• Title/Summary/Keyword: Amorphous Boron

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Development of Fuel-Rich Propellant Using High Energy Metal Fuel (고에너지 금속 연료를 이용한 Fuel-Rich 추진제 개발)

  • Kim, Hye-Lim;Shin, Kyung-Hoon;Choi, Sung-Han;Lee, Won-Bok;Kim, Jun-Hyung;Ko, Seung-Won
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.424-428
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    • 2012
  • Air-breathing Propulsion System is one of the promising propulsion systems because of low cost, easy storage, compactness and simplicity. A study of gas generator propellant for air-breathing propulsion system was performed in this paper. Amorphous Boron Powder was applied in propellant with various kinds of additives to determine combustion characteristics. And boron beads were made to apply them to the propellant. Combustion characteristics of propellant using amorphous boron powder and boron beads was compared.

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Novel Properties of Boron Added Amorphous Rare Earth-transition Metal Alloys for Giant Magnetostrictive and Magneto-optical Recording Materials

  • Jai-Young Kim
    • Journal of Magnetics
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    • v.3 no.3
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    • pp.78-81
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    • 1998
  • Large magneto crystalline anisotropy energy and demagnetization energy of rare earth-transition metal (RF-TM) alloys play roles of bottlenecks towards their commercial applications for giant magnetostrictive and blue wavelength magneto optical recording materials, respectively. To solve the above problems, boron is added into amorphous RE-TM alloys to produce its electron transferring. The boron added amorphous RE-TM alloys show novel magnetic and magneto-optical properties as follows; 1) an amorphous $(Sm_{33}Fe_{76})$97B3 alloy obtains the magnetostriction of$ -550{times}10^{-6}$ at 400 Oe compared with saturation magnetostriction of$ -60{\times}10^{-6}$ in conventional Ni based alloys, 2) an amorphous$ (Nd_{33}Fe_{67})_{95}B_5$ alloy increases effective magnetic anisotropy to$ -0.5{\times}10^{-6} ergs/cm^3 from -3.5{\times}10^6 ergs/cm^3$ without boron, which correspond to the polar Kerr rotation angles of 0.52$^{\circ}$and 0.33$^{\circ}$, respectively. These results attribute to selective 2p-3d electron orbits exchange coupling (SEC).

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Mechanical Properties and Neutron Shielding Performance of Concrete with Amorphous Boron Steel Fiber (비정질 붕소강 섬유를 혼입한 콘크리트의 역학적 성능 및 중성자 차폐성능 평가)

  • Lee, Jun Cheol;Kim, Wha Jung
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.1
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    • pp.9-14
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    • 2017
  • Mechanical properties and neutron shielding performance of concrete with amorphous boron steel fiber have been investigated in this study. The measurement of this investigation includes air contents, slump loss, compressive strength, flexural strength, flexural toughness and neutron shielding rate. Four different fiber volume fractions were selected ranging from 0.25% to 1.0% by volume for the amorphous boron steel fibers. The testing results showed that the flexural toughness and the neutron shielding rate were increase with the increase of volume fraction for amorphous boron steel fiber. Based on the result, it is concluded that the concrete with the amorphous boron steel fiber can be effectively applied to shield the neutron and to improve mechanical properties.

Mechanical Properties and Neutron Shielding Rate of Concrete with Borosilicate-Glasses and Amorphous Boron Steel Fiber (붕규산유리 및 비정질 붕소강 섬유를 혼입한 콘크리트의 역학적 성능 및 중성자 차폐성능 평가)

  • Lee, Jun-Cheol
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.269-275
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    • 2016
  • In this study, the mechanical properties and the neutron shielding rate of concrete with the borosilicate glass and the amorphous boron steel fiber were investigated. The measures of this investigation includes air contents, slump loss, compressive strength, static modulus of elasticity, compressive toughness, flexural strength, flexure toughness and neutron shielding rate. As a result, the neutron shielding rate of the concrete with borosilicate glasses increased even though the compressive strength and flexural strength decreased in comparison with that of plain concrete. Also, the mechanical toughness and the neutron shielding rate of the concrete with amorphous boron steel fiber increased in comparison with that of plain concrete.

