• Journal of Korean Society for Atmospheric Environment
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• 제27권4호
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• pp.387-394
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• 2011

A study on the removal of sulfur dioxide and nitrogen oxide was carried out using a non-thermal nano-pulse corona discharger at different gas temperatures. Pulse voltage with a high voltage of 50 kV, a pulse rising time of about 100 ns, a full width at half maximum of about 500 ns and a frequency of 1 kHz was applied to a wire-cylinder corona reactor. Ammonia and propylene gases were added into the corona reactor as additives with a static mixer. Ammonia addition had less effect on $SO_2$ reduction at the higher temperature because of the retardation of ammonium sulfate formation. However, propylene addition enhanced NO reduction at higher temperature due to increased gas mixture. $SO_2$ was further removed at the mixed $SO_2$ and NO gas due to increased $NO_2$ by the conversion of NO. The addition of ammonia and propylene gases was more highly dominant for the removal of sulfur dioxide compared to the sole pulse corona without the additives. However, the specific energy density per unit concentration of pulse corona as well as propylene additive was an important factor to remove NO gas. Therefore, the specific energy density per unit concentration of 0.04 Wh/($m^3{\cdot}ppm$) was necessary for the NO removal of more than 80% with the concentration ratio of 2.0 for propylene and NO. Hydrogen peroxide was another alternative additive to remove both $SO_2$ and NO in the nano-pulse corona discharger.

• Transactions of the Korean Society of Mechanical Engineers A
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• 제24권11호
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• pp.2762-2770
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• 2000

The refuse incineration plant has an important role in saving the combustion energy for local heating system. But harmful combustion gas(NOx etc.) leads to some serious environmental problem. To reduce the gas, a SCR(Selective Catalytic Reduction)system is installed and it is controlled by adjusting the flow of ammonia gas(NH3) . In this paper, we apply a repetitive control method to reduce NOx by adjusting the flow of ammonia gas for SCR system in a refuse incineration plant which is located in Haeundae, Pusan, Firstly, we analyze the inlet NOx period by FFt method, and verify its periodic variations. Secondly, we design a repetitive control system by using state space model method. Lastly, the effectiveness of repetitive control system is shown by comparing to a conventional PID control in simulation and experimental results.

• Journal of ILASS-Korea
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• 제11권1호
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• pp.30-38
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• 2006

High temperature furnaces such as power plant and incinerator contribute considerable part of NOx generation and face urgent demand of De-NOx system. Reducing agent is injected into the flue gas flow to activate do-NOx system. Almost SCR system adopt vaporized ammonia injection system. Vaporizer, dilution system and additional space are needed to gasify and inject ammonia. Liquid spray injection system can simplify and economize post-treatment system of flue gas. In this study, mixing caused by gas or liquid injection of reducing agent into flue gas duct was investigated experimentally. Carbonated water was used as tracer and simulated agent and mixing of liquid spray in a duct flow was studied. To achieve that, the angle of attack of static mixer is simulated and $CO_2$ concentration is measured.

• Transactions of the Korean hydrogen and new energy society
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• 제24권6호
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• pp.510-517
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• 2013

The ammonia-water based power generation cycle utilizing liquefied natural gas (LNG) as its heat sink has attracted much attention, since the ammonia-water cycle has many thermodynamic advantages in conversion of low-grade heat source in the form of sensible energy and LNG has a great cold energy. In this paper, we carry out thermodynamic performance analysis of a combined power generation cycle which is consisted of an ammonia-water regenerative Rankine cycle and LNG power generation cycle. LNG is able to condense the ammonia-water mixture at a very low condensing temperature in a heat exchanger, which leads to an increased power output. Based on the thermodynamic models, the effects of the key parameters such as source temperature, ammonia concentration and turbine inlet pressure on the characteristics of system are throughly investigated. The results show that the thermodynamic performance of the ammonia-water power generation cycle can be improved by the LNG cold energy and there exist an optimum ammonia concentration to reach the maximum system net work production.

• Journal of the Korea Convergence Society
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• 제12권5호
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• pp.185-190
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• 2021

An electrolyzed-acidic water treatment was investigated as a methods for removing ammonia, which is a cause of odor in life environment. The prepared electrolyzed-acidic water was found out as stable solvent capable of neutralizing weak alkaline ammonia by measuring changes in pH and ORP. It was found out that ammonia was removed from the mixture solution of electrolyzed-acidic water and ammonia water by the UV-vis absorbance analysis and electrochemical open-circuit potential measurement. The neutralized ammonia by electrolyzed-acidic water and effectively removed odor was measured using ammonia gas detecter. Consequently, we recommend the electrolyzed-acidic water can effectively and safely remove ammonia in eco-friendly.

• Corrosion Science and Technology
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• 제21권6호
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• pp.514-524
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• 2022

Carbon emissions from fuel consumption have been pointed by scientists as the cause of global warming. In particular, fossil fuels are known to emit more carbon when burned than other types of fuels. In this regard, International Maritime Organization has announced a regulation plan to reduce carbon dioxide emissions. Therefore, recently, Liquefied Natural Gas propulsion ships are responding to such carbon reduction regulation. However, from a long-term perspective, it is necessary to use carbon-free fuels such as hydrogen and ammonia. Nitrogen oxides might be generated during ammonia combustion. There is a possibility that incompletely burned ammonia is discharged. Therefore, rather than being used as a direct fuel, Ammonia is only used to reduce NO_X such as urea solution in diesel vehicle Selective Catalyst Reduction. Currently, LPG vehicle fuel feed system studies have evaluated the durability of combustion injectors and fuel tanks in ammonia environment. However, few studies have been conducted to apply ammonia as a ship fuel. Therefore, this study aims to evaluate corrosion damage that might occur when ammonia is used as a propulsion fuel on ships.

