• Title/Summary/Keyword: Alpha phase

Search Result 1,603, Processing Time 0.026 seconds

Synthesis and Selective Gas Permeability of Liquid Crystalline Poly(allyl sulfone) Networks (액정폴리알릴술폰의 합성 및 기체 선택투과 특성)

  • Jo, Byung-Wook;Choi, Jae-Kon;Kim, Joon-Seop;Choi, Soo-Kyung
    • Elastomers and Composites
    • /
    • v.40 no.2
    • /
    • pp.136-142
    • /
    • 2005
  • Liquid crystalline poly(allylsulfone) networks having $SO_2$ in a main chain and mesogens in a side chain were synthesized and their gas permeability and permselectivity were determined. The monomer II having two allyl groups on the each end group was able to form polymer networks by polymerization reaction, while the monomer I having only one allyl group was not. Molecular motion of the poly(allylsulfone) networks were retarded with increasing the cross-linking density, and the segmental motion of networks was developed enough to show isotropic phase transition. Gas permeabilities of poly(II-5 $01/I-OCH_3$ 99) were 2.58 baller for $O_2$ and 18.4 barrer for $H_2$. It means that hydrogen gas are 7 times more permeable than oxygen. Its permselectivities were high as 23.9 for ${\alpha}(H_2/N_2)$. The permselectivity was increased with increasing the cross-linking density. For example, ${\alpha}(H_2/N_2)$ was 36.8 in poly(II-5 $10/I-OCH_3$ 90), which was shown to be the highest value among these poly(allylsulfone) networks.

Effects of Niobium Addition on the Corrosion Behavior of Ti Alloys in NaCl Solution (NaCl 용액에서 Nb 첨가가 Ti 합금의 부식 거동에 미치는 영향)

  • Kim, E.S.;Kim, W.G.;Choe, H.C.
    • Corrosion Science and Technology
    • /
    • v.12 no.1
    • /
    • pp.34-39
    • /
    • 2013
  • In this study, the effect of niobium addition on the passivation behavior of Ti alloys in NaCl solution was investigated using various electrochemical methods. An ${\alpha}$-phase in Ti alloy was transformed into a ${\beta}$-phase and martensite structure decreased as Nb content increased. The corrosion and passivation current density($+300mV_{SCE}$) decreased as Nb content increased, and thereby a stable passive film was formed on the Ti alloy. Potential of Ti-xNb alloy in the passive region increased, whereas, current density decreased with time from results of potentiostatic and galvanostatic tests. Also, the corrosion morphology showed the smaller pits as Nb content increased. Consequently, Ti alloy contained high Nb content showed a good resistance to pitting corrosion in 0.9% NaCl solution.

Validity and Reliability of Korean Version of Older Patients in Acute Care Survey (한국어판 급성기 노인 환자 돌봄 측정도구의 타당도 및 신뢰도)

  • Kim, Jung-Min;Jeong, Hyo-Eun;Han, Jeong-Won
    • The Korean Journal of Health Service Management
    • /
    • v.11 no.3
    • /
    • pp.91-104
    • /
    • 2017
  • Objectives : This study was a methodological study to verify the validity and reliability of the translated and modified Older Patients in Acute Care Survey-US (OPACS) tool, which was originally developed by Dikken and his colleagues. Methods : The OPACS was translated into Korean, and the content validity, composition validity, and reliability were verified using 348 nurses working for hospitals with over 200 beds and located in C city, B city, and K province. Results : The analysis showed that the Korean version of the OPACS had of eleven questions in the practice experience section and twelve in the general opinion section for older patients in the acute phase. Cronbach's ${\alpha}s$ were 0.84 for practice experience and 0.81 for general opinion. Conclusions : The study showed that the OPACS could measure the practice and opinion of Korean nurses who cared for elderly patients in the acute phase. The significance of the study was that it provided baseline data information regarding the performance and opinion of these nurses for nursing managers to improve the nursing environment.

