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Properties Analysis of Environment Friendly Coating Films Formed by Using Electrodeposition Principle on Seawater (해수환경중 전착원리에 의해 형성시킨 환경친화적인 코팅막의 특성 분석)

  • Baek, S.M.;Lee, C.S.;Kim, K.J.;Moon, K.M.;Lee, M.H.
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.196-197
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    • 2005
  • Cathodic protection is one of the successful ways to prevent corrosion of steel structures in marine environments. The unique feature of cathodic protection in seawater is the formation of calcareous deposits on cathodic metal surface. The formation principles of calcareous deposit seawater had been known for a long time. That is, cathodic reduction reactions associated with cathodic protection in seawater generate $OH^-$ at the metal surface in accordance with the formular ; 1/2 $O_2$ + $H_2O$ + $2e^-$ $2OH^-$ and $2H_2O$ + $2e^-$ ${\rightarrow}$ $H_2$ + $2OH^-$. These reactions increase the pH at the metal / seawater interface. The high pH causes precipitation of $Mg(OH)_2$ and $CaCO_3$ in accordance with the formular ; $Mg^{2+}$ + $2(OH)^-$ ${\rightarrow}$ $Mg(OH)_2$ and $Ca^{2+}$ + $HCO_3^-$ + $OH^-$ ${\rightarrow}$ $H_2O$ + $CaCO_3$. These are typically the main compounds in calcareous deposits. It obviously has several advantages compared to the conventional coatings, since the environment-friendly calcareous deposit coating is formed by the elements($Mg^{2+}$, $Ca^{2+}$) naturally present in seawater. In this study, environmental friendly calcareous deposit films were prepared on steel plates by electro plating technic in natural seawater. The influence of current density on composition ratio, structure and morphology of the coated films were investigated by scanning electron microscopy formation process of calcareous deposits films in natural seawater. And we confirmed the properties of all the films can be improved greatly by controlling the material structure and morphology with effective use of the electroplating method in natural seawater.

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Plasma Sex Steroid Hormone Profiles and Testicular Development in Artificially Maturing Cultured Mille Eel, Anguilla japonica (양식산 수컷 뱀장어 Anguilla japonica의 인위적 성숙유도에 따른 혈중 성호르몬 변동과 정소 발달)

  • Kim, Eung-Oh;Bae, Jun-Yong;Lim, Sang-Gu;Son, Maeng-Hyun;Park, Min-Woo;Park, Mi-Seon;Cho, Yong-Chul;Kim, Dae-Jung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.39 no.6
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    • pp.466-471
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    • 2006
  • We investigated the changes in body weight (BW), plasma sex steroid hormone profiles, and testicular development of cultured male eel Anguilla japonica during an artificial maturation process. Eels that received weekly intraperitoneal injections of eel's ringer solution containing human chronic gonadotropin (HCG) were examined. In the ringer-treated control, BW changes decreased slowly during the experimental period. Plasma testosterone (T), 11-ketotestosterone (11-KT) and $17{\alpha},\;20{\beta}$-dihydroxy-4-pregnen-3-one (DHP) levels In the control remained low and did not show significant changes. Moreover, all germ cells in the testes of the control were spermatogonia. In the HCG-treated male eels, however, BW changes increased gradually from the fifth week and then decreased slowly. The plasma T level increased rapidly (p<0.05) in the second week and then decreased slowly. The plasma 11-KT level increased dramatically (p<0.05) in the second week and was maintained until the end of the experiment. The plasma DHP level increased progressively from the second week and peaked in the eighth week (p<0.05). The testes of HCG-treated male eels were more developed than those of the control; most were at the spermatozoa and spermatid stages and showed active spermiation. Thus, spermatogenesis and spermiation in the cultured eel can be induced by repeated injections of HCG.

Optimal Design Of Multisite Batch-Storage Network under Scenario Based Demand Uncertainty (다수의 공장을 포함하는 불확실한 수요예측하의 회분식 공정-저장조 망의 최적설계)

  • 이경범;이의수;이인범
    • Journal of Institute of Control, Robotics and Systems
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    • v.10 no.6
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    • pp.537-544
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    • 2004
  • An effective methodology is reported for determining the optimal lot size of batch processing and storage networks which include uncertain demand forecasting. We assume that any given storage unit can store one material type which can be purchased from suppliers, internally produced, infernally consumed, transported to or from other sites and/or sold to customers. We further assume that a storage unit is connected to all processing and transportation stages that consume/produce or move the material to which that storage unit is dedicated. Each processing stage transforms a set of feedstock materials or intermediates into a set of products with constant conversion factors. A batch transportation process can transfer one material or multiple materials at once between sites. The objective for optimization is to minimize the probability averaged total cost composed of raw material procurement, processing setup, transportation setup and inventory holding costs as well as the capital costs of processing stages and storage units. A novel production and inventory analysis formulation, the PSW(Periodic Square Wave) model, provides useful expressions for the upper/lower bounds and average level of the storage inventory. The expressions for the Kuhn-Tucker conditions of the optimization problem can be reduced to two sub-problems. The first yields analytical solutions for determining lot sires while the second is a separable concave minimization network flow subproblem whose solution yields the average material flow rates through the networks for the given demand forecast scenario. The result of this study will contribute to the optimal design and operation of the global supply chain.

