• Title/Summary/Keyword: Ammonia Gas

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Effects of Microbial Additives on the Chemical Characteristics, Microbes, Gas Emissions, and Compost Maturity of Hanwoo Steer Manure (미생물 첨가제가 거세한우 분의 이화학적 특성, 미생물 성상, 가스 발생량 및 퇴비 부숙도에 미치는 영향)

  • Young Ho Joo;Myeong Ji Seo;Seung Min Jeong;Ji Yoon Kim;Sam Churl Kim
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.42 no.4
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    • pp.264-269
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    • 2022
  • The present study investigated effects of microbial additives on the floor of Hanwoo steer manure in barn. The treatment following: without additives (CON); additives (AMA). Each treatment used 3 barns as replication and each barn contained 5 Hanwoos. The Hanwoo steer manure in barns was sub-sampled from 5 sides of pen at 0, 4 and 12 weeks. The sub-samples were used for analyses of chemical compositions, microbial counts, gas emissions and compost maturity. The concentrations of moisture, organic matter, total nitrogen and carbon-to-nitrogen (C/N ratio) of Hanwoo steer manure before the microbial additives were each 59.1%, 83.2%, 1.78% and 50.0%, respectively. The counts of lactic acid bacteria, Yeast, Bacillus subtilis, and Escherichia coli (E. coli) were each 5.94, 6.83, 7,28 and 5.52 cfu/g, but Salmonella was not detected. The ammonia-N gas was 4.67 ppm, but hydrogen sulfide gas was not detected. After 4 weeks, moisture, organic matter, total nitrogen, pH and yeast count were lowest (p<0.05). The lactic acid bacteria, yeast, Escherichia coli (E. coli) and ammonia-N gas were not effects of microbial additives. All treatments was not detected at Salmonella count and hydrogen sulfide emission, and compost maturity was completed. After 12 weeks, the lactic acid bacteria and Bacillus subtilis were highest in AMA, while moisture, yeast and E. coli were lowest (p<0.05). The ammonia-N gas was not effect by microbial additive. Salmonella and hydrogen sulfide emission were not detected in all treatments, and compost maturity was completed. Therefore, in present study, the microbial additive did not affect of gas and compost maturity, but the pathogenic microorganism such as E. coli, were inhibited by microbial additives.

Quantitative Measurement of General Odorant Using Electroantennogram of Male Silkworm Moth, Bombyx mori

  • Yun, Enug-Sik;Park, Tai-Hyun
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.5 no.2
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    • pp.150-152
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    • 2000
  • The investigation of electroantennogram (EAG) using insect antennad has been primarily focused on the measurement of insect pheromone. Insect has highly specialized olfactroy receptors inside their antennae. In this paper, EAG was applied to detect general oborants and the feasibility of this system for the olfactroy biosensor was investigated. Electroantennogram measurement was carried out using the antennae of male silkworm moth, bombyx mori, and ammonia gas as the model odorant. EAG parametres including peak ampiltude increased linearly with the ammonia concentration and the reproducible electrical signals were generated at least for 2 hrs after the antenna was cut off from the sulkworm moth.

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Isolation and Characteristics of Novel Ammonia Oxidizing Bacteria Brevundimonas diminuta (암모니아산화세균 Brevundimonas diminuta의 분리 및 암모니아 산화 특성)

  • Kwon, Hyuk-Ku;Jung, Joon-Oh
    • Journal of Environmental Health Sciences
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    • v.33 no.4
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    • pp.293-298
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    • 2007
  • The microorganism for ammonia gas removal was isolated from composting product. This was identified as Brevundimonas diminuta by morphological, biochemical characteristics study and 16S rDNA sequence analysis. Optimal incubation temperature for cell growth and oxidizing ability of $NH_4-N$ was $30^{\circ}C$ and optimal initial pH was 7. Glucose affected the growth of cell and the removal of $NH4^+$. The growth rate of the isolates were increased when grown in the presence of 0.05-1%(w/v) glucose in the selective medium and lurker increases in glucose concentration to 2% caused significant decreases in the cell growth and oxidizing ability of $NH4^+$.

Failure of Ammonia Synthesis Converter Due to Hydrogen Attack and Its On-Stream Assessment Using ToFD Method

  • Albiruni, Farabirazy;Lee, Joon-Hyun
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.132-137
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    • 2008
  • A failure analysis of ammonia converter which suffered hydrogen attack in two years since its initial operating time was presented. It is constructed from 2.25 Cr.1 Mo steel. Analysis showed that the failure on closing seam weld joint was due to local improper post weld heat treatment (PWHT). Improper PWHT can introduce high residual stresses in thick-walled pressure vessel. High residual stress level in weld joint is very prone to hydrogen attack for any components which are operating in hydrogen gas environment. The repair procedures based on the principle to decrease the residual stress then proposed. The repair was controlled very carefully by applying several nondestructive tests in the each stage of repair. To assure the successful of the proposed repair, after one year since repair time, high temperature ultrasonic and TOFD methods were applied on-stream to this equipment in order to evaluate its post repair condition. The two methods showed good results on the repaired area.

