• Title/Summary/Keyword: Alpha phase

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Evaluation of the functional phenolic compounds as to various ripening phases of the reddish rice cultivar(Oryza sativa, Superhongmi)

  • Ham, Tae-Ho;Kwon, Soon Wook;Kwon, Young In;Ryu, Su-Noh
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.272-272
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    • 2017
  • Recently, consumer's demands are increasing for new natural functional and healthful food. These demands have encouraged a better understanding of the biochemical, chemical and nutritional composition of plant products. Superhongmi rice variety was derived from a cross between CG2-3-5-2-6-2 (Heugjinju/Suwon 425) having reddish brown color and Daeribbyeo 1 having a large grain size. Superhongmi rice headed on Sep. 5th and has 94.7 cm culm length. Taxifolin, a phenolic compound in superhongmi rice extract had high ${\alpha}-glucosidase$ inhibitory activity. The ${\alpha}-glucosidase$ inhibitory activity of the superhongmi rice extracts correlated to the taxifolin content and antioxidant activity of the extracts. A new method for quantitative determination of taxifolin in superhongmi rice variety by high performance liquid chromatography was established. A reversed-phase system with Tosoh TSK-gel $C_{18}$ column using 60% methanol in water(pH 2.4) as a mobile phase was developed. Taxifolin was detected at 280 nm and the analysis was successfully carried out within 40 min. In ripening phase, the amount of taxifolin showed a mild decreasing slope. The highest contents was 59.27mg in 100g seed on the 30 days after heading(DAH). The optimum harvesting time, considering taxifolin content, maturity rate and thousand seed weight(TSW) was DAH 50. These results suggest that superhongmi rice which has high taxifolin content has the potential to contribute as a dietary supplement for controlling hyperglycemia and oxidative stress-linked diabetes complications.

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Spatial - Frequency Analysis of time-varying Coherence using ERP signals for attentional visual stimulus (시각 자극의 집중에 따른 시간 변화에 대한 뇌 유발전위의 공간 - 주파수간 상관 변화 분석)

  • Lee, ByuckJin;Yoo, Sun-Kook
    • Science of Emotion and Sensibility
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    • v.16 no.4
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    • pp.527-534
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    • 2013
  • In this study, we analyzed spatial-frequency relationship related brain function for change of the time during attentional visual stimulus through the analysis of Coherence. With experimentation about ERP(Event Related Potential)data, it revealed that change of the phase synchronization between different scalp locations at ${\theta}$, ${\alpha}$ band. ERP between left and right frontal lobes, between the frontal and central lobes showed the phase synchronization at the P100, N200, ERP between the frontal and occipital lobes showed the phase synchronization at the P300 related information of visual stimulus. Compared to STFT using the window of a fixed length, CWT is able to multi-resolution analysis with the adjustment of parameters of mother wavelet. Thus, coherence results with CWT was found to be effective for analysis of time-varying spatial-frequency relationship in ERP. The phase synchronization for inattentional visual stimulus was not observed.

Selective Separation of Hydrogen from Gas Mixture using LaNi5 (LaNi5를 이용한 혼합기체로부터 수소의 선택적 분리)

  • Sun, Yang Kook;Nahm, Kee Suk;Lee, Wha Young
    • Journal of Hydrogen and New Energy
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    • v.1 no.1
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    • pp.15-23
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    • 1989
  • The selective separation of hydrogen from gas mixture containing hydrogen was experimentally studied using $LaNi_5$. The capacity and the rate of hydrogen separation, the purity of recovered hydrogen and the optimum condition of the regeneration of deactivated $LaNi_5$ were investigated. The separation rate and the recovery ratio of hydrogen were slowly decreased with the increase of the number of hydrogen absorption cycle. It was found that this result comes from the deactivation of $LaNi_5$ partly because of the blocking of hydrocarbon compounds in the $LaNi_5$ lattice and partly because of the poisoning of $LaNi_5$ surface by carbon monoxide contained in the gas mixture. The optimum condition for the regeneration of deactivated $LaNi_5$ was obtained by heating in a vacuum to about 637 K. The recovery ratio of hydrogen at the optimum condition was observed to be about 80%. The rates of hydrogen separation were measured in the ${\alpha}$-phase and two phase regions. The rate equations could be expressed as follows ; ${\alpha}$ - phase : $$-\frac{dP{_{H_2}}}{dt}=9.836{\times}10^{-3}(P{_{H_2}}_{-P_{eq}})$$ two phase region : $$-\frac{dP_{H{_2}}}{dt}=1.6909{\times}10^2\exp(-17560/RT)(P{_{H_2}}_{-P_{eq}})$$.

