• Title/Summary/Keyword: Aluminum film

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Ge-Al Multilayer Thin Film as an Anode for Li-ion Batteries

  • Lee, Jae-Young;Ngo, Duc Tung;Park, Chan-Jin
    • Journal of the Korean Ceramic Society
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    • v.54 no.3
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    • pp.249-256
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    • 2017
  • We design Ge-Al multilayer assemblies as anode materials for Li-ion batteries, in which Ge and Al thin films are alternately deposited by a radio sputtering method. By sandwiching Ge layers between Al layer, the cyclability, rate capability, and capacity of Ge are improved significantly. The success of the Ge-Al multilayer is attributed to the Al films. To maintain the integrity of electrical contact, Al acts as an elastic layer, which can expand or shrink with the Ge film upon lithiation or delithiation. In addition, the presence of the Al film on the surface can prevent direct contact of Ge and electrolyte, thereby reducing the growth of a SEI layer. Importantly, with high electrical and ionic conductivities, the Al film provides efficient electrical and ionic routes for electrons and Li-ions to access the Ge film, promoting a high specific capacity and high rate capability for Ge.

A STUDY ON COPPER DEPOSITION PROCESS DURING ANODIC OXIDATION OF ALUMINIUM ALLOY

  • Koh, I.S.;Han, S.H.;Shin, D.H.
    • Journal of Surface Science and Engineering
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    • v.32 no.3
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    • pp.444-446
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    • 1999
  • The structure and composition of anodic films, formed on 6063 commercial aluminium alloy at constant current density of $1.5A/^dm2$ with various superimposed cathodic current ratio, in the range 0~33%, in the 11% $H_2SO_4$ with various concentration of $CuSO_4{\cdot}5H_2O$, in the range 0~75 g/l, without cathodic current are generally porous-type and no sign of Cu co-deposition appearance, suggesting that cathodic current is an important factor in the Cu co-deposition. Comparison with the anodic film thickness measurement results obtained from anodic film formed by direct anodic current and anodic film formed by superimposed various portion of cathodic current, the portion of cathodic current of input current increases with decrease of anodic film thickness and increases with increase of concentration of $Cu_2S{\;}and{\;}Cu_2O$ in the anodic film.

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A Study on Surface Growth Direction and Particle Shape According to the Amount of Oxygen and Deposition Parameters

  • Jeong, Jin;Kim, Seung Hee
    • Journal of Integrative Natural Science
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    • v.11 no.4
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    • pp.209-211
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    • 2018
  • A zinc oxide thin film doped with aluminum was deposited by RF sputtering. The deposition temperature of the sputter chamber was kept constant at $350^{\circ}C$, the power supplied to the chamber was 75 W, the oxygen flow rate was changed to 10 sccm and 20 sccm, and the thin film deposition time was changed to 120 and 180 minutes. The structures of the deposited zinc oxide thin films were analyzed by van der Waals method using an X-ray diffractometer. As a result of X-ray diffraction, the amount of oxygen supplied to the zinc oxide thin film increased, and the surface growth of the (002), (400), (110), and (103) planes showed a change with increasing deposition time. Moreover, as the amount of oxygen supplied to the zinc oxide thin film increased, their shape was observed to be coarse, and the thin film' s particles shape was correlated with the oxygen chemical defect introduced.

Atomistic Study of Metal Cluster Deposition and Nanowires (금속 덩어리 증착 및 금속 나노와이어에 관한 원자단위 이론 연구)

  • 강정원;이강환;황호정
    • Proceedings of the IEEK Conference
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    • 2001.06b
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    • pp.21-24
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    • 2001
  • We studied aluminum cluster deposition using molecular dynamics simulation. We investigated the variations of the cluster momentum and the impulse force during collisions, and found that the close-packed cluster impact has some of properties of the single particle collision and the linear chain collisions. We also simulated the series of energetic cluster deposition with energy Per atom. When energy Per atom in cluster has some eV rather than very low, the intermixing occurred easily in growth film and we can obtain a good film without subsequent annealing process.

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A Study on the Adhesion Property of Al-Cr Alloy Films by Evaporation (진공증착법으로 제조된 Al-Cr 박막의 밀착성에 관한 연구)

  • 주봉환;이규환;권식칠;백운승;임수근
    • Journal of Surface Science and Engineering
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    • v.27 no.1
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    • pp.19-28
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    • 1994
  • A study on adhesion property of evaporated Al-Cr films was conducted on steel sheet by using two-source evaporator. Adhesion of Al-Cr coated steel was evaluated by tape test after $180^{\circ}$bending. Adhesion was decreased with increasing the Cr content in Al-Cr films. It was thought that the decrease in adhesion with increasing Cr content be related to insufficient wetting and diffusion of Cr atoms in the film. Best adhesion was achieved in the case of pure aluminum film..

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Anodic Film Formation on Aluminum(IV) (양극산화피막 형성에 관한 연구(IV))

  • 한성호
    • Journal of Surface Science and Engineering
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    • v.22 no.3
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    • pp.145-153
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    • 1989
  • 양극산화 피막의 형성 반응에 대한 연구는 1930년대부터 되어 왔으며, 특히 High Field Conduction에 대한 물리학자들의 관심도는 아주 높아었다. 1960년대 이르러 비정질 구조에 대한 심도 있는 연구가 진행되면서, 여러 가지 이론적으로 풀지 못하는 실험실적 결과들에 대한 제한들이 나오게 되었고, Ionic Migration Process에 대한 Kinetics는 많은 발전을 보게 되었다. 최근까지의 연구결과, Ioinc Conduction Mechanism은 Anodic Film의 미세 결정 구조와 밀접한 연관성을 가진다는 결론에 도달하였고, 비정질 구조의 High Field하에서의 거동에 대한 새로운 분야의 연구가 진행되고 있다. 본 고에서는 반응 Mechanism에 관한 연구결과들을 1930년대 이후 어떻게 진행되어 설명 되었는가를 조명하므로서 실제 실험 결과의 해석게 도움이 되었으면 하는 바램이다.

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Development of Inspection System for Aluminum Castings with X-Ray TDI Camera (X-Ray TDI Camera를 이용한 알루미늄 주강품 검사장치 개발)

  • Nam, Mun-Ho;Park, Seong-Wook;Kim, Chang-Ho;Chung, Chan-Soo
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1734-1735
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    • 2011
  • In case of inspection on aluminum castings, traditional RT (Radiographic Testing) method have been utilized for its advantages in interpretation, cost and perpetual storage. But it has disadvantages like time consumption in film processing, low efficiency in storage and environmental pollution. In this thesis, a DRS (Digital Radiography System) utilizing X-Ray TDI Camera (Time Delay and Integration Camera) is developed. Inspections on aluminum castings are performed using the developed Digital Radiography System, DRS and reviewed if newly developed system can substitute for the traditional method.

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Elucidation of the Noise in Corrosion of Aluminum Foil

  • Chiba, Atsushi;Hattori, Atsushi;Wu, Weng-Chang
    • Corrosion Science and Technology
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    • v.3 no.3
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    • pp.102-106
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    • 2004
  • Al foil used was 99.9 and 99.99 %. Test solution used was NaCl solution. The noise was determined using controlled potential electrolysis at -200 and -700 mV vs. NHE. The current fluctuation was caused by breakdown and repaired process of aluminum oxide film. The current fluctuation value of noise was proportion to degree of growth. The number of noise was proportion to the number of pit. The examining of current flutulation value and number of noise could be evaluated corrosion. A 99.99 % Al foil was the mostly crystal of {100} plane, and showed three-dimensional, as azimuth pit with along the direction of this place piled up. A 99.9 % Al foil was polycrystal, and in order of (311) >(222) >(200) >(111) plane. The azimuth pit did not occurred as the dissolution was occurred from each plane.

Electrical Properties of Both a Monolayer at the Air/Water Interface and a Langmuir-Blodgett Film Sandwiched Between Aluminum Electrodes (수면상의 고분자막과 알루미늄 전자간의 Langmuir-Blodgett막에 대한 전기적 특성)

  • Mitsumasa Iwamoto;Kang, Dou-Yol
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.38 no.1
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    • pp.35-42
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    • 1989
  • Electrical properties of both a monolayer at the air/water interface and Langmuir-Blodgett films sandwiched between aluminum electrodes are studied using a current-measuring technique. A change in induced charges on an electrode suspended in the air was measured in combination with the surface area isotherm in the electrical measurement of the monolayer. A change in induced charges on an electrode is measured while heating the sample in the electrical measurement of the LB films. From both measurements, we elucidated that a spontaneous polarization plays very important role in the electrical properties of both a monolayer at the air/water interface and LB films sandwiched between aluminum electrodes.

Three-Dimensional (3D) Anodic Aluminum Surfaces by Modulating Electrochemical Method

  • Jeong, Chanyoung;Choi, Chang-Hwan
    • Journal of Surface Science and Engineering
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    • v.50 no.6
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    • pp.427-431
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    • 2017
  • Anodic aluminum oxide (AAO) film has recently attracted much attention as a key material for the fabrication of various nanostructures. A control of anodizing voltage (U) was employed to render different anodic aluminum oxide (AAO) nanostructures with pore diameter ($D_p$) and interpore distance ($D_{int}$) in oxalic acid. In this work, we study the effect of stepwise modulation of anodizing voltages on the shape and dimension of porous structures along the vertical direction and demonstrate the fabrication of hierarchical layers of systematically controlled three-dimensional (3D) pore profile.