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Effect of Dietary Yeast (Saccharomyces exiguus) on Growth Performance, Cecal Microflora and Fecal Ammonia Gas in Broiler Chickens (효모(Saccharomyces exiguus)의 급여가 육계 생산성, 맹장내 미생물 및 분내 암모니아 가스 발생에 미치는 영향)

  • Kim, D.W.;Jang, B.G.;Kim, J.H.;Yu, D.J.;Kang, K.H.;Kang, H.G.;Na, J.C.;Kim, S.H.;Lee, D.S.;Suh, O.S.
    • Korean Journal of Poultry Science
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    • v.34 no.2
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    • pp.137-141
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    • 2007
  • This experiment was conducted to investigate the effects of dietary yeast (Saccharomyces exguus) supplementation on growth performance, cecal microflora and fecal ammonia gas in broiler chicks. A total of two hundred seventy, 1-d-old male broiler chicks (Ross strain) were randomly allotted to nine pens (replicates), 30 birds per pen. There were three dietary treatments with three replicates. The treatments were control (virginiamycin 0.05%+salinomycin 0.03%), Saccharomyces exguus 0.5 and 1.0%. Total body weight gain were significantly higher in Saccharomyces exguus1 1.0% treatment than the control (P<0.05). Although not significant, the yeast supplementation tended to improve the feed conversion ratio. No significant differences were observed on the numbers of cecal E. coli, Salmonella and Lactobacillus in yeast treatments compared to those of control. The production of fecal ammonia gas was significantly lower in yeast treatments than the control (P<0.05). The concentrations of fecal short chain fatty acids and volatile organic compounds were not different among the groups. These results suggest the possibility that yeast (Saccharomyces exguus) could be used as the alternative of antibiotic growth promoters by improving the performance of broiler chicks. In addition, dietary yeast could improve the environment of broiler houses by reducing fecal ammonia production.

Effect of Dietary Zeolite Treated on the Performance and Carcass Characteristics in Finishing Pigs (사료내 Zeolite 첨가가 비육돈의 생산성과 도체특성에 미치는 영향)

  • Kim, J.H.;Kim, S.C.;Ko, Y.D.
    • Journal of Animal Science and Technology
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    • v.47 no.4
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    • pp.555-564
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    • 2005
  • This study was conducted to investigate the effect of dietary supplementation of zeolite on growth performance, carcass characteristics and fecal ammonia gas release in the finishing pigs. A total of 120 crossbred finishing pigs (50.2$\pm$1.4kg, Landrace$\time$Yorkshire$\time$Duroc) were assigned to 4 treatments and randomly divided into 12 groups. They were divided between early finishing period (50~80kg) and late finishing period (80-120kg). Finishing pigs were fed on a basal diet supplemented with 0, 1, 2 and 4% levels of zeolite. Average daily gain and feed conversion were significantly (P<0.05) improved by the dietary supplementation of 4% zeolite compared with other treatments during overall period. In the finishing periods, ammonia gas emission was reduced (P<0.05) in 4% zeolite treatment more than that of the other treatments. Carcass weight and back fat thicknesses were not affected by zeolite treatments. But, the appearance of A grade pork was increased by the dietary supplementation of 4% zeolite. Feed cost was linearly decreased by increasing the supplementation of zeolite. According to this study, 4% supplement of zeolite is suitable for the improvement of carcass quality and feed conversion, the reduction of fecal ammonia gas emission and feed cost per body weight gain.

Analysis of Damage Impact Range according to the NG/NH3 Mixing Ratio when applying Ammonia as Fuel for a Combined Cycle Power Plant using an ALOHA Program (ALOHA 프로그램을 활용한 복합화력발전소 내 암모니아 연료 적용 시 NG/NH3 혼소율에 따른 피해영향범위 분석)

  • Yoo Jeong Choi;Hee Kyung Park;Min Chul Lee
    • Journal of the Korean Institute of Gas
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    • v.28 no.1
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    • pp.73-84
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    • 2024
  • In this study, a quantitative risk impact assessment is performed using an ALOHA program to identify the risks when applying ammonia as fuel for combined cycle power plants as one of the solutions of climate change. The worst and the alternative accident scenarios are established for the Sejong combined cycle power plant and the effective ranges are calculated in terms of flammability, thermal radiation, overpressure and toxicity. The analysis results show that the toxic risk is the most critical and the effective distance is highly proportional to the mixing ratio of natural gas and ammonia by showing the Pearson's correlation coefficient over 98% as 0.991, 0.987 and 0.989 for the Level Of Concern(LOC)-1, LOC-2 and LOC-3, respectively. In addition, the coefficients of linearity for LOC-1, LOC-2 and LOC-3 are calculated to 133, 70 and 29, respectively so it can be confirmed that the effective distance increases as the criterion decreases.

