• 한국세라믹학회지
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• 제47권2호
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• pp.122-126
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• 2010

In this article photoluminescence of the $Al_2O_3:xCr_2O_3$ solid solutions prepared by solid state reaction method are represented. The effect of $Cr_2O_3$-activator concentration and heat treatment time on the PL characteristics have been discussed in conjunction with microstructure of phosphor samples. The $Al_2O_3:xCr_2O_3$ phosphors show the highest PL intensity at x=0.003 mole when the samples are reacted at $1600^{\circ}C$ for 5 h. The PL emission and absorption spectra show the maximum peaks at 698 nm and at 398 nm respectively. The CIE color coordinate is (x=0.646, y=0.316) at 0.003 mole $Cr_2O_3$, which value is very close to the NTSC coordinate of red color. This characteristic feature of $Al_2O_3:xCr_2O_3$ has been applied for an additive to improve the color characteristic of other red phosphor $LiEuW_2O_8$ which has a relatively poor color purity with an emission peak centered at 615 nm and with a CIE coordinate (x=0.530, y=0.280). The $Al_2O_3:0.003Cr_2O_3$ phosphor has been mixed with the $LiEuW_2O_8$ phosphor powder and the PL characteristics and CIE color coordinates are characterized. The $Al_2O_3:xCr_2O_3$ phosphor was found effective for improving the CRI (color rendering index) of $LiEuW_2O_8$ phosphor.

• 한국세라믹학회지
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• 제19권3호
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• pp.179-186
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• 1982

This research is to aim at the study of sintering mechanism through the observation of microstructure by scanning electron microscopy, after the mixture of 30wt% $Al_2O_3$ (White Alundum) powder is fired in air at the temperature range of 1350~150$0^{\circ}C$ in order to sinter $Al_2O_3$-Al through the oxidation of Al powder. The results obtained in this experiment are as follows: 1. While the compressive strength of $Al_2O_3$(WA) body fired at $1450^{\circ}C$ for 5hrs in air is 150kg/$\textrm{cm}^2$, that of Al-$Al_2O_3$ body fired at 135$0^{\circ}C$, $1400^{\circ}C$ for 5hrs in air is 1100kg/$\textrm{cm}^2$, 1600kg/$\textrm{cm}^2$ respectively, and the higher the firing temperature, the more the compressive strength increases. These results from the sintering effect between $Al_2O_3$(WA) grains and surrounding Al-oxidation layer. 2. While the compressive strength of Al2O3(WA) body fired at 150$0^{\circ}C$ for 5hrs in air is 250kg/$\textrm{cm}^2$, the compressive strength of Al-$Al_2O_3$body fired under the same condition is 2050kg/$\textrm{cm}^2$ and water absorption 9.0%, porosity 23.3%, bulk density 2.60gr/$cm^3$. It is assumed that these results come from not only the grain growth of oxidized Al grains but also the increase of bonding strength between $Al_2O_3$(WA) grains.

• 한국세라믹학회지
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• 제41권3호
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• pp.253-258
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• 2004

Polyacrylamide(PAA) 겔법은 매우 간단한 중합법이며, 고분자 망상구조가 $\alpha$-Al$_2$O$_3$ 분말의 응집을 억제하므로 미 응집된 나노 크기의 $\alpha$-Al$_2$O$_3$ 분말은 polyacrylamide(PAA) 겔법을 통하여 성공적으로 합성되었다 본 연구에서는 황산알루미늄, acrylamide 및 N,N'-methylene-bis-acrylamide(BIS)의 여러 농도에서 합성된 겔 전구체를 공기 중에서 110$0^{\circ}C$, 2시간동안 하소시켜서 약 8-l5 nm의 직경을 가진 나노 $\alpha$-Al$_2$O$_3$ 입자들을 제조할 수 있었다. Acrylamide에 대한 황산알루미늄의 몰비를 증가시켰을 때는 나노 입자들의 크기는 변하지 않았지만, acrylamide에 대한 BIS의 몰비를 증가시켰을 때는 나노입자들의 크기는 작아지는 경향을 나타내었다.

