• Title/Summary/Keyword: Alum sludge

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Selection of coagulant using jar test and analytic hierarchy process: A case study of Mazandaran textile wastewater

  • Asadollahfardi, Gholamreza;Zangooei, Hossein;Motamedi, Vahid;Davoodi, Mostafa
    • Advances in environmental research
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    • v.7 no.1
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    • pp.1-11
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    • 2018
  • Textile factories are one of the industries which its wastewater treatment is a challenging issue, especially in developing countries and a conventional treatment cannot treat all its pollutants properly. Using chemical coagulants is a technique for physical and chemical primary treatment of the wastewater. We applied jar test for selection of suitable coagulant among the five coagulants including alum, calcium hydroxide, ferrous sulfate, ferrous chloride and barium chloride for the effluent of wastewater in Mazandran textile factory located in Mazandran Province, Iran. In addition, jar test, we also used analytic hierarchy process (AHP) method considering criteria which included coagulation cost, sensitivity to pH change, the amount of sludge generation and side effects for coagulation. The results of the jar test indicated that calcium hydroxide was proper among the coagulants which it removed 92.9% total suspended solid (TSS), 70% dye and 30% chemical oxygen demand. The AHP analysis presented that calcium hydroxide is more suitable than other coagulants considering five criteria.

Characteristics of The Wastewater Treatment Processes for The Removal of Dyes in Aqueous Solution(1) - Chemical Precipitation or Biological Treatment - (수용액 중의 염료 제거를 위한 폐수처리공정의 특성(1) -화학적 응집 및 생물학적 처리-)

  • Han Myung Ho;Huh Man Woo
    • Textile Coloration and Finishing
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    • v.17 no.2 s.81
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    • pp.31-39
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    • 2005
  • This study was conducted to remove the dyes in dye wastewater by the chemical precipitation or biological treatment which are one of the main pollutants in dye wastewater. In order to remove the disperse dyes effectively in aqueous solution by chemical precipitation process, coagulation and flocculation tests were carried out using several coagulants on various reaction conditions. It was found that the Ferrous sulfate was the most effective coagulant for the removal of disperse dye(DB79), and we could get the best result for the removal of disperse dye(DB56) in the aspects of TOC removal efficiency and sludge yield. When the Ferrous sulfate dosage was 800mg/l, the sludge settling velocity was very fast$(SV_{30}=4\%)$, and the color was effectively removed in the disperse dye(DB79) solution. Although the color removal was ineffective when the Alum was used as a coagulant, the sludge yield decreased in comparison with the Ferrous sulfate or the Ferric sulfate being used in the disperse dye(DB56) solution. In order to decolorize disperse dye(DR17) by using biological treatment process, a strain which has potential ability to degrade disperse dyes was isolated from natural system. The optimal culture conditions of temperature and pH were found to be $40^{\circ}C\;and\;8.5\~9$, respectively. When yeast extract was mixed with polypeptone at the mixing ratio of 1:1 as a nitrogen source, decolorization efficiency was highest$(93\%)$ among the nitrogen sources. The strain screened was excellent to adjust to pH, and it seems to have ability to control pH needed to growth. The optimal culture conditions in concentration of $MgSO_{4.}\cdot7H_2O\;and\;KH_2PO_4$ were $0.1\%(w/v)\;and\;0.2\%(w/v)$, respectively. Strains degrading and decolorizing reactive dyes, RB198 and RR141 which were isolated from water system, are named RBK1 and RRK. And the cell growth characteristics of RBK1 and RRK were investigated. The optimal culture conditions of temperature and pH were found to be 30t' and 7.0, respectively. Optimum nitrogen source was peptone, and it was found that decolorization efficiencies by strains RBK1 and RRK, were $85\%\;and\;62\%$, respectively, with introduction of 4,000mg/l of peptone. In the case of RBK1, color removal efficiencies were very high below 400mg/l. Decolorization efficiency was over $90\%$ at 20hours of culture time. The Color degradation ability of RRK was lower than that of RBK1.

