• 한국세라믹학회지
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• 제36권6호
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• pp.662-670
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• 1999

Porous alumina was fabricated from pressureless powder packing forming method using powders granulated by spray drying. It was investigated the pore size distribution of fabricated porous alumina. The results of microstructural observation showed that intraganular pore size and intragranular pore size. At 1700$^{\circ}C$ there were no intragranular pores but it showed homogeneous distribution of intergranular pore size. The bending strength and shrinkage increased as porosity decreased. In case of thermal shock resistance sudden decrease of bending strength to $\Delta$T was not shown because intergranular large pore prevented sudden crack propagation.

• 한국정밀공학회지
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• 제23권1호
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• pp.80-88
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• 2006

In this study, unsintered and presintered low purity alumina ceramics were machined with various tools to clarify the machinability and the optimum cutting conditions. The main conclusions obtained were as fellows. Machined with ceramic tool, the ceramics presintered at the temperature range of $1000\~1100^{\circ}C$ showed the best machinability due to the adhesion formed in weared surface within a certain cutting speed range. In the above combination and conditions, the ceramic tool showed the highest productivity through all experiments. The life of CBN tool was longer in machining of the ceramics presintered at $1000^{\circ}C$ than in the case of that presintered at $600^{\circ}C$, but the diamond tool showed adverse tendency. In machining of the ceramics presintered at $1000^{\circ}C$, the ceramic tool exhibits the longest tool life in high speed, the tool lives became extremely worse in the order of CBN tool and diamond tool. However, in the case of the ceramics presintered at $600^{\circ}C$, the diamond tool shows the longest tool life, the tool lives was much worse in the order of CBN tool and ceramic tool.

• 한국세라믹학회지
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• 제39권2호
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• pp.164-170
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• 2002

Acrylate 수계 결합제를 사용한 알루미나 테이프 캐스팅용 슬러리의 완전분산을 위한 최적의 분산제와 분산제량을 결정하기 위해 침강실험, 분말 함유량 실험, 점도 및 zeta 전위 측정을 행하였다. 알루미나 슬러리의 완전분산은 분산제를 polycarboxylic acid로 했을 때 얻어졌으며, 최적의 첨가량은 알루미나 100에 대하여 0.23∼0.24g 이었다. 분말에 대한 분산제량이 증가할수록 분산은 잘 이루어졌으나, 일정량 이상이 첨가되면 분산제가 용매 안에 과잉으로 존재하여 분산을 저해하는 요인으로 작용하였다. 테이프 캐스팅용 슬러리는 100g의 알루미나 분말에 0.2g의 polycarboxylic acid를 첨가하였을 때 분산 및 테이프 특성이 가장 우수하였고, 이 때 혼합한 결합제는 acrylate였고, 가소제는 Benzoflex를 사용하였다. 이 때 슬러리 최적 점도는 약 570 cps였고, 테이프 내 알루미나 량은 57 vol%이었다.

• 한국세라믹학회지
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• 제36권10호
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• pp.1062-1068
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• 1999

상온 25$^{\circ}C$의 증류수에 단일 열충격을 시행한 후 ball-on-3 ball test로 강도를 측정하고 강도의 변화를 관찰하였다. 시편은 상용 알루미나 시편을 사용하였고, disc 형태의 시편에 대하여 열충격 후의 균열의 모양과 강도 시험 후의 균열의 모양을 잉크 침투법에 의해 관찰하였다. 통계적인 파괴 확률방법을 제시하였으며, thermal shock Weibull plot을 이용하여 3점 꺾임 강도와 비교하였다. ball-on-3 ball test 강도에 미치는 인자에 대해 통계학적인 접근을 통해 관찰한 결과, 시편중심에서 균열까지의 거리가 균열 밀도보다 더 큰 영향을 미치고 있음을 알 수 있었다.

