• 한국염색가공학회지
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• 제16권5호
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• pp.35-41
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• 2004

Poly(ethylene terephthalate), polyimide(Kapton), and polypropylene surfaces were modified with argon low temperature plasma by RF glow discharge at 240m Torr, 40W to investigate the surface morphological changes due to the plasma treatment using atomic force microscopy(AFM). Analysis of the AFM images and Ra(average roughness) revealed that the plasma treatment resulted in significant ablation on the surfaces. The morphological changes and surface roughness, however, were different depending on material characteristics such as heat stability, presence of amorphous region, swelling phenomenon, and molecular structure of repeating unit. It was assumed that polypropylene due to its tertiary hydrogen was ablated easily compared to poly(ethylene terephthalate), and that polyimide was more resistant to the ablation than PET due to rigid skeleton of imide and stable phenyl ring structure.

• 전기학회논문지
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• 제66권6호
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• pp.962-967
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• 2017

The Diamond-Like-Carbon (DLC) coating is a new carbon-based amorphous material. Carbon ions in the plasma are electrically accelerated and collide with the substrate to form a thin film. This film has similar properties to diamonds such as high surface hardness, low coefficient of friction, corrosion resistance and durability that do not react with acids and bases. Also, since there is no thermal deformation, it can be printed at room temperature. and coated on almost all materials such as paper, polymer, ceramics and various metals even aspheric lens it is possible to mirror surface coating with excellent surface roughness. In this paper, we have analyzed the DLC film formed by Filtered Arc Ion Plating (Filtered AIP) process.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2015년도 춘계학술대회 논문집
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• pp.101-101
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• 2015

Photoelectrochemical water splitting is considered as a promising method of transforming solar energy into chemical energy stored in the type of hydrogen. An n-type $WO_3$ semiconductor is one of the most promising photoanodes for hydrogen production from water splitting. Films annealed at lower temperatures consisted of amorphous, whereas films annealed above $500^{\circ}C$ comprised solely of monoclinic $WO_3$. In this study, we observed photoactivity of $WO_3$ as increasing thickness of $WO_3$. And it shows good photoacivity as thickness increases. Also we tried to improve photoactivity through surface modification and bulk modification by using hydrogen treatment and conducting polymer. The photocurrent was measured in potentiostatic method with the three electrode system. A Pt wire and Ag / AgCl electrode were used as the counter electrode and the reference electrode, respectively. photocurrent-time (I-T) curve was measured at a bias potential of 0.79 V.

• 한국정밀공학회지
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• 제28권12호
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• pp.1403-1410
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• 2011

Creep characteristic is an important failure mechanism when evaluating engineering materials that are soft material as polymers or used as mechanical elements at high temperatures. One of the popular thermo-elastic polymers, Polymethyl methacrylate(PMMA) which is used broadly for engineering polymer, as it has excellent mechanical and thermal properties compared to other polymers, was studied for creep characteristic at various level of stresses and temperatures. From the experimental results, the creep limit of PMMA at room temperature is 85 % of tensile strength. which is higher than that of PE (75%)at room temperature. Also the creep limits decreased to nil linearly as the temperatures increased, up to $120^{\circ}C$ of the melting point($267^{\circ}C$). Also the first and third stage among the three creep stages were non-existent nor were there any rupture failure which occurred for many metals at high temperatures.

• Bulletin of the Korean Chemical Society
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• 제14권6호
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• pp.708-712
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• 1993

The Polymerization of p-chlorophenyl propargyl ether (CPE) was carried out using various transition metal catalysts. The catalytic activity of $MoCl_{5}$-based catalysts was greater than that of $WCl_6$-based catalysts. $MoCl_5$ alone and $MoCl_{5}$-cocatalyst systems polymerized CPE very effectively to give a high yield of poly(CPE). In most cases, the polymer yield was quantitative and the average molecular weight $({\bar{M}}n)$ was in the range of 9,000 and 17,000. The NMR, IR, UV-visible spectra indicated that the present poly(CPE) has a linear conjugated polyene structure having p-chlorophenyl oxymethylene substituent. The poly(CPE) was mostly dark-brown colored powder and was completely soluble in various organic solvents such as chloroform, methylene chloride, THF, chlorobenzene, etc. The X-ray diffraction analysis indicated that the present poly(CPE) is amorphous.