A Study on the Denitrification Characteristics of Permeabilized Paracoccus denitrificans (Permeabilized Paracoccus denitrificans의 탈질 특성연구)

  • 송주영;황심연;김덕술
    • KSBB Journal
    • /
    • v.16 no.3
    • /
    • pp.290-294
    • /
    • 2001
  • The removal of nitrogen compounds from waste water is essential and is often accomplished by biological process. The denitrifying bacterium, Paracoccus denitrificans (KCTC 2530), was employed to study the characteristics and the denitrification differences of Permeabilized strains and untreated strains. The permeabilization rate increased with increasing toluene concentration, but some part of the toluene contributed to denaturing the datachment of proteins from the plasma membrane. Permeabilized Paracoccus denitrificans had long lag phase and high specific growth rate in cultivation, and showed excellent denitrification characteristic compared with untreated strains. But, in both cases, the denitrification ability was significantly reduced after 4 or 5 denitrifications. It seems that the strains fall into the death phase when the nutrient was exhausted. When the nutrient recovered to its initial level, the denitrification ability also recovered to the normal level. The results obtained were encouraging enough to apply to practical water treatment situation.

  • PDF

Cyclodextrin Glucanotransferase와 Cyclodextrinase를 생산하는 Bacillus 속 세균의 분리와 그 효소들의 특성

  • Kwon, Hyun-Ju;Nam, Soo-Wan;Kim, Kwang-Hyun;Kwak, Young-Gyu;Kim, Byung-Woo
    • Microbiology and Biotechnology Letters
    • /
    • v.24 no.3
    • /
    • pp.274-281
    • /
    • 1996
  • A bacterium producing Cyclodextrin Glucanotransferase (CGTase) and Cyclodextrinase (CDase) was isolated from soil, and named as Bacillus stearothermophilus KJ16. The growth of the isolated strain occurred in two steps, and syntheses of CGTase and CDase were dependedt on the growth cycle of the cell. CGTase was constitutively synthesized during the 1st growing phase, while CDase was synthesized inducibly during the 2nd growing phase. When the midium pH was controlled at 7.0 the maximum enzyme activities of CGTase and CDase were increased by 12-fold (1300 mU/ml) and 2-fold (225 mU/ml), respectively, compared with the pH-uncontrolled batch culture. The CGTase of the isolate converted soluble starch to CDs with the ratio of $\alpha$-CD:$\beta$-CD:$\gamma$-CD=42:46:12 at $55^{\circ}C$.The optimal pH and temperature of CGTase were 6.0 and $60^{\circ}C$, respectively and the optimal pH and temperature of CDase were 6.0 and $55^{\circ}C$. The molecular weights of the purified CGTase and CDase were estimated to be 65, 000 and 68, 000 dalton, respectively. Among several substrates, $\gamma$-CD was most rapidly hydrolyzed by the purified CDase.

  • PDF

The Thermotropic Phase Behaviors of Artificial Phospholipid Liposomes Incorporated with Soyasaponin (대두사포닌이 침투된 인공 인지질 생체유사막의 열에 의한 상변화에 관한 연구)

  • Kim, Nam-Hong;Roh, Sung-Bae
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.22 no.3
    • /
    • pp.323-327
    • /
    • 1993
  • The effect of soyasaponin on the liposomal phospholipid membrane was investigated by differential scanning calorimetry (DSC). Soyasaponins were obtained and the enthalpy changes and the sizes of cooperative unit of the transition were calculated. The thermograms of L-$\alpha$-dimyristoyl phosphatidylcholine (DMPC) incorporated with soyasaponin showed that the phase transition temperature was significantly lowered and the peak was broadened. This was attributed to the possibility that incorporation of soyasaponin into the lipid bilayers reduced the cooperative unit of phospholipid bilayers. These results indicate soyasaponin might have significant effect on the fluidity of biological membrane.

  • PDF

Preparation of Silicon Carbide Ceramics with Self-reinforced Microstructure by the Control of Starting Phases (출발상 제어에 의한 자기복합화 미세구조의 탄화규소 세라믹스 제조)

  • Lee, Jong-Kook;Kang, Hyun-Hee;Lee, Eun-Gu;Kim, Hwan
    • Journal of the Korean Ceramic Society
    • /
    • v.34 no.12
    • /
    • pp.1240-1246
    • /
    • 1997
  • Silicon carbides with self-reinforced microstructure which hore a small grain matrix and dispersed large grains with rod-like type were prepared by the liquid-phase sintering and the control of starting phases of raw materials. The specimens with self-reinforced microstructure could be obtained from the compacts with mixed compositions of $\alpha$-SiC and 10-50 % $\beta$-SiC powders and by the pressureless sintering at 185$0^{\circ}C$ for 5h. Large grains with rod or plate-like types were 4H-SiC and small grains with equi-axed type were 6H-SiC. Fracture grains with rod or plate-like types were 4h-SiC and small grains with equi-axed type were 6H-SiC. Fracture toughness of specimens with self-reinforced microstructure was increased by the crack deflection and formation of microcracking due to the existence of rod-like large grains during crack propagation.

