• 제목/요약/키워드: Allylsilane

검색결과 7건 처리시간 0.021초

Thermal and Photoinduced Silylallylation Reactions of Organic Halides with 3-Stannyl-2-(silylmethyl)propene

  • 강경태;황성심;곽우영;윤웅찬
    • Bulletin of the Korean Chemical Society
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    • 제20권7호
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    • pp.801-804
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    • 1999

  • Thermal and photoinduced silylallylation reactions of organic halides with 3-stannyl-2-(silylmethyl)propene are explored. Silylallylations occur in moderate to high yields, producing various functionalized allylsilane products in which halide carbon is bonded to the terminal alkenic carbon of allylsilane with the removal of tributyltin group. The reactions, which tolerate functional groups such as carbonyl, ester, nitrile, acetal, and ketal, hold synthetic potential for the construction of functionalized allylsilanes.

  • https://doi.org/10.5012/bkcs.1999.20.7.801 인용 PDF

Stereocontrolled Preparation of 2,6-Disubstituted 4-Methylenetetrahydropyrans by Lewis Acid Promoted Allylsilane-Acetal Cyclization

  • 성태명;곽우영;강경태
    • Bulletin of the Korean Chemical Society
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    • 제19권8호
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    • pp.862-868
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    • 1998

  • The Lewis acid mediated intramolecular additions of allylsilanes to acetal substrates are described. Excellent regio- and diastereoselectivity are achieved by boron trifluoride promoted cyclization of allysilane-acetals 5 and 8 derived from hydroxy allysilances 3. Cyclizations occur in moderate to high yields, providing directr routes to cis-2, 6-disubstituted 4-methylenetetrahydropyrans 6 and 9.

  • https://doi.org/10.5012/bkcs.1998.19.8.862 인용 PDF