• Bulletin of the Korean Chemical Society
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• 제17권7호
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• pp.607-612
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• 1996

A series of new NLO-active poly(4-nitrophenylallylamine) derivatives was synthesized by the nucleophilic substitution reaction of several substituted 4-nitrohalobenzenes and poly(allylamine hydrochloride). All polymers obtained were amorphous and their glass transition temperatures (Tg) were observed around 148-160 ℃. For each of these polymers, their specific Tg values were dependent on characteristic electronic structures. UV-visible absorption spectra showed maximum absorption intensity at 355-393 nm for π-π* transition of alkylaminonitrophenyl groups. The χ(2)value of poly(4-nitrophenylallylamine), as determined by the second harmonic generation at 1064 nm, for a thin polymer film poled at an elevated temperature, was 1.4x10-8esu. The third-order NLO properties of poly(4-nitrophenylallylamine) derivatives were evaluated through measurement of degenerate four-wave mixing technique and χ(3) coefficient in the range of 2.7~3.2x10-12 esu at 602 nm was found with 400 fs laser pulses.

• Bulletin of the Korean Chemical Society
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• 제20권3호
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• pp.333-336
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• 1999

The polyaniline films with various insoluble parts are fabricated. The oxidation state (1-y) of these polyaniline is 0.53 and 0.54, respectively. To control the interchain and intrachain interaction of the polymer, the polyaniline films are stretched with appropriate ratio. The insoluble part of polyaniline synthesized at room temperature (low molecular weight) is 12%-76% and that of polyaniline synthesized at 0 'IC (intermediate molecular weight) is 65%-89%. The low molecular weight polyaniline films with various drawing ratios have amorphous structure. In the intermediate weight polyaniline films, the crystallinity of films increases with drawing ratio as well as insoluble part. The difference of the insoluble part affects electrical conductivity which is increased dramatically with draw ratio. In particular, the higher insoluble part caused greater increase in electrical conductivity.

• 한국기계가공학회지
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• 제21권5호
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• pp.77-83
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• 2022

A high-hardness tool material is required to reduce extreme abrasive wear when drilling carbon fiber reinforced plastic (CFRP). Single-crystal diamond is the hardest material in the world, but it is very expensive to be used as a cutting tool. Polycrystalline diamond (PCD) is a diamond grit fused at a high temperature and pressure, and diamond-like carbon (DLC) is an amorphous carbon with high hardness. This study compares DLC coatings and PCD inserts to conventional TiAlN-coated tungsten carbide drills. In fiberglass and carbon fiber reinforced polymer drilling, the tool wear of DLC-coated carbide was approximately half that of TiAlN-coated tools, and slight tool wear occurred in the case of PCD insert end drills.

• 전기화학회지
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• 제3권2호
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• pp.85-89
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• 2000

Lithium ion Battery(LIB)의 음극 활물질로써 리튬을 대체하기 위한 노력으로 phenol resin을 탄화시킨 탄소재료를 사용하였다. Phenol resin을 소성하면 축합반응을 일으키면서 탄화되어 무정형 탄소가 된다. 무정형 탄소는 층간거리가 넓어 리튬의 삽입과 탈리가 용이하지만 탄소간의 결합력이 약하여 구조적 붕괴가 일어난다. 이러한 문제를 해결하기 위해 세공형성제로서 $ZnCl_2$를 사용하였다. $ZnCl_2$는 생성된 물질에서 3차원적 망상구조로 성장하는 개방세공을 형성하는 세공형성제로서 뿐만 아니라, 벌크 첨가제가 도핑된 느슨한 구조를 형성하는 미세세공 형성제로서 작용하였다. SEM을 통해서 구조적 차이를 알 수 있었으며, XRD분석으로 층간의 거리를 알 수 있었다. CV측정을 통해 두 가지 샘플에 대한 산화와 환원 반응의 차이를 알아보았다.

• 대한화학회지
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• 제50권3호
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• pp.196-202
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• 2006

점탄성 용융 폴리우레탄의 자체확산분포가 완화스펙트럼과 자체확산분포 관계식으로부터 얻어졌다. ester, PCL PCL dyed 형의 용융 폴리우레탄의 완화스펙트럼은 실험적인 응력완화 곡선을 Ree-Eyring and Maxwell non-Newtonian model(REM 모델)이론식에 적용시켜서 얻는다. 용융폴리우레탄의 응력완화 실험은 온도조절 장치가 있는 physica 레오메타를 이용하여 여러 온도에서 수행되었다. 이론적인 완화스펙트럼은 REM model로부터 유도한 이론적인 완화스펙트럼식을 프로그램화한 컴퓨터 계산에서 구하였다. 폴리우레탄 시료의 자체확산과 비결정 영역의 홀거리가 응력완화 실험에 의해서 연구 조사되었다. 비결정 영역에서의 유동단위의 확산을 연구하기 위해서 확산계수와 홀부피가 유변학적인 파라메타와 결정크기로부터 계산되었다. 폴리우레탄 시료의 완화스펙트럼과 자체확산은 유동 단위의 분자량분포, 점도, 홀부피, 활성화에너지와 밀접한 관계가 있는 것을 알 수 있다.