Effect of Additives on the Characteristics of Amorphous Nano Boron Powder Fabricated by Self-Propagating High Temperature Synthesis (자전연소합성법을 이용한 비정질 나노 붕소 분말 특성에미치는 첨가제의 영향)

  • Joo, Sin Hyong;Nersisyan, Hayk H.;Lee, Tae Hyuk;Cho, Young Hee;Kim, Hong Moule;Lee, Huk Hee;Lee, Jong Hyeon
    • Korean Journal of Materials Research
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    • v.25 no.12
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    • pp.659-665
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    • 2015
  • The self-propagating high temperature synthesis approach was applied to synthesize amorphous boron nano-powders in argon atmospheres. For this purpose, we investigated the characteristics of a thermally induced combustion wave in the $B_2O_3+{\alpha}Mg$ system(${\alpha}=1.0-8.0$) in an argon atmospheres. In this study, the exothermic nature of the $B_2O_3-Mg$ reaction was investigated using thermodynamic calculations. Experimental study was conducted based on the calculation data and the SHS products consisting of crystalline boron and other compounds were obtained starting with a different initial molar ratio of Mg. It was found that the $B_2O_3$ and Mg reaction system produced a high combustion temperature with a rapid combustion reaction. In order to regulate the combustion reaction, NaCl, $Na_2B_4O_7$ and $H_3BO_3$ additives were investigated as diluents. In an experimental study, it was found that all diluents effectively stabilized the reaction regime. The final product of the $B_2O_3+{\alpha}Mg$ system with 0.5 mole $Na_2B_4O_7$ was identified to be amorphous boron nano-powders(< 100 nm).

Durability of Nozzle Materials for Strip Casting of Amorphous Alloys (비정질합금 박판 제조용 노즐 재료의 내구성평가)

  • Kang, Bok-Hyun;Kim, Ki-Young
    • Journal of Korea Foundry Society
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    • v.31 no.5
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    • pp.267-273
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    • 2011
  • Erosion and thermal shock resistance of several refractory materials have been investigated, which are expected to be used as nozzles in a planar flow casting equipment for amorphous alloys. The test was conducted on five materials; graphite, boron nitride, fused silica, alumina and zirconia. Test specimens were preheated and dipped into the melt of carbon steel and amorphous alloys. Some test specimens were rotated to develop high erosion and to shorten the test periods. Fused silica and boron nitride specimens showed the excellent erosion and thermal shock resistance irrespective of the kind of melt and melting atmosphere.

Boron Doping Method Using Fiber Laser Annealing of Uniformly Deposited Amorphous Silicon Layer for IBC Solar Cells (IBC형 태양전지를 위한 균일하게 증착된 비정질 실리콘 층의 광섬유 레이저를 이용한 붕소 도핑 방법)

  • Kim, Sung-Chul;Yoon, Ki-Chan;Kyung, Do-Hyun;Lee, Young-Seok;Kwon, Tae-Young;Jung, Woo-Won;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.456-456
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    • 2009
  • Boron doping on an n-type Si wafer is requisite process for IBC (Interdigitated Back Contact) solar cells. Fiber laser annealing is one of boron doping methods. For the boron doping, uniformly coated or deposited film is highly required. Plasma enhanced chemical vapor deposition (PECVD) method provides a uniform dopant film or layer which can facilitate doping. Because amorphous silicon layer absorption range for the wavelength of fiber laser does not match well for the direct annealing. In this study, to enhance thermal affection on the existing p-a-Si:H layer, a ${\mu}c$-Si:H intrinsic layer was deposited on the p-a-Si:H layer additionally by PECVD. To improve heat transfer rate to the amorphous silicon layer, and as heating both sides and protecting boron eliminating from the amorphous silicon layer. For p-a-Si:H layer with the ratio of $SiH_4$ : $B_2H_6$ : $H_2$ = 30 : 30 : 120, at $200^{\circ}C$, 50 W, 0.2 Torr for 30 minutes, and for ${\mu}c$-Si:H intrinsic layer, $SiH_4$ : $H_2$ = 10 : 300, at $200^{\circ}C$, 30 W, 0.5 Torr for 60 minutes, 2 cm $\times$ 2 cm size wafers were used. In consequence of comparing the results of lifetime measurement and sheet resistance relation, the laser condition set of 20 ~ 27 % of power, 150 ~ 160 kHz, 20 ~ 50 mm/s of marking speed, and $10\;{\sim}\;50 {\mu}m$ spacing with continuous wave mode of scanner lens showed the correlation between lifetime and sheet resistance as $100\;{\Omega}/sq$ and $11.8\;{\mu}s$ vs. $17\;{\Omega}/sq$ and $8.2\;{\mu}s$. Comparing to the singly deposited p-a-Si:H layer case, the additional ${\mu}c$-Si:H layer for doping resulted in no trade-offs, but showed slight improvement of both lifetime and sheet resistance, however sheet resistance might be confined by the additional intrinsic layer. This might come from the ineffective crystallization of amorphous silicon layer. For the additional layer case, lifetime and sheet resistance were measured as $84.8\;{\Omega}/sq$ and $11.09\;{\mu}s$ vs. $79.8\;{\Omega}/sq$ and $11.93\;{\mu}s$. The co-existence of $n^+$layeronthesamesurfaceandeliminating the laser damage should be taken into account for an IBC solar cell structure. Heavily doped uniform boron layer by fiber laser brings not only basic and essential conditions for the beginning step of IBC solar cell fabrication processes, but also the controllable doping concentration and depth that can be established according to the deposition conditions of layers.