Characteristics of Crystalline Silicon Solar Cells with Double Layer Antireflection Coating by PECVD (결정질 실리콘 태양전지의 이중 반사방지막 특성에 대한 연구)

  • Kim, Jin-Kuk;Park, Je-Jun;Hong, Ji-Hwa;Kim, Nam-Soo;Kang, Gi-Hwan;Yu, Gwon-Jong;Song, Hee-Eun
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.243-247
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    • 2012
  • The paper focuses on an anti-reflection (AR) coating deposited by PECVD in silicon solar cell fabrication. AR coating is effective to reduce the reflection of the light on the silicon wafer surface and then increase substantially the solar cell conversion efficiency. In this work, we carried out experiments to optimize double AR coating layer with silicon nitride and silicon oxide for the silicon solar cells. The p-type mono crystalline silicon wafers with $156{\times}156mm^2$ area, 0.5-3 ${\Omega}{\cdot}cm$ resistivity, and $200{\mu}m$ thickness were used. All wafers were textured in KOH solution, doped with $POCl_3$ and removed PSG before ARC process. The optimized thickness of each ARC layer was calculated by theoretical equation. For the double layer of AR coating, silicon nitride layer was deposited first using $SiH_4$ and $NH_3$, and then silicon oxide using $SiH_4$ and $N_2O$. As a result, reflectance of $SiO_2/SiN_x$ layer was lower than single $SiN_x$ and then it resulted in increase of short-circuit current and conversion efficiency. It indicates that the double AR coating layer is necessary to obtain the high efficiency solar cell with PECVD already used in commercial line.

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A Workflow Time Analysis Applying the Queueing Model (대기행렬모형에 의한 워크플로우 시간분석)

  • Park, Jinsoo
    • Journal of the Korea Society for Simulation
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    • v.23 no.3
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    • pp.1-9
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    • 2014
  • Traditional workflow time analyses have been performed treating an activity as an independent M/M/1queueing system. Using the general forms of performance measures in the M/M/1 system, various aspects of analyses can be performed. Especially, on the time analysis of an AND structure in a workflow system, the mean system sojourn time can be formalized by applying the performance measures of M/M/1 system. In the real workflow system, the AND structure cannot be described correctly under the assumption of independent M/M/1 systems. To overcome this limitation, this research makes the assumption that the all activities for a task starts simultaneously. In this situation, the theoretical solution can be derived using the performance measures of the M/G/1 system. In addition, the simulation modeling method will be proposed to analyze the AND structure of a real workflow system. Finally, some numerical results from the theoretical solutions and simulation models will be provided for verification. The main performance measures used in this research are mean queueing time and mean sojourn time.

Vitrification of Highly Active Liquid Waste(I) (Thermal Decomposition of Nitrates and Additives for Glass-making)

  • Chun, Kwan-Sik;Lee, Sang-Hoon
    • Nuclear Engineering and Technology
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    • v.9 no.4
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    • pp.211-222
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    • 1977
  • The decomposition of all the individual chemicals used in the Harwell inactive vitrification pilot plant has been studied by means of a thermal balance. Weight loss curves to 110$0^{\circ}C$ have been obtained. The four materials (sodium nitrate, cesium nitrate, lithium nitrate and ruthenium nitroso-nitrate solution) showed a greater weight loss than that based on an oxide yield, and hence these compounds of their products of decomposition are volatile below 110$0^{\circ}C$. The remaining materials suffered a weight loss no more than that corresponding to a full yield of the oxide, and hence they were not volatile below 110$0^{\circ}C$. Most of chemicals begin to decompose at less than 75$^{\circ}C$ but the nitrates of cesium, strontium, barium and sodium not until 295$^{\circ}C$ to 59$0^{\circ}C$. The results obtained can be used in the analysis of process conditions in the vitrification and calcination of highly radioactive wastes and also of the thermal decomposition behaviour of mixtures containing those materials.