• 한국세라믹학회지
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• 제23권3호
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• pp.53-61
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• 1986

A gas sensor which has been made by wet process had fabricated by coating each of the mixture on alumina tube and firing at 85$0^{\circ}C$ for 3hrs. A gas concentration such $H_2$, CO, $C_3H_8$, $C_2H_2$ and $CH_4$ vs its detection voltage characteristics has been in-vestigated on $SnO_2-In_2O_3-MgO$ system doped with PdO, $La_2O_3$, $ThO_2$, NiO and $Nb_2O_5$ The optimum sensitivity composition for various gases were 90w/o $SnO_2$-9w/o $In_2O_3$-1w/o MgO for $H_2$, $C_2H_2$ CO and $C_3H_8$ and 95w/o $SnO_2$-4w/o $In_2O_3$-1w/o MgO for $CH_4$. The sample which has been made by wet process than dry process had predominated sensitivity for each gases and particle size of the sample coprecipitated with PH=9 was 0.1${\mu}{\textrm}{m}$ The $SnO_2$-In2_O_3-MgO$ system doped with 2w/o $Nb_2O_5$ and NiO was the most sensitive for $H_2$ and $C_2H_2$ gas. In $SnO_2$-In2_O_3-MgO$ system doped with $ThO_2$ the sensitivity of $H_2$ gas was decreased but CO gas was in-creased when dopant con was increased.

• 한국세라믹학회지
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• 제56권4호
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• pp.350-353
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• 2019

Porous alumina ceramics with addition of 0, 5, 10, 15, and 20 wt% Al(H₂PO₄)₃ were sintered at 1300, 1350, and 1400℃. The effects of the Al(H₂PO₄)₃ addition on crystal phases, water absorption, open porosity, pore size distribution, microstructures, and flexural strength were studied extensively. The experimental results revealed that only characteristic peaks of corundum were indexed in the XRD patterns of the as-prepared porous ceramics. The water absorption and open porosity of the porous Al₂O₃ ceramics increased remarkably with an increase in Al(H₂PO₄)₃ addition. The flexural strength first increased to a maximum value when 5 wt% Al(H₂PO₄)₃ was added and then decreased as additional Al(H₂PO₄)₃ was further added. SEM images showed that the average Al₂O₃ grain size in the porous ceramics changed in an opposite way as the flexural strength. The porous Al₂O₃ ceramics with 10 wt% Al(H₂PO₄)₃ addition exhibited comparable flexural strength to the ceramics without Al(H₂PO₄)₃ addition, although the latter had much higher porosity.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집A
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• pp.561-566
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• 2001

A long bar impact test to alumina plates(AD 85 and AD 90) was carried out by using fabricated impact testing apparatus. The apparatus adopting a long bar of 2.1m in length made it possible to measure directly the applied impact force to the specimen during bar impact. The dimension of specimens was $33{\times}33mm$ and thickness was 3.4mm. Confinement of D2=18mm outer diameter and D1=10.5mm inner diameter was used to provide contact pressure to the specimen. Contact pressure of p=100 or 200MPa was applied to specimen before impact test. Damage caused in those cases were compared with the case of without contact pressure. The damage of specimen was different depending upon the pressure level of confinement. The existence of confinement had suppressed the development of radial cracks from the bottom of specimen and reduced the extent of damage as compared with cases without contact pressure(p=0MPa). Because the application of contact pressure to the specimen increased the apparent flexural stiffness of specimen during bar impact, it had produced the change of developed damage in the specimen; from the radial cracks to the local contact stress dominant damage. It would contribute to the improvement of the ballistic property in ceramic plates.

