• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2001년도 추계학술강연 및 발표대회
• /
• pp.7-7
• /
• 2001

The increasing interest in light weight materials coupled to the need for cost -effective processing have combined to create a significant opportunity for aluminum P/M. particularly in the automotive industry in order to reduce fuel emissions and improve fuel economy at affordable prices. Additional potential markets for Al PIM parts include hand tools. Where moving parts against gravity represents a challenge; and office machinery, where reciprocating forces are important. Aluminum PIM adds light weight, high compressibility. low sintering temperatures. easy machinability and good corrosion resistance to all advantages of conventional iron bm;ed P/rv1. Current commercial alloys are pre-mixed of either the AI-Si-Mg or AL-Cu-Mg-Si type and contain 1.5% ethylene bis-stearamide as an internal lubricant. The powder is compacted in closed dies at pressure of 200-500Mpa and sintered in nitrogen at temperatures between $580~630^{\circ}C$ in continuous muffle furnace. For some applications no further processing is required. although most applications require one or more secondary operations such as sizing and finishing. These sccondary operations improve the dimension. properties or appearance of the finished part. Aluminum is often considered difficult to sinter because of the presence of a stable surface oxide film. Removal of the oxide in iron and copper based is usually achieved through the use of reducing atmospheres. such as hydrogen or dissociated ammonia. In aluminum. this occurs in the solid st,lte through the partial reduction of the aluminum by magncsium to form spinel. This exposcs the underlying metal and facilitates sintering. It has recently been shown that < 0.2% Mg is all that is required. It is noteworthy that most aluminum pre-mixes contain at least 0.5% Mg. The sintering of aluminum alloys can be further enhanced by selective microalloying. Just 100ppm pf tin chnnges the liquid phase sintering kinetics of the 2xxx alloys to produce a tensile strength of 375Mpa. an increilse of nearly 20% over the unmodified alloy. The ductility is unnffected. A similar but different effect occurs by the addition of 100 ppm of Pb to 7xxx alloys. The lend changes the wetting characteristics of the sintering liquid which serves to increase the tensile strength to 440 Mpa. a 40% increase over unmodified aIloys. Current research is predominantly aimed at the development of metal matrix composites. which have a high specific modulus. good wear resistance and a tailorable coefficient of thermal expnnsion. By controlling particle clustering and by engineering the ceramic/matrix interface in order to enhance sintering. very attractive properties can be achicved in the ns-sintered state. I\t an ils-sintered density ilpproaching 99%. these new experimental alloys hnve a modulus of 130 Gpa and an ultimate tensile strength of 212 Mpa in the T4 temper. In contest. unreinforcecl aluminum has a modulus of just 70 Gpa.

• 한국결정성장학회지
• /
• 제27권1호
• /
• pp.18-21
• /
• 2017

본 연구에서는 homogeneous precipitation method를 통하여 구형의 단분산(monodispersed) YAG : $Ce^{3+}$를 합성했다. 단분산 YAG : $Ce^{3+}$의 전구체를 합성하는 과정에서 aluminum ion들이 먼저 석출되어 aluminum 화합물을 형성하고 후에 yttrium 화합물들이 aluminum 화합물들의 표면에서 석출된다. 합성된 전구체를 파우더형태로 얻기 위해 건조과정을 거치는데, oven에서 건조했을 때 보다 동결건조기에서 건조했을 때 비교적 구형의 단분산 YAG : $Ce^{3+}$ 입자를 얻을 수 있었다. 하소 과정에서 공정을 진행하는 온도로서 $1100^{\circ}C$와 $1200^{\circ}C$를 비교해 보았다. 실험 결과 $1200^{\circ}C$의 온도로 상압에서 6시간 동안의 하소 과정을 진행하였을 때 400~500 nm 입자크기를 가진 단분산된 구형의 나노 YAG : $Ce^{3+}$ 입자가 합성되었다.