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Influence of Composition on Soft Magnetic Properties of As-Deposited Fe-Sm-O Thin Films (조성변화에 따른 Fe-Sm-O계 박막의 연자기적 성질)

  • Yoon, T.S.;Cho, W.S.;Koo, E.S.;Li, Ying;Park, J.B.;Kim, C.O.
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.39-43
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    • 2001
  • Nanocrystalline Fe-Sm-O thin films were prepared by RF magnetron reactive sputtering method in $Ar+O_2$mixed atmosphere with the $O_2$content of 5%. The compositions of the thin films were changed by changing the number of $Sm_2O_3$ chips. The best soft magnetic properties of the thin film with the composition of $Fe_{83.4}Sm_{3.4}O_{13.2}$ were saturation flux density of 18 kG, coercivity of 0.82 Oe and effective permeability about 2,600 at 0.5~100 MHz, respectively. The electrical resistivity of Fe-Sm-O thin films was increased with increasing the amount of Sm and O elements which combined each other, the electrical resistivity of$Fe_{83.4}Sm_{3.4}O_{13.2}$ thin film was $130{\mu}{\Omega}cm$. In case of the small amount of Sm and O elements, the microstructures of Fe-Sm-O thin films showed a precipitated phase of $Sm_2O_3$ on the ${\alpha}-Fe$ phase. With the increase of the amount of Sm and O elements, the microstructures of the Fe- Sm-O thin films were changed into a mixed structure of ${\alpha}-Fe$ crystal-phase and Sm-oxide amorphous phase. The Fe-Sm-O thin films with Fe content in the range of 72~94 at% exhibited the quality factor (Q = $\mu$′/$\mu$") of 7~75 up to 50 MHz.

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Gly-His-Lys Conjugated Chitosan and its Cell Proliferation Effects (Gly-His-Lys 펩타이드가 결합된 키토산과 그의 세포증식 효과에 관한 연구)

  • Ha Byung-Jo;Lee Yoon-Sik;Park Soo Nam
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.3 s.47
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    • pp.399-404
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    • 2004
  • Novel GHK-conjugated chitosan was prepared by the solid-phase method using $N^{\alpha}-Fmoc$ amino acids/BOP coupling reagent. For this purpose, the chitosan microbeads which had a mean diameter of 70 um were prepared by the W/O emulsion-phase separation method. The GHK was successfully coupled to the chitosan microbeads by stepwise solid-phase method. The result of amino aid analysis was in good agreement with the theoretical values; $Gly_{1.02}\;of\;His_{1.13}\;Lys_{0.96).$. The cell proliferation effect of the GHK-bound chitosan microbeads was measured by MTT assay. We concluded that GHK-bound chitosan microbeads gave higher cell Proliferation effect than chitosan microbeads.

Synthesis of boehmite powder from aluminum etching solution (알루미늄 에칭액으로부터 베마이트 분말 합성)

  • Park, Young-Soo;Wui, In-Hee;Cho, Woo-Seok;Kim, Jin-Ho;Hwang, Kwang-Taek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.6
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    • pp.286-290
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    • 2012
  • Boehmite (AlOOH) powder was synthesized using waste aluminium etching solution. In waste solution, precipitated phase was gibbsite ($Al(OH)_3$), and boehmite (AlOOH) phase was obtained at pH of 7 and 8 controlled by addition of acid. Boehmite powder was obtained by washing process to remove the Na ion in precipitated solution. Mean particle size of obtained powder was 40 nm. Boehmite phase transformed to ${\alpha}-Al_2O_3$ phase via ${\gamma}-Al_2O_3$, ${\delta}-Al_2O_3$, and ${\Theta}-Al_2O_3$.

Microstructure and Mechanical Properties of Mg-Li Powder by Hot Rolling Process

  • Choi, Jeong-Won;Kim, Yong-Ho;Kim, Jung-Han;Yoo, Hyo-Sang;Woo, Kee-Do;Kim, Ki-Beom;Son, Hyeon-Taek
    • Korean Journal of Materials Research
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    • v.25 no.1
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    • pp.32-36
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    • 2015
  • Hot rolling of Mg-6Zn-0.6Zr-0.4Ag-0.2Ca-(0, 8 wt%)Li powder was conducted at the temperature of $300^{\circ}C$ by putting the powder into the Cu pipe. The microstructure and mechanical properties of the samples were observed. Mg-6Zn-0.6Zr-0.4Ag-0.2Ca without Li element was consisted of ${\alpha}$ phase and precipitates. The microstructure of the 8 wt%Li containing alloy consisted of two phases (${\alpha}$-Mg phase and ${\beta}$-Li phase). In addition, $Mg_2Zn_3Li$ was formed in 8%Li added Mg-6Zn-0.6Zr-0.4Ag-0.2Ca alloy. By addition of the Li element, the non-basal planes were expanded to the rolling direction, which was different from the based Mg alloy without Li. The tensile strength was gradually decreased from 357.1 MPa to 264 MPa with increasing Li addition from 0% to 8%Li. However, the elongation of the alloys was remarkably increased from 10 % to 21% by addition of the Li element to 8%. It is clearly considered that the non-basal texture and ${\beta}$ phase contribute to the increase of elongation and formability.