Strength properties of composite clay balls containing additives from industry wastes as new filter media in water treatment

  • Rajapakse, J.P.;Gallage, C.;Dareeju, B.;Madabhushi, G.;Fenner, R.
    • Geomechanics and Engineering
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    • v.8 no.6
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    • pp.859-872
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    • 2015
  • Pebble matrix filtration (PMF) is a water treatment technology that can remove suspended solids in highly turbid surface water during heavy storms. PMF typically uses sand and natural pebbles as filter media. Hand-made clay pebbles (balls) can be used as alternatives to natural pebbles in PMF treatment plants, where natural pebbles are not readily available. Since the high turbidity is a seasonal problem that occurs during heavy rains, the use of newly developed composite clay balls instead of pure clay balls have the advantage of removing other pollutants such as natural organic matter (NOM) during other times. Only the strength properties of composite clay balls are described here as the pollutant removal is beyond the scope of this paper. These new composite clay balls must be able to withstand dead and live loads under dry and saturated conditions in a filter assembly. Absence of a standard ball preparation process and expected strength properties of composite clay balls were the main reasons behind the present study. Five different raw materials from industry wastes: Red Mud (RM), Water Treatment Alum Sludge (S), Shredded Paper (SP), Saw Dust (SD), and Sugar Mulch (SM) were added to common clay brick mix (BM) in different proportions. In an effort to minimize costs, in this study clay balls were fired to $1100^{\circ}C$ at a local brick factory together with their bricks. A comprehensive experimental program was performed to evaluate crushing strength of composite hand-made clay balls, using uniaxial compression test to establish the best material combination on the basis of strength properties for designing sustainable filter media for water treatment plants. Performance at both construction and operating stages were considered by analyzing both strength properties under fully dry conditions and strength degradation after saturation in a water bath. The BM-75% as the main component produced optimum combination in terms of workability and strength. With the material combination of BM-75% and additives-25%, the use of Red Mud and water treatment sludge as additives produced the highest and lowest strength of composite clay balls, with a failure load of 5.4 kN and 1.4 kN respectively. However, this lower value of 1.4 kN is much higher than the effective load on each clay ball of 0.04 kN in a typical filter assembly (safety factor of 35), therefore, can still be used as a suitable filter material for enhanced pollutant removal.

Effective Chemical Treatment of Biologically Treated Distillery Wastewater in Industrial Scale (생물학적으로 처리한 주정폐액의 효율적인 화학적 처리방법)

  • Nam, Ki-Du;Chung, In;Hur, Daniel;Park, Wan
    • Journal of Life Science
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    • v.9 no.6
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    • pp.692-697
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    • 1999
  • For further removal of non-biodegradable CODs and color in biologically treated distillery waster water, we selected a chemical treatment with Fe(III) and cationic polymers and then another chemical treatment with Fenton reagent. We developed Pregenerated Bubble Flotation(PBF) to effectively remove the chemical sludge from each chemical reaction process. The flotation unit was constructed with hydraulic loading rate, 7 ㎥/$m^2$.hr. The CODMn and suspended solids (SS) in biologically treated distillery waste water were reduced by the first PBF from 310-1096 mg/L to 141-303 mg/L and from 160-990 mg/L to 48-385 mg/L, respectively. Again, after the Fenton reaction process, floated SS was skimmed off at the top of the flotation unit and the final effluent was directly discharged without any tap water dilution. The quality of final effluent can be below 40 mg/L-CODMn but IISan Distilery has been maintained effluent quality of 73 mg/L-CODMn and 10-80 mg/L-SS. The chemical cost was saved by more than 30% as compared with that of prior process.

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Measuring of Cadmium Content in Sorghum(Sorghum bicolor (L.) Moench) (수수(Sorghum bicolor (L.) Moench)의 카드뮴 함량 측정 방법)

  • Park, Byung-Hoon;Lee, Su-Chan;Choi, In-Sub;Kim, Jun-Ho;Lee, Hyo-Jeong;Park, Mun-Soo;Kim, Sang-Deog A.
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.28 no.3
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    • pp.185-192
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    • 2008
  • We have studied effect of water treatment sludge (WTS) on trace metals of sorghum hybrid (Sorghum bicolor (L.) Moench). In the present report it was for cadmium (Cd) content on background correction (BGC) mode with an atomic absorption spectrophotometer. The four treatments were Control, Compost, Alum + nitrogen, phosphorus, potassium (NPK), Compost + NPK. In the analysis, burner height of the atomic absorption spectrophotometer was adjusted to three levels; 3 mm, 6 mm, 9 mm. As a conclusion, 3 mm and 6 mm burner height conditions were better than 9 mm height for Cd analysis. And the conditions for widening the range, the mean, and the standard deviation (SD) values of observed absorbances as well as the condition for lessening the mean of observed background values are necessary for getting the better measuring of Cd. At the present experiment, 6 mm burner height condition is the best among the three burner heights.