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Suppression of Boron Penetration into Gate Oxide using Amorphous Si on $p^+$ Si Gated Structure (비정질 실리론 게이트 구조를 이용한 게이트 산화막내의 붕소이온 침투 억제에 관한 연구)

  • Lee, U-Jin;Kim, Jeong-Tae;Go, Cheol-Gi;Cheon, Hui-Gon;O, Gye-Hwan
    • Korean Journal of Materials Research
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    • v.1 no.3
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    • pp.125-131
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    • 1991
  • Boron penetration phenomenon of $p^{+}$ silicon gate with as-deposited amorphous or polycrystalline Si upon high temperature annealing was investigated using high frequency C-V (Capacitance-Volt-age) analysis, CCST(Constant Current Stress Test), TEM(Transmission Electron Microscopy) and SIMS(Secondary Ion Mass Spectroscopy), C-V analysis showed that an as-deposited amorphous Si gate resulted in smaller positive shifts in flatband voltage compared wish a polycrystalline Si gate, thus giving 60-80 percent higher charge-to-breakdown of gate oxides. The reduced boron penetration of amorphous Si gate may be attributed to the fewer grain boundaries available for boron diffusion into the gate oxide and the shallower projected range of $BF_2$ implantation. The relation between electron trapping rate and flatband voltage shift was also discussed.

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The Effect of Boron Content and Deposition Temperature on the Microstructure and Mechanical Property of Ti-B-C Coating Prepared by Plasma-enhanced Chemical Vapor Deposition (PECVD법에 의해 증착된 Ti-B-C코팅막 내의 보론함량과 증착온도에 따른 미세구조 및 기계적 물성의 변화)

  • Ok, Jung-Tae;Song, Pung-Keun;Kim, Kwang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.38 no.3
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    • pp.106-111
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    • 2005
  • Ternary Ti-B-C coatings were synthesized on WC-Co and Si wafers substrates by a PECVD technique using a gaseous mixture of $TiCl_4,\;BCl_3,\;CH_4,\;Ar,\;and\; H_2$. The effects of deposition variables such as substrate temperature, gas ratio, $R_x=[BCl_3/(CH_4+BCl_3)]$ on the microstructure and mechanical properties of Ti-B-C coatings were investigated. From our instrumental analyses, the synthesized Ti-B-C coatings was confirmed to be composites consisting of nanocrystallites TiC, quasi-amorphous TiB2, and amorphous carbon at low boron content, on the contrary, nanocrystallites $TiB_2$, quasi-amorphous TiC, and amorphous carbon at relatively high boron content. The microhardness of the Ti-B-C coatings increased from $\~23 GPa$ of TiC to $\~38 GPa$ of $Ti_{0.33}B_{0.55}C_{0.11}$ coatings with increasing the boron content. The $Ti_{0.33}B_{0.55}C_{0.11}$ coatings showed lower average friction coefficient of 0.45, in addition, it showed relatively better wear behavior compared to other binary coatings of $TiB_2$ and TiC. The microstruture and microhardness value of Ti-B-C coatings were largely depend on the deposition temperature.

Anode Properties of Boron Doped Polyacene Derived from Phenolic Resin (페놀수지로부터 유도된 Boron을 Doping한 polyacene계 부극의 특성)

  • Oh, Won-Chun;Park, Seung-Huyk;Kim, Bum-Soo
    • Analytical Science and Technology
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    • v.13 no.6
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    • pp.705-711
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    • 2000
  • We have studied the structural characterization, surface morphology and electrical properties for boron dopped polyacene anode material from phenolic resin for lithium secondary battery. The boron dopped anode material were characterized as boron contents of 5, 10, 15 and 20%, respectively. From the X-ray results, the all kinds of compounds were observed for the diffraction patterns for typical amorphous carbons. The SEM morphology showed formation of semi spherical granule for the boron dopped compounds. As the result of the electrical charge/discharge and impedance data, the 10 and 15% boron dopped materials showed good properties on the ions and electron transfer effect of battery.

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