Effects of Mill Annealing Temperature on the Microstructure and Hardness of Ti-6Al-4V Alloys (밀어닐링 온도가 Ti-6Al-4V 합금의 미세조직 및 경도에 미치는 영향)

  • Seo, Seong-ji;Kwon, Gi-hoon;Choi, Ho-joon;Lee, Gee-young;Jung, Min-su
    • Journal of the Korean Society for Heat Treatment
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    • v.32 no.6
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    • pp.263-269
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    • 2019
  • The mechanism of microstructure and hardness changes during mill annealing of Ti-6Al-4V alloy was investigated. The annealing heat treatments were performed at $675{\sim}795^{\circ}C$ in vacuum for 2 hours, followed by air cooling. The microstructure was observed by using an optical microscope and X-ray diffraction, and hardness was measured by using a Rockwell hardness tester and micro Vickers hardness tester. The average grain size becomes smaller at $675^{\circ}C$ to $735^{\circ}C$ due to the formation of new grains rather than grain growth, but becomes larger at $735^{\circ}C$ to $795^{\circ}C$ due to growth of the already-formed grains rather than formation of new grains. The mill annealing temperature becomes higher, the ${\beta}$ phase fraction decreases and ${\alpha}$ phase fraction increases at room temperature. This is because the higher annealing temperature, the smaller amount of V present in the ${\beta}$ phase, and thus the ${\beta}$ to ${\alpha}$ transformation occurs more easily when cooled to room temperature. As the mill annealing temperature increases, the hardness value tends to decrease, mainly due to resolution of defects such as dislocations from $675^{\circ}C$ to $735^{\circ}C$ and due to grain growth from $735^{\circ}C$ to $795^{\circ}C$, respectively.

Effects of Ti Addition on Microstructure and Mechanical Properties of Mg-xAl-yZn Magnesium Alloys by Thixomolding Process (Thixomolding 공정으로 제조된 Mg-xAl-yZn계 마그네슘 합금의 미세조직과 기계적 물성에 미치는 Ti 첨가 영향)

  • Park, Sung-Hyun;Jang, Ho-Seung;Lee, Ji-Ho;Park, No-Jin;Oh, Myung-Hoon
    • Journal of the Korean Society for Heat Treatment
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    • v.32 no.4
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    • pp.168-174
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    • 2019
  • The microstructural features and relative room temperature mechanical properties were investigated in various compositions of Mg-xAl-yZn alloys by thxiomolding process. The microstructure was composed of ${\alpha}$-Mg particles and mixture of ${\alpha}$-Mg and ${\beta}-Mg_{17}Al_{12}$ eutectic phase. The amount of ${\beta}-Mg_{17}Al_{12}$ eutectic phase in mixture was increased with increasing Al and Zn contents without grain refinement. After adding Ti content, however, the morphology of ${\beta}-Mg_{17}Al_{12}$ eutectic phase transformed from net-like to discontinuous shape and the average grain size reduced. To determine the relationship between microstructural features and their mechanical properties, a tensile test was performed at room temperature. As a result, it was found that the mechanical properties were improved in all of Ti contained alloys due to increased elongation and the mechanisms are discussed in terms of microstructural evolution.

Synthesis and Phase Relations of Potassium-Beta-Aluminas in the Ternary System K2O-MgO-Al2O3 (K2O-MgO-Al2O3 3성분계에서 K+-β/β"-Al2O3의 합성 및 상관계)

  • Ham, Choul-Hwan;Lim, Sung-Ki;Lee, Chung-Kee;Yoo, Seung-Eul
    • Applied Chemistry for Engineering
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    • v.10 no.7
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    • pp.1086-1091
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    • 1999
  • $K^+-{\beta}/{\beta}"-Al_2O_3$ in the ternary system $K_2O-MgO-Al_2O_3$ was directly synthesized by solid state reaction. The phase formation and phase relation were carefully investigated in relation to starting composition, calcining temperature and time, and dispersion medium. The optimal synthetic condition was also examined for the formation of ${\beta}"-Al_2O_3$ phase with a maximum fraction. As a composition range, the mole ratio of $K_2O$ to $Al_2O_3$ was changed from 1:5 to 1:6.2 and the amount of MgO used as a stabilizer was varied from 4.2 wt % to 6.3 wt %. The calcining temperature was selected between $1000^{\circ}C$ and $1500^{\circ}C$. At $1000^{\circ}C$, the ${\beta}/{\beta}"-Al_2O_3$ phases began to form resulted from the combining of ${\alpha}-Al_2O_3$ and $KAlO_2$ and increased with temperature rising. All of ${\alpha}-Al_2O_3$ phase disappeared to be homogenized to the ${\beta}/{\beta}"-Al_2O_3$ phase at $1200^{\circ}C$. Near the temperature at $1300^{\circ}C$, the fraction of ${\beta}"-Al_2O_3$ phase showed a maximum value with the composition of $K_{1.67}Mg_{0.67}Al_{10.33}O_{17}$. At temperatures above $1300^{\circ}C$, the fraction of ${\beta}"-Al_2O_3$ phase decreased gradually owing to $K_2O$ loss caused by a high potassium vapor pressure, and the appropriate calcining time was about 5 hours. Acetone was more effective than distilled water as a dispersion medium for milling and mixing.

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