• Journal of the Semiconductor & Display Technology
• /
• v.22 no.3
• /
• pp.96-100
• /
• 2023

We have investigated the effect of the substrate temperature and oxygen flow rate on the characteristics of IGZO thin films for the TCO (transparent conducting oxide). For this purpose, IGZO thin films were deposited by RF magnetron sputtering at room temperature and 300℃ with various O₂ flow rate. Experiments were carried out while varying the oxygen gas flow rate from 0sccm to 1.0sccm to see how the oxygen gas affects the IGZO thin films. IGZO thin films deposited at room temperature and 300℃ showed amorphous. The lowest resistivity value was 2125x10^-3 Ωcm when the IGZO film was deposited at RT and set up at 0.1sccm. As the oxygen vacancy rate decreased, the resistivity intended to increase. In conclusion, Oxygen vacancy affects the IGZO thin film's electrical characteristic.

• Journal of the Korean Electrochemical Society
• /
• v.22 no.1
• /
• pp.1-12
• /
• 2019

The reduction of nitrogen to produce ammonia has been attracting much attention as a renewable energy technology. Ammonia is the basis for many fertilizers and is also considered an energy carrier that can power internal combustion engines, diesel engines, gas turbines, and fuel cells. Traditionally, ammonia has been produced through the Haber-Bosch process, in which atmospheric nitrogen combines with hydrogen at high temperature ($350-550^{\circ}C$) and high pressure (150-300 bar). This process consumes 1-2% of current global energy production and relies on fossil fuels as an energy source. Reducing the energy input required for this process will reduce $CO_2$ emissions and the corresponding environmental impact. For this reason, developing electrochemical ammonia-production methods under ambient temperature and pressure conditions should significantly reduce the energy input required to produce ammonia. In this review, we introduce the electrochemical nitrogen reduction reaction at ambient condition. Numerical studies on the electrochemical nitrogen reduction mechanism have been carried out through the computation of density function theory. Electrodes such as nanowires and porous electrodes have been also actively studied for further participation in electrochemical reactions.

• Journal of Korean Society for Atmospheric Environment
• /
• v.31 no.5
• /
• pp.449-460
• /
• 2015

Carbonaceous aerosol is generally classified into OC (organic carbon) and EC (elemental carbon) by thermal optical analysis. Both NIOSH (National institute of occupational safety and health) with high temperature (HighT) and IMPROVE-A (Interagency monitoring of protected visual environments) with low temperature (LowT) protocols are widely used. In this study, both protocols were applied for ambient $PM_{2.5}$ samples (Daejeon, Korea) in order to underpin differences in OC and EC measurements. An excellent agreement between NIOSH and IMPROVE-A protocol was observed for TC (total carbon). However, significant differences between OC and EC appeared and the differences were larger for EC than OC. The main differences between two protocols are temperature profile and charring correction method. For the same charring correction method, HighT_OC was 10% higher than LowT_ OC, while HighT_EC was 15% and 33% lower than LowT_EC for TOT (thermal-optical transmittance) and TOR (thermal-optical reflectance), respectively. This difference may be caused by the temperature of OC4 in He step and possibly difference in POC (pryorilized OC) formation. For the same temperature profile, OC by TOT was about 26% higher than that by TOR. In contrast, EC by TOT was about 50% lower than that by TOR. POC was also dependent on both temperature profile and the charring correction method, showing much distinctive differences for the charring correction method (i.e., POC by TOT to POC by TOR ratio is about 2). This difference might be caused by different characteristics between transmittance and reflectance for monitoring POC formation within filters. Results from this study showed that OC and EC depends on applied analysis protocol as shown other studies. Because of the nature of the thermal optical analysis, it may not be possible to have an absolute standard analysis protocol that is applicable for any ambient $PM_{2.5}$. Nevertheless, in order to provide consistent measurement results for scientists and policy makers, future studies should focus on developing a harmonized standard analysis protocol that is suitable for a specific air domain and minimizes variations in OC and EC measurement results. In addition, future elaborate studies are required to find and understand the causes of the differences.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.15 no.5
• /
• pp.399-405
• /
• 1990

Rapid Thermal Process(RTP) has been used to precisely control and study the reaction rate for the formation of refractory titanuium silicide. Samples were prepared by sputtering deposition layer of titanium on n-type, poly-deposit silicon wafers. The process were then sujected to a matrix of rapid time-temperature profile under nitrgen, argon gas ambient to precisely control the silicide formation. Reacted films were analyzed by the sheet resistance measursrement, SEM, ASR and X-ray diffraction. Results were shown that the resistivity of the silicide films are below 20u-cm and the thickness of silicide films are about two times than that of as-deposited titanium films. Silicidation ambient was likely to happen at the same tamperature-time condition for argon and nitrogen gas.

• Journal of ILASS-Korea
• /
• v.1 no.1
• /
• pp.35-43
• /
• 1996

A vaporization model for single component fuel droplet has been developed for applying to sub- and supercritical conditions. This model can account for transient liquid heat ins and circulation effect inside the droplet, forced and natural convection, Stefan flow effect, real gas effect and ambient gas solubility into the liquid droplet in high-pressure conditions. Thermodynamic and transport properties are calculated as functions of temperature and pressure in both phases. Numerical calculations are carried out for several validation cases with the detailed experimental data. Numerical results confirm that this supercritical vaporization model is applicable to the high-pressure conditions encountered in the combustion processes of diesel engine.

• Journal of Korea Foundry Society
• /
• v.27 no.3
• /
• pp.131-134
• /
• 2007

[ $SF_6$ ] gas that is used as a protective cover gas for Mg and Mg alloys during melting and casting has extremely high greenhouse effect. CaO added Mg alloys could maintain their original mechanical properties and original abilities such as fluidity and hot tearing susceptibility. The ignition temperature increased with increasing CaO addition under ambient atmosphere and nitrogen atmosphere. The minimum amount of $SF_6$ gas decreased by 0.13 wt%CaO added AZ91D Mg alloy in the sealed condition.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.36 no.10
• /
• pp.1011-1016
• /
• 2008

Jet-A spray and combustion were numerically analyzed in annular type combustor model using KIVA3V. The combustor geometry have 6 dilute holes. Swirl effect and thermal NO were considered in this investigation to analyze mixing and combustion characteristics. Fuel vapor, flame temperature, NO generation were investigated for various spray angle. As increase of spray angle, Jet-A vapor appeared uniformly in primary zone and evaporation rate was increased. Mixing between fuel vapor and ambient gas was enhanced as increase of spray angle. As a result, high temperature region appeared widely and thermal NO generation rate was increased.

• 한국연소학회:학술대회논문집
• /
• 2006.04a
• /
• pp.189-193
• /
• 2006

Experiments were performed to investigate the melting characteristics of pellet fuel made of LDPE and PP for a waste plastic firing boiler. Pellet fuel in a burner goes through conduction, convection and radiation transferred from flame in a furnace, and complex thermo/chemical processes. To figure out effects of ambient temperature and size of pellet on melting time pellets with a diameter from 5 mm to 40 mm were made to contact high temperature flue gas generated by a LNG firing pilot burner. Though melting processes of plastics include complicated heat transfer in a burner, parameters are limited to flue gas temperature and size for the simplicity in this study. From the results, melting times of LDPE and PP with a diameter of 5mm are 63 and 62 secs respectively at 600 $^{\circ}C$ while 677 and 583 sees respectively for a diameter of 40 mm. At $900^{\circ}C$, melting times of LDPE and PP with a diameter of 5mm are 21 and 24 sees respectively while 408 and 337 secs respectively for a diameter of 40 mm. It is found that melting time of LDPE is longer than that of PP, and melting times of both in general increase with diameter of pellets. It is thought melting is dependent mostly on melting temperature of plastic. It is expected melting times obtained from the study might be taken into account in designing a pellet firing burner for a boiler

• Progress in Superconductivity and Cryogenics
• /
• v.14 no.3
• /
• pp.38-42
• /
• 2012

Fixtures such as bushings in terminations of high temperature superconducting(HTS) power cable systems are subjected to high voltages, which have to transition from ambient to cryogenic temperatures. As such it is imperative to ensure the integrity of the dielectrics under all operating conditions, including thermal aspects brought about by the passage of current. Gaseous helium(GHe) at high pressure is regarded as a potential coolant for superconducting cables. The dielectric aspects of cryogenic helium gas are both complex and demanding. In this experimental study we looked at the interface between a smooth epoxy surface and high pressure helium gas in a homogeneous electric field. The alternating current(AC) flashover voltages of epoxy samples are presented. The results have been analyzed by using Weibull statistics. In addition to the behavior of the epoxy in gaseous helium as a function of pressure and temperature we also present data of the characteristics of the epoxy in mineral oil and in liquid nitrogen($LN_2$). The breakdown characteristics of a uniform field gap in gaseous helium as a function of pressure and temperature under AC, direct current(DC) and lightning impulse voltages are also given. Electric field calculations have been made for one of the experimental geometries in an attempt to explain some of the anomalies in the experimental results.

• Journal of the Korean institute of surface engineering
• /
• v.32 no.1
• /
• pp.3-9
• /
• 1999

Pt thin film of about 7000$\AA$ thickness was deposited on the alumina substrate using DC Magnetron Sputter and the characteristics of the film for temperature sensor were investigated. When film of about 7000$\AA$ thickness was deposited at working gas pressure of $2.0{\times}10^{-3}$torr, sputtering power of 50W, substrate temperature of $350^{\circ}C$(Ts), sheet resistance(Rs), resistivity($\rho$) and temperature coefficient of resistivity(TCR) of the film were respectively 0.39$\Omega$/$\square$, 27.60$\mu\Omega$-cm and $3350 ppm/^{\circ}C$. When the film was annealed at $1000^{\circ}C$ for 240min in hydrogen ambient, Rs, $\rho$ and TCR were respectively 0.236$\Omega$/$\square$, 15.18$\mu\Omega$-cm and 3716 ppm/$3716 ppm/^{\circ}C$. When working gas of 15sccm oxygen and 100sccm Argon were used, Rs, $\rho$ and TCR were respectively 0.335$\Omega$/$\square$, 22.45$\mu\Omega$-cm and $3427 ppm/^{\circ}C$. When the film was annealed at $1000^{\circ}C$ for 240min, Rs, $\rho$and TCR were respectively 0.224/$\Omega$$\square$, 14$\mu\Omega$-cm and $3760 ppm/^{\circ}C$ and the characteristics of the film were much improved.