• 전기화학회지
• /
• 제3권3호
• /
• pp.136-140
• /
• 2000

용융탄산염 연료전지의 분리판 재료로 사용되는 스테인레스 스틸은 고온 용융탄산염 분위기에서 부식이 심각하여 일반적으로 표면에 알루미늄 확산막을 코팅함으로써 내식성을 향상시켜 사용하고 있다. 본 연구에서는 기존 방법에 비해 보다 경제적인 슬러리 페인팅 및 열처리에 의한 알루미늄 확산막 형성 방법을 고안하여, 스테인레스 스틸 시편 표면에 알루미늄 확산막을 코팅하고, 산화 분위기의 용융탄산염에서 부식 실험을 수행하였다. $650\~800^{\circ}C$에서 제작된 알루미늄 확산막의 두께는 $25\~80{\mu}m$였으며, 열처리 온도가 높고 열처리 시간이 증가할 수록 알루미늄 확산막의 두께가 증가하였다. 부식 실험 결과 스테인레스 스틸 316L의 용융탄산염에 대한 내식성은 알루미늄 확산막을 표면에 형성시킴으로써 크게 향상되었음을 확인하였다. 또한 분극 실험 결과 슬러리 페인팅 및 열처리 방법에 의하여 알루미늄 확산막이 형성된 시편은 기존의 IVD 및 열처리 방법에 의해 알루미늄 확산막이 제작된 시편과 유사하게 안정한 부동태 피막을 형성함으로써 스테인레스 스틸 316L의 부식을 효과적으로 억제시킴을 알 수 있었다.

• 한국구조물진단유지관리공학회 논문집
• /
• 제27권3호
• /
• pp.38-46
• /
• 2023

본 연구에서는 원형 단부 콘크리트의 알루미늄 보강재 적용에 따른 지압 성능을 평가하기 위하여 지압 시험을 수행하고 이를 해석적으로 평가하였다. 지압강도 실험에서는 원형 단부 콘크리트 제작용 알루미늄 거푸집을 이용한 알루미늄 보강재와 부재이동 및 조립을 위한 강재 앵커볼트로 인한 지압성능 변화를 확인하였다. FE 해석모델은 실험조건과 동일하게 구성하여 결과를 실험과 비교하였으며, 균열 양상과 응력 거동 등도 확인하였다. 또한, 알루미늄 보강재의 강도변화가 원형 단부 콘크리트에 미치는 영향도 해석적으로 평가하였다. 원형 단부 콘크리트는 알루미늄 보강재로 인하여 지압강도가 약 20% 증가하였고, 강재 앵커볼트는 지압강도에 영향을 미치지 않는 것으로 확인되었다. FE 해석 결과 나타난 최대 하중과 균열 양상은 실험과 유사하게 나타났다. 알루미늄 보강재의 강도변화에 따른 FE 해석 결과, 알루미늄 보강재의 강도가 10%, 20% 증가 및 감소함에 따른 최대하중 변화는 강도변화 전과 비교하여 최대 약 4% 수준으로 큰 영향이 없는 것으로 평가되었다.

• 한국세라믹학회지
• /
• 제39권3호
• /
• pp.315-320
• /
• 2002

저농도로 희석된 HF 수용액(6 wt%)을 사용하여 $Al(OH)_3$의 표면을 F/Al의 몰비 0.15에서 처리하고, 처리 전후 표면특성을 관찰하였다. 반응계의 온도 및 pH 변화로부터 $Al(OH)_3$에 대한 HF의 표면반응은 HF와 접촉한 $Al(OH)_3$ 표면부에서 metastable한 ${\alpha}$형의 불화알루미늄$({\alpha}-AlF_3{\cdot}3H_2O)$이 안정한 ${\beta}$형의 불화알루미늄$({\beta}-AlF_3{\cdot}3H_2O)$으로 전이되는 과정으로 진행되며, 다량의 발열을 수반하면서 반응계의 온도상승을 유발하였다. 이러한 ${\beta}-AlF_3{\cdot}3H_2O$의 생성은 표면처리된 분말의 FT-IR 및 X-선 회절분석결과를 통해 확인되었다. ${\beta}-AlF_3{\cdot}3H_2O$의 morphology와 분포상태를 SEM을 통해 관찰한 결과 $Al(OH)_3$ 표면에 $1{\mu}m$ 이하의 미세분말 형태로 피복층을 형성하며 균일하게 분포된 것으로 확인되었다. HF로 처리된 시료의 표면 백색도는 미처리에 비해 약 6.6% 증가되었으며, 이는 $Al(OH)_3$보다 높은 백색도를 지닌 ${\beta}-AlF_3{\cdot}3H_2O$ 피복 효과 때문인 것으로 나타났다.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
• /
• pp.304.1-304.1
• /
• 2016

We have investigated the effect of plasma nitridation of atomic layer deposited-Al2O3 films of monocrystalline Si wafers and the thermal properties of nitridated Al2O3 films. Nitridation was performed on Al2O3 to form aluminum oxynitride (AlON) using NH3 plasma treatment in a plasma-enhanced chemical vapor deposition and it was conducted at temperature of $400^{\circ}C$ with various plasma power condition. After nitridation, we performed firing and forming gas annealing (FGA). For each step, we have observed the minority carrier lifetime and the implied Voc by using quasi-Steady-State photoconductance (QSSPC). We confirmed a tendency to increase the minority carrier lifetime and the implied Voc after the nitridation. On the other hand, the minority carrier lifetime and the implied Voc was decreased after Firing and forming gas annealing (FGA). To get more information, we studied properties of the plasma treated Al2O3 films by using Secondary Ion Mass Spectroscopy (SIMS) and X-ray Photoelectron Spectroscopy (XPS).

• Geomechanics and Engineering
• /
• 제10권1호
• /
• pp.109-124
• /
• 2016

In this paper, process of dynamic powder compaction is investigated experimentally using impact of drop hammer and die tube. A series of test is performed using aluminum powder with different grain size. The energy of compaction of powder is determined by measuring height of hammer and the results presented in term of compact density and rupture stress. This paper also presents a mathematical modeling using experimental data and neural network. The purpose of this modeling is to display how the variations of the significant parameters changes with the compact density and rupture stress. The closed-form obtained model shows very good agreement with experimental results and it provides a way of studying and understanding the mechanics of dynamic powder compaction process. In the considered energy level (from 733 to 3580 J), the relative density is varied from 63.89% to 87.41%, 63.93% to 91.52%, 64.15% to 95.11% for powder A, B and C respectively. Also, the maximum rupture stress are obtained for different types of powder and the results shown that the rupture stress increases with increasing energy level and grain size.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2003년도 춘계학술대회
• /
• pp.381-388
• /
• 2003

The material deficiencies in the form of pre-existing defects can initiated cracks and fractures. The stress distribution and fatigue crack initiation life of engineering materials may be associated with the size, the shape and the relative location of defects contained in the component. The objective of this study is to investigate the effect of arbitrarily located hole defect around the rivet hole of a wing section in monolithic aluminum and Al/GFRP laminates under cyclic bending moment during a service load. The stress distribution and the fatigue crack initiation behavior near a rivet hole of on the relationships between stress concentration factor ($K_t$) and relative position of defects were considered. The test results indicated the features of different stress field. Therefore, the stress concentration factor ($K_t$) and the fatigue crack initiation behavior was illustrated different behavior according to each position of hole defect around the rivet hole in monolithic aluminum and Al/GFRP laminates.

• 한국정밀공학회지
• /
• 제27권3호
• /
• pp.66-72
• /
• 2010

Recently, the use of means of transportation of the lightweight aluminum to temper the trend is increasing. More efficient use of lightweight aluminum material to Friction stir welding has been widely attempted. Types of welding tools at the right screw to rotate anti-clockwise direction, when the tensile stress exerted on the location of the top plate to the left in the direction of the welding process to the installation was able to obtain high tensile strength. A5052 to the top of the left in the direction of the welding process to install and, when you installed the right under the A6061 was not easily come up to the top of the A5052. Conversely, at the bottom left to install on top of the A6061 and A5052 have been installed at the bottom of the upper area of the A6061 and A5052 intrude easily form the shape of the hill you can see that it was formed.

• Advances in environmental research
• /
• 제5권2호
• /
• pp.141-151
• /
• 2016

Large amounts of aluminum hydroxide ($Al(OH)_3$) exist in water purification sludge (WPS) because of the added aluminum coagulant in water treatment process. Notably, $Al(OH)_3$ is an amphoteric compound, can be dissolved in its basic condition using sodium hydroxide to form aluminate ions ($Al(OH)_4{^-}$). However, in a process in which pH is increasing, the humid acid can be dissolved easily from WPS and will inhibit the recovery and reuse of the dissolved aluminate ions. This study attempts to fix this problem by a novel approach to separate $Al(OH)_4{^-}$ ions using nanofiltration (NF) technology. Sludge impurity in a alkaline solution is retained by the NF membrane, such that the process recovers $Al(OH)_4{^-}$ ions, and significantly decreases the organic matter or heavy metal impurities in the permeate solution. The $Al(OH)_4{^-}$ ion is an alkaline substance. Experimental results confirm that a recovered coagulant of $Al(OH)_4{^-}$ ion can effectively remove kaolin particles from slightly acidic synthetic raw water.