• 한국분말재료학회지
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• 제17권4호
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• pp.319-325
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• 2010

Electrical discharge machining (EDM) is an attractive machining technique but it requires electrically conductive ceramic materials. In this study, Alumina matrix composites reinforced with CNTs were fabricated through CNT purification, mixing, compaction and spark plasma sintering (SPS) processes. $Al_2O_3$ nanocomposites with the different CNT concentrations were synthesized. The mechanical and electrical characteristics of $Al_2O_3$/CNTs composites were examined in order to apply the materials to the EDM process. In addition, micro-EDM using wire electrical discharge grinding (WEDG) was conducted under the various EDM parameters to investigate the machining characteristics of machined hole by Field Emission Scanning Electron Microscope (FE-SEM). The results show that $Al_2O_3$/CNTs 10%Vol. was more suitable than the other materials because high conductivity and large discharge energy caused violent sparks resulting in bad machining accuracy and surface quality.

• 멤브레인
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• 제22권6호
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• pp.424-434
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• 2012

본 연구에서는 CVD법으로 세라믹 막을 제조하였다. 튜브의 ${\alpha}-Al_2O_3$ 지지체 위에 Ga 염이 첨가된 ${\gamma}-Al_2O_3$를 코팅하였고, 실란화합물인 tetramethylorthosilane (TMOS) 를 $650^{\circ}C$에서 화학적 기상 증착법으로 막에 증착하였다. 제조된 세라믹 막을 사용하여 수소, 질소, 이산화탄소, 메탄의 단일조성 기체투과 실험을 $600^{\circ}C$에서 시행하였다. Ga 염 비첨가 시, $600^{\circ}C$ 수분 처리 실험의 $H_2/N_2$ 선택도가 926에서 829로 감소한 반면, Ga 염 첨가 시에는 910에서 904로 안정하였다. 이 결과를 통해, 막에 금속염을 첨가하여 제조한 막이 수분 안정성을 향상시킴을 확인하였다.

• 한국세라믹학회지
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• 제38권10호
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• pp.936-941
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• 2001

5.31 mol% ${Y_2}{O_3}$-4.45 mo1% ${Nb_2}{O_5}$-90.31 mo1% $ZrO_2$에 ${Al_2}{O_3}$를 첨가한 복합체를 제조하여 알루미나 입도가 복합체의 균열 전파 저항성에 미치는 영향을 조사하였다. $ZrO_2/{Al_2}{O_3}$ 복합체에서는 R-cuve 거동이 관찰되었으며 0.2, $2.8{\mu}m$ ${Al_2}{O_3}$가 20 vol%가 첨가된 복합체의 인성값은 각각 7.9, $8.8MPam^{1/2}$이었다. 파괴인성값의 차이는 ${Al_2}{O_3}$ 입도 크기에 의존하는 $ZrO_2/{Al_2}{O_3}$ 복합체 내의 정방정 $ZrO_2$의 결정립 크기 차이에 의한 것으로 추정된다.

• 한국세라믹학회지
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• 제38권10호
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• pp.948-952
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• 2001

스크린 인쇄법으로 알루미나 기판 위에 PZT 후막을 제조하였으며, 공기 또는 Pb 분위기의 $750{\sim}1050^{\circ}C$에서 1시간 동안 소결하여 소결 조건이 후막의 물성에 미치는 영향을 조사하였다. 공기 중에서 $950^{\circ}C$ 이상의 온도로 소결한 PZT 후막에는 파이로클로 상이 제 2상으로 존재하고 있었으며, Pb분위기에서 소결한 PZT 후막이 공기 중에서 소결한 후막보다 치밀한 미세구조와 큰 유전상수 그리고 잘 발달된 P-E 이력특성을 보였다. $900^{\circ}C$의 Pb 분위기에서 소결한 PZT 후막은 잘 포화된 전형적인 강유전 P-E 이력곡선 모양을 보였으며, 잔류분극과 항전계가 각각 $29.8{\mu}C/cm^2$, 48.4 kV/cm이었다.