Trend and Future Strategy of Ammonia Gas Recovery based on Adsorption from Livestock Fields (축산현장에서 발생된 암모니아 기체의 흡착기반 회수 동향 및 향후 전략)

  • Sangyeop Chae;Kwangmin Ryu;Sang-hun Lee
    • Resources Recycling
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    • v.32 no.6
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    • pp.45-53
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    • 2023
  • This study discussed the trend and future strategy of adsorption technology R&D to effectively recover ammonia emitted from the livestock fields. A proper ammonia adsorbent should incorporate acidic or hydrogen bonding functional groups on the surface, as well as a high specific surface area and a good surface structure appropriate for ammonia adsorption. Activated carbon and minerals such as zeolite have widely been used as ammonia adsorbents, but their adsorption effects are generally low, so any improvement through surface modification should be necessary. For example, incorporation of metal chloride included in a porous adsorbent can promote ammonia adsorption effectiveness. Recently, new types of adsorbents such as MOFs (Metal-Organic Frameworks) and POPs (Porous Organic Polymers) have been developed and utilized. They have shown very high ammonia adsorption capacity because of adjustable and high specific surface area and porosity. In addition, Prussian Blue exhibited high ammonia adsorption and desorption performance and selectivity. This looks relatively advantageous in relation to the recovery of ammonia from livestock waste discharge. In the future, further research should be made to evaluate ammonia adsorption/desorption efficiency and purity using various adsorbents under conditions suitable for livestock sites. Also, effective pre- and/or post-treatment processes should be integrated to maximize ammonia recovery.

Ammonia and Carbon Dioxide Concentrations in a Layer House

  • Kilic, Ilker;Yaslioglu, Erkan
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.8
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    • pp.1211-1218
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    • 2014
  • Higher concentrations of ammonia ($NH_3$) and carbon dioxide ($CO_2$) in animal barns can negatively affect production and health of animals and workers. This paper focuses on measurements of summer concentrations of ammonia ($NH_3$) and carbon dioxide ($CO_2$) in a naturally ventilated laying henhouse located at an egg production facility in Bursa region, western Turkey. Also, indoor and ambient environmental conditions such as temperature and relative humidity were measured simultaneously with pollutant gas concentrations. The average $NH_3$ concentrations during summer of 2013 was 8.05 ppm for exhaust and 5.42 ppm for inlet while average $CO_2$ concentration was 732 ppm for exhaust and 625 ppm for inlet throughout summer. The overall minimum, average and maximum values and humidity were obtained as $16.8^{\circ}C$, $24.72^{\circ}C$, and $34.71^{\circ}C$ for indoor temperature and 33.64%, 63.71%, and 86.18% for relative humidity. The lowest exhaust concentrations for $NH_3$ and $CO_2$ were 6.98 ppm and 609 ppm, respectively. They were measured in early morning at the maximum diurnal ventilation rate in July 2013 and August 2013. The highest concentrations were 10.58 ppm for $NH_3$ and 904 ppm for $CO_2$ recorded in the afternoon when the ventilation rate was the lowest in June 2013.

Preparation and characterization of niobium carbide crystallites

  • Choi, Jeang-Gil
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.3
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    • pp.125-129
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    • 2009
  • The preparation and characterization of niobium carbide crystallites were investigated in this study, and in particular, the effect of preparation conditions were studied on the synthesis of niobium carbides crystallites. For this purpose, various characterization techniques including x-ray diffraction, BET surface area, and oxygen uptake measurements were employed to characterize the synthesized niobium carbide crystallites. The niobium carbide crystallites were prepared using niobium oxide and methane gas or methane-hydrogen mixture. Using x-ray diffraction a lattice parameter of $4.45{\AA}$ and a crystallite size ranging from $52{\AA}$ to $580{\AA}$ was found. BET surface areas ranged from $3.2\;m^2/g$ to $16.6\;m^2/g$ and oxygen uptake values varied from $0.5{\mu}mol/g$ to $6.1{\mu}mol/g$. It was observed that niobium carbide crystallites were active for ammonia decomposition reaction. While the BET surface area increased with increasing the oxygen uptake, the conversion of ammonia decomposition reaction decreased. These results indicated that the ammonia decomposition over these materials was considered to be structure-sensitive.