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A study on the design and cooling of the heat sink with hybrid structure of conductive polymer composite and metal (열전도성 고분자 복합소재/금속 소재 하이브리드 구조의 방열기구 설계 및 방열특성에 관한 연구)

  • Yoo, Yeong-Eun;Kim, Duck Jong;Yoon, Jae Sung;Park, Si-Hwan
    • Design & Manufacturing
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    • v.10 no.3
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    • pp.14-19
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    • 2016
  • Thermally or electrically conductive filler reinforced polymer composites are extensively being developed as the demand for light weight material increases rapidly in industiral applications need good conductivity such as heat sink of the electronics or light. Carbon or ceramic materials like graphite, carbon nanotube or boron nitride are typical conductive fillers with good thermal or electical conductivity. Using these conductive fillers, the polymer composites in the market show wide range of thermal conductivity from approximately 1 W/mK to 20 W/mK, which is quite enhanced considering the thermal conductivity lower than 0.5 W/mK for most polymeric materials. The practical use of these composites, however, is yet limited to specific applications because most composites are still not conductive enough or too difficult to process, too brittle, too expensive for higher conductivity. For practical use of conductive composite, the thermal conductivity required depending on the heat releasing mode are studied first for simplified unit cooling geometry to propose thermal conductivities of the composites for reasonable cooling performance comparing with the metal heat sink as a reference. Also, as a practical design for heat sink based on polymer composite, composite and metal sheet hybrid structures are investigated for LED lamp heat sink and audio amplication module housing to find that this hybrid structure can be a good solution considering all of the cooling performance, manufacturing, mechanical performance, cost and weight.

Form-Finding of Tensegrity Structures based on Eigenvalue Formulation (고유치문제로 정식화된 텐세그러티 구조물의 형상탐색)

  • Jung, Mi-Roo;Lee, Jae-Hong
    • Journal of Korean Association for Spatial Structures
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    • v.10 no.2
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    • pp.87-94
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    • 2010
  • Form-Finding of tensegrity structures by eigenvalue problem is presented, In ardor to maintain the structures stable, "Form-Finding" should be performed. The types of analytical methods are known to solve this phenomenon: One is to use force density method, and the other is to apply so called, generalized inverse method. In this paper, new form finding methods are presented to obtain the self-equilibrium stress of the tensegrity structures. This method is based on the equilibrium equation of the all of the joint and the governing equation is formulated as eigonvalue problem. In order to verify this approach, numerical example(tensegrity structures) are compared with others calculated by previous methods. The solution by present method is shown identical results. Furthermore, the developed process to find the results is more efficient than previous approaches.

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Design and Load Map of the Next Generation Convergence Security Framework for Advanced Persistent Threat Attacks

  • Lee, Moongoo
    • IEIE Transactions on Smart Processing and Computing
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    • v.3 no.2
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    • pp.65-73
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    • 2014
  • An overall responding security-centered framework is necessary required for infringement accidents, failures, and cyber threats. On the other hand, the correspondence structures of existing administrative, technical, physical security have weakness in a system responding to complex attacks because each step is performed independently. This study will recognize all internal and external users as a potentially threatening element. To perform connectivity analysis regarding an action, an intelligent convergence security framework and road map is suggested. A suggested convergence security framework was constructed to be independent of an automatic framework, such as the conventional single solution for the priority defense system of APT of the latest attack type, which makes continuous reputational attacks to achieve its goals. This study suggested the next generation convergence security framework to have preemptive responses, possibly against an APT attack, consisting of the following five hierarchical layers: domain security, domain connection, action visibility, action control, and convergence correspondence. In the domain, the connection layer suggests a security instruction and direction in the domains of administrative, physical and technical security. The domain security layer has consistency of status information among the security domain. A visibility layer of an intelligent attack action consists of data gathering, comparison and decision cycle. The action control layer is a layer that controls the visibility action. Finally, the convergence corresponding layer suggests a corresponding system of before and after an APT attack. The administrative security domain had a security design based on organization, rule, process, and paper information. The physical security domain is designed to separate into a control layer and facility according to the threats of the control impossible and control possible. Each domain action executes visible and control steps, and is designed to have flexibility regarding security environmental changes. In this study, the framework to address an APT attack and load map will be used as an infrastructure corresponding to the next generation security.

Asymptotic Analysis for Hydraulic Fractures and Applicability of Boundary Collocation Method (수압파쇄균열의 점근적 해석과 경계병치법의 적용성)

  • Sim Young-Jong;kim Hong-Ta다
    • Journal of the Korean Geotechnical Society
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    • v.21 no.6
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    • pp.93-100
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    • 2005
  • The occurrence of multi-segmented hydraulic fractures that show different behavior from the single fracture is common phenomenon. However, it is not easy to evaluate the behavior of multiple fractures computed by most numerical techniques because of complicated process computation. This study presents how to efficiently calculate the displacement of the multi-segmented hydraulic fractures using the boundary collocation method (BCM). First of all, asymptotic solutions are obtained for the closely spaced overlapping fractures and are compared with those by the BCM where the number of collocation points is varied. As a result, the BCM provides an excellent agreement with the asymptotic solutions even when the number of collocation points is reduced ten times as many as that of conventional implementations. Accordingly, the numerical simulation of more realistic and, hence, more complex fracture geometries by the BCM would be valid with such a significant reduction of the number of collocation points.