, 서비스학에 대한 포괄적인 접근은 부족하였으므로, 서비스학의 본질에 중심을 둔 서비스연구 프레임워크를 제시하였다. 즉, 서비스본질 연구, 서비스기능 및 시스템연구, 서비스인 연구, 서비스기업 및 경영연구, 서비스산업 및 경제연구 등 다섯 개의 연구부문으로 구성되는 서비스연구 프레임워크가 제안되었다. 본 연구의 결과는 학제적인 신학문으로서 서비스학의 프레임워크를 정립하고, 서비스산업의 경쟁력을 강화하는데 학계가 기여해야할 주요 분야를 발굴하는데 유용할 것이다. 향후 보다 본질에 충실하면서도, 실용 학문으로서의 서비스학의 발전에 기여하는 후속 연구들이 필요하다.

• 간호행정학회지
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• 제12권2호
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• pp.311-322
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• 2006

Purpose: The objective of this literature review study was to identify patterns and trends of studies on leadership among nurse managers in nursing organization and suggest the direction of future researches. Methods: Research Studies on the leadership were selected from thesis and related journals, which had been conducted from 1975 to 2006.5. Search Terminologies were used "leadership". The Total number of the collected studies were 69. Results: The number of studies on leadership has been increased rapidly since 1990's. In research design, Quantitative studies were 68 except for a Qualitative study. Correlation research were 45(65.2%) among quantitative studies. Conceptual frameworks, research questions and hypotheses were involved 31.9%, 98.6%, 31.9%. In subject, General nurse is 46.4%, Head nurse and General nurse was 23.2% and Head nurse is 2.9%. All the studies used questionnaire in data collection method. Measurement tools were used 50% for Bass' MLQ(MLQ-5X). For the statistical analysis, Correlation, ANOVA, t-test were used for 20.3%, 17.4%, 10.5% respectively. The number of leadership related variables were work-related, organization-related, personal recognition or attitude, empowerment, personality. The sub-variables were used for 31 Job satisfaction. Further studies were suggested the develop of leadership program, measurement for the effect of leadership, repeated studies on leadership, the development of measurement about leadership. Conclusion: These results will be used to provide the basic data for developing leadership theory on nursing organization.

• The Journal of Advanced Prosthodontics
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• 제5권2호
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• pp.118-125
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• 2013

PURPOSE. The purpose of this study was to evaluate the effect of the span length on the fit of zirconia framework fabricated using CAD/CAM system. MATERIALS AND METHODS. Abutments for single, 4-unit and 6-unit fixed partial prostheses were fabricated. Ten zirconia frameworks were fabricated for each group. The marginal and internal gap were presented by means of replica technique and measured by measuring microscope ($AXIO^{(R)}$, Carl Zeiss, Rochester, NY) and software (I-$solution^{(R)}$, IMT i-solution Inc., Vancouver, BC, Canada). The results were statistically analyzed by multivariate analysis test and Dunnett T3 test for post hoc test (${\alpha}$=.05). RESULTS. There were statistically significant differences at 2, 4, 7, 8 points (mesio-distal section) and b, d, e, f, g (labio-lingual section). In some marginal reference points of 6-unit group (P<.05), the marginal gap were larger than 120 ${\mu}m$. CONCLUSION. Span length of zirconia core may have an influence on marginal and internal fit. Within the limitation of this study, the increase of span length of zirconia framework of 6 or more-unit fixed partial denture may decrease the marginal and internal fit.

• Journal of Electrochemical Science and Technology
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• 제9권1호
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• pp.28-36
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• 2018

Metal-organic frameworks have recently been considered very promising modifiers in electrochemical analysis due to their unique characteristics among which tunable pore sizes, crystalline ordered structures, large surface areas and chemical tenability are worth noting. In the present research, $Cu(btec)_{0.5}DMF$ was electrodeposited on the surface of glassy carbon electrode at room temperature under cathodic potential and was initially used as the active materials for the detection of $H_2O_2$. The cyclic voltammogram of $Cu(btec)_{0.5}DMF$ modified GC electrode shows distinct redox peaks potentials at +0.002 and +0.212 V in 0.1 M phosphate buffer solution (pH 6.5) corresponding to $Cu^{(II)}/Cu^{(I)}$ in $Cu(btec)_{0.5}DMF$. Acting as the electrode materials of a non-enzymatic $H_2O_2$ biosensor, the $Cu(btec)_{0.5}DMF$ brings about a promising electrocatalytic performance. The high electrocatalytic activity of the $Cu(btec)_{0.5}DMF$ modified GC electrode is demonstrated by the amperometric response towards $H_2O_2$ reduction with a wide linear range from $5{\mu}M$ to $8000{\mu}M$, a low detection limit of $0.865{\mu}M$, good stability and high selectivity at an applied potential of -0.2 V, which was higher than some $H_2O_2$ biosensors.

• 한국IT서비스학회지
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• 제15권4호
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• pp.63-72
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• 2016

Critical infrastructure has been operating in a closed environment with a completely separate information system and in the private area. However, with the current ICT environment changes due to convergence and open platforms it has increased the threats and risks to critical infrastructure. The importance of cyber security is increasing in the infrastructure control system, such as the outbreak of Ukraine blackout in 2015 by a malicious code called 'black energy'. This thesis aims to recognize the importance and necessity of protecting the critical infrastructure service, designing a security framework reflecting environmental and characteristic changes, and analyzing the management system suitable for a security framework. We also propose a theoretical basis for constructing a new security framework by comparing and analyzing seven international security management system standards, such as NIST 800-82 and IEC 62443-2-1, which are used in the control system. As a result, the environment surrounding critical infrastructure changes with the characteristics of connectivity, openness, and finality was studied, and as a response to this, many scholars and institutions present critical infrastructure security frameworks as cycle enhancement type structures, risk management structures, and management domain expansion structures. In response, the security framework encompassing these structures, CISF (Critical Infrastructure Security Framework), was designed. Additionally, through the security related international standard and criterion analysis, as a newly designed security standard suitable for CISF, IEC 62443-2-1 is reviewed and suggestions are made.