  • PDF

Mechanical Properties of the Ceramics of the System Al2O3-ZrO2-Y2O3 Prepared by the Precipitation Method (침전법에 의한 Al2O3-ZrO2-Y2O3계 세라믹스의 기계적 특성)

  • 김준태;이홍림
    • Journal of the Korean Ceramic Society
    • /
    • v.25 no.4
    • /
    • pp.364-372
    • /
    • 1988
  • The mechanical properties and microstructure of ceramics of the system Al2O3-ZrO2-Y2O3 sintered at 1$650^{\circ}C$ for 2h after powder preparation by the precipitation method from Al2(SO4)3.18H2O, ZrOCl2.8H2O and YCl3.6H2O were investigated. The Al2O3-ZrO2-Y2O3 ceramics sintered at 1$650^{\circ}C$ for 2h after mixing alpha-Al2O3 and ZrO2-Y2O3 powders, both were separately precipitated and calcined, were found to have the relative density higher than 97.5% so that the strengthening and toughening mechanisms could be explained mainly as the stress-induced phase transformation. On the other hand, the sintered bodies prepared by co-precipitating the three starting materials were measured to have the relative density lower than 85% so that the degradation of strength were observed above 15 vol% ZrO2 contents due to the high porosity by which the effect of stress-induced phase transformation was assumed to be depressed.

  • PDF

Photospheric and Chromosphereic Oscillation in a Pore observed by NST/FISS

  • Cho, Il-Hyun;Cho, Kyung-Suk;Bong, Su-Chan;Kim, Yeon-Han;Park, Young-Deuk
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.38 no.2
    • /
    • pp.88.2-88.2
    • /
    • 2013
  • Exploration of the wave-mode identification and its propagating property in the solar pore is desirable to study the energy transfer in the solar atmosphere. The Fast Imaging Solar Spectrograph (FISS) installed at the New Solar Telescope (NST) is a unique system that can do imaging of H-alpha and Ca II 8542 band simultaneously, which is quite suitable for studying of dynamics of chromosphere. In this study, we inspect a relationship between the cross-sectional area and intensity of the pore at continuum (-0.4 nm) near the Ca II line. We find coherent oscillations of the area and intensity. They shows out-of-phase (~ 180 degree difference) in photosphere, which implies that the oscillation is fast sausage mode. We also investigate a relationship between LOS velocities above the pore obtained from the Ca II and the Ha line cores, and find no significant difference of the phase (~10 degree) between the formation heights of the lines in chromosphere.

  • PDF

2nd Nanotube Formed Surface Observation of the Ti-25Ta-xZr Alloys Using ATO Technique

  • Kim, Hyun-Ju;Lee, Ho-Jong;Choe, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2013.05a
    • /
    • pp.79-80
    • /
    • 2013
  • The purpose of this study was to investigate $2^{nd} $nanotube formed surface observation of the Ti-25Ta-xZr alloys using ATO(anodic titanium oxide) technique. Ti-25Ta-xZr alloy was anodized in 1M $H_3PO_4$ electrolytes containing 0.8 Wt. % NaF at room temperature. After formation of nanotube was achieved out, nanotube was eliminated, and then anodization was carried out repeatedly. The microstructures, phase transformation, and morphology of nanotubular Ti-25Ta-xZr alloys and process of nanotube growth by using ATO method was examined by optical microscopy (OM), X-ray diffraction (XRD), and field emission scanning electron microscopy (FE-SEM). The ${\alpha}$ phase and ${\beta}$ phases were affected to form the second nanotube morphology of Ti-25Ta-xZr alloys.

  • PDF