• Journal of Biosystems Engineering
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• 제28권5호
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• pp.457-464
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• 2003

The purpose of this study was to develop a pilot scale bio-filter system removing ammonia gas with microorganisms. The system consisted of chaff(filter medium), a blower, a temperature sensor, a moisture sensor, a solenoid valve, and a heating system. Temperature and moisture contents were controlled via a PC to provide the microorganisms with proper environment. The microorganisms used in this study were Bacillius. coagulans NLRI T-6 and Pseudononas. putida NLRI S-21 of bacilli. Performance tests were performed to evaluate gas removal rate during 20 days. The result was shown that the removal rate was high in early days and gradually dropped below 90% without injecting the microbes. However, it was shown that when injecting the microbes, the removal rate was almost 100% and pH value was maintained at between 7 and 9 during the whole twenty-day period.

• Korean Journal of Soil Science and Fertilizer
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• 제43권6호
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• pp.975-977
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• 2010

Ammonium nitrogen is volatilized as ammonia at high pH soil. This study was conducted to observe an injury cause of egg plant grown in a high pH rockwool amended with ammonium phosphate. The etiolation symptom (yellowing) was appeared on veins of a leaf but not in healthy root when nutrient solution containing ammonium phosphate in addition to essential elements was applied in a top soil of which pH was 7.8. However, the same symptom did not appeared in the egg plant from the top soil in which the nutrition solution containing potassium phosphate instead of ammonium phosphate was applied. pHs were similar between these two different solutions. This revealed that the injury was caused by ammonia gas.

• Korean Journal of Environmental Agriculture
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• 제41권4호
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• pp.230-235
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• 2022

BACKGROUND: Ammonia gas emitted from nitrogen fertilizers applied in agricultural land is an environmental pollutant that catalyzes the formation of fine particulate matter (PM2.5). A significant portion (12-18%) of nitrogen fertilizer input for crop cultivation is emitted to the atmosphere as ammonia gas, a loss form of nitrogen fertilizer in agricultural land. The widely practiced method for fertilizer use in agricultural fields involves spraying the fertilizers on the surface of farmlands and mixing those with the soils through such means as rotary work. To test the potential reduction of ammonia emission by nitrogen fertilizers from the soil surface, we have added N, P, and K at 2 g each to the glass greenhouse soil, and the ammonia emission was analyzed. METHODS AND RESULTS: The treatment consisted of non-fertilization, surface spray (conventional fertilization), and soil depth spray at 10, 15, 20, 25, and 30 cm. Ammonia was collected using a self-manufactured vertical wind tunnel chamber, and it was quantified by the indophenol-blue method. As a result of analyzing ammonia emission after fertilizer treatments by soil depth, ammonia was emitted by the surface spray treatment immediately after spraying the fertilizer in the paddy soil, with no ammonia emission occurring at a soil depth of 10 cm to 30 cm. In the upland soil, ammonia was emitted by the surface spray treatment after 2 days of treatment, and there was no ammonia emission at a soil depth of 15 cm to 30 cm. Lettuce and Chinese cabbage treated with fertilizer at depths of 20 cm and 30 cm showed increases of fresh weight and nutrient and potassium contents. CONCLUSION(S): In conclusion, rather than the current fertilization method of spraying and mixing the fertilizers on the soil surface, deep placement of the nitrogen fertilizer in the soil at 10 cm or more in paddy fields and 15 cm or more in upland fields was considered as a better fertilization method to reduce ammonia emission.

• KSBB Journal
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• 제22권3호
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• pp.162-167
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• 2007

Ammonia gas is one of the major pollutants which cause environmental pollution and damage to the human and the livestock. The objective of this study was to investigate the important parameters for the development of efficient removal of ammonia gas by Bacillius subtilis IB101 and to optimize the medium composition for the mass production of B. subtilis IB101. The ammonia gas removal efficiency was evaluated at different growth phases and by changing culture conditions (temperature, pH). The effect of $(NH_4)_2SO_4$ concentration in preculture medium was examined. Medium optimization for the mass production of B. subtilis IB101 was performed by using Plackett-Burman design and one factor at a time method. The removal of ammonia gas was more efficient at exponential phase by 20% than at stationary phase. The ammonia gas removal was the highest at pH 4 and 30 $^{\circ}C$. There was not any significant influence of concentration of $(NH_4)_2SO_4$ on the removal of ammonia gas. The components of optimized medium for the production of viable Bacillus subtilis IB101 was yeast extract 10 g/l, soluble starch 2.5 g/l, $MgSO_4$ 6 g/l, $CaCl_2$ 1.55 g/l, $(NH_4)_2SO_4$ 5 g/l, $KH_2PO_4$ 0.75 g/l, soy bean meal 8 g/l.