• 전기화학회지
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• 제12권1호
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• pp.54-60
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• 2009

The redox characteristics of 2-arylaldehydehydrazono-3-phenyl-5-substituted-2, 3-dihydro-1, 3, 4-thiadiazoles (1a-h) have been investigated in nonaqueous solvents such as 1, 2-dichloroethane (DCE), dichloromethane (DCM), acetonitrile (AN), Tetrahydrofuran (THF), and dimethylsulfoxide (DMSO) at platinum electrode. Through controlled potential electrolysis, the oxidation and reduction products of the investigated compounds had been separated and indentified. The redox mechanism had been suggested and proved. It had been found that all the investigated compounds were oxidized in two irreversible one-electron processes following the well-known pattern of The EC-mechanism; the first electron loss gives the corresponding cation-radical which is followed by proton removal from the ortho-position in the N-phenyl ring forming the radical. The obtained radical undergoes a second electron uptake from the nitrogen in the N = C group forming the unstable intermediate (di-radical cation) which undergoes ring closure forming the corresponding cation. The formed cation was stabilized in solution through its combination with a perchlorate anion from the medium. On the other hand, these compounds are reduced in a single two-electron process or in a successive two one-electron processes following the well known pattern of the EEC-mechanism according to the nature of the substituent; the first one gives the anion-radical followed by a second electron reduction to give the dianion which is basic enough to abstract protons from the media to saturate the (C = O) bond.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.193.1-193.1
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• 2014

This study was to investigate the electronic structure and optical properties of Na doped into NiO thin film using XPS and REELS. The films were grown by electron beam evaporation with varying the annealing temperature. The relationship between the electrical characteristics with the local structure of NiO thin films was also discussed. The x-ray photoelectron results showed that the Ni 2p spectra for all films consist of Ni 2p3/2 which indicate the presence of Ni-O bond from NiO phase and for the annealed film at temperature above $200^{\circ}C$ shows the coexist Ni oxide and Ni metal phase. The reflection electron energy loss spectroscopy spectra showed that the band gaps of the NiO thin films were slightly decreased with Na-doped into films. The Na-doped NiO showed relatively low resistivity compared to the undoped NiO thin films. In addition, the Na-doped NiO thin films deposited at room temperature showed the best properties, such as a p-type semiconducting with low electrical resistivity of $11.57{\Omega}.cm$ and high optical transmittance of ~80% in the visible light region. These results indicate that the Na doping followed by annealing process plays a crucial in enhancing the electrical and optical properties of NiO thin films. We believe that our results can be a good guide for those growing NiO thin films with the purpose of device applications, which require deposited at room temperature.

• Journal of the Korean Wood Science and Technology
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• 제23권2호
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• pp.55-69
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• 1995

The primary objective of this research was to investigate optimum manufacturing condition of thin composite panels composed of sawdust, polyethylene film and polypropylene net. At the study the experiment was designed to make thin board in which sawdust offers effectiveness as core composing material, polyethylene as adhesive with added urea resin, and polypropylene as stiffness and flexibility in the composition panel. 100 types of thin composite panels were manufactured according to press-lam and mat-forming process of various hot pressing conditions(pressure, temperature and time). They were tested and compared with control boards on bending properties(MOR, MOE, SPL, WML), internal bond strength, thickness swelling, linear expansion and water absorption. At the same time the visual inspections of each types of panels were accomplished. The physical and mechanical properties of composite types passed by visual inspection were analyzed by Tukey's studentized range test. From the statistical analysis, the optimum manufacturing condition of thin composite panels were selected. Compared with two manufacturing processes, mat-forming process performed better than press-lam process in all tested properties. The optimum manufacturing conditions resulted from the experiment and statistical analysis were able to determine as following: the press temperature was shown the most good result at 130$^{\circ}C$ in mat forming process and 140$^{\circ}C$ press lam process, the press time 4 min in both processes, but the press pressure was 25-10kg/$cm^2$ in mat forming and 15k/$cm^2$ press lam process.

• 대한화학회지
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• 제24권2호
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• pp.150-154
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• 1980

Benzyl benzenesulfonate와 피리딘의 반응속도를 아세톤 용매중에서 20∼$40^{\circ}C$ 및 1∼2000 bars에서 전기전도도법으로 측정하였다. 반응속도는 온도 및 압력이 증가함에 따라 증가하였다. 이 반응의 활성화엔탈피$({\Delta}H^{