• 대한기계학회논문집
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• 제18권8호
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• pp.2073-2080
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• 1994

In this paper, a model of material removal in abrasive water jet machining of brittle material is developed, and experimentally evaluated. Abrasive water jet machining proved to yield better material removal rate than other machining techniques for hard and brittle material (alumina ceramics). It was also found that large scale fracture may develop at the exit of the jet from the material. The fracture size was predicted as a function of water jet pressure and size of the hole. Finally, the feasibility of using acoustic emission signals for in-process monitoring of the abrasive water jet machining process is investigated.

• 한국세라믹학회지
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• 제30권9호
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• pp.747-753
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• 1993

The investigation was carried out to study the behaviors of the pore size and porosity, the mechanical strength, the resistance to thermal spallings and slag attacks according to particle sizes of starting raw materials in porous high Alumina ceramics. This porous ceramics have been used in processing of the clean steel by the blowing of the inert gas. The required properties in the practice are the suitable pores size, the sharp pores distribution for a uniform blowing of the gas, the strong corrosion resistance to slags and molten metals and the resistance to thermal spalling. The optimized properties in porous high alumina ceramics of the specimen No. 3 was found to be the very low slag intrusion and the superior resistance to thermal spalling because of the suitable pore size of 2.5${\mu}{\textrm}{m}$, the porosity of 30% and the high sinterability.

• 한국정밀공학회지
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• 제24권2호
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• pp.33-40
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• 2007

In this study, presintered and full sintered low purity alumina ceramics were machined with various tools to clarify the effect of cutting fluid in machinability. The main conclusions obtained were as follows. When the presintered ceramics were wet machined with sintered diamond tool, the tool wear becomes extremely large, and higher cutting speed can be used than in the case of full sintered ceramics. The productivity of wet cutting with the sintered diamond tool is much higher than that of dry cutting. In the case of the CBN and ceramic tools, the tool wear were smaller at wet cutting than at dry cutting, especially exhibiting considerably larger grooved tool wear in wet cutting with ceramic tool.

• 한국정밀공학회지
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• 제27권5호
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• pp.14-21
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• 2010

In this study, presintered low purity alumina ceramics were machined with various tools to clarify the effects of the tool material, cutting condition and tool geometry on machinability. The main conclusions obtained were as follows. (a)The wear of tungsten carbide tool becomes smaller with the increase of the feed and clearance angle, and with the decrease of rake angle, especially exhibiting considerably smaller wear with both the decrease of rake angle and the increase of clearance angle. (b) So far as turning the ceramic presintered at low temperature, the diamond tool shows the best performance with higher feed. (c) The effect on the tool wear of the feed, clearance angle and rake angle becomes smaller in turning the ceramic presintered at higher temperature. (d) The tool wear is not severely affected by the depth of cut.

• Bulletin of the Korean Chemical Society
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• 제25권6호
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• pp.843-846
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• 2004

Pt nanoparticles loaded on alumina through an impregnation at room temperature was prepared using $K_2PtCl_4$ and acrylic acid as capping material. Transmission electron microscopy showed that the deposited Pt particles indicate ca. 80% cubic shapes with a narrow distribution of 8-10 nm in size. Propylene hydrogenation over the catalyst has been carried out to evaluate their catalytic performance by the values of activation energy. It is determined from the initial rate, reaction order, and rate constant and is found to be $9.7{\pm}0.5$ kcal/mol. This value has been discussed by comparing to those of encapsulated- and truncated octahedral Pt nanoparticles deposited on alumina, respectively, to study influence of the particle size and shape, and capping material used on the activation energy.

• 한국세라믹학회지
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• 제36권8호
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• pp.871-875
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• 1999

Theoretical equation to calculate thermal fatigue life was derived in which slow crack growth theory was adopted. The equation is function of crack growth exponent n. Cyclic thermal fatigue tests were performed at temperature difference of 175, 187 and 200$^{\circ}C$ respectively. At each temperature difference critical thermal fatigue life cycles of the alumina ceramics were 180,37 and 7 cycles. And theoretical thermal fatigue life cycles were calculated as 172, 35 and 7 cycles at the same temperature difference conditions. Therefore thermal fatigue behavior of alumina ceramics can be represented by derived equation. Also theoretical single cycle critical thermal shock temperature difference can be calculated by this equation and the result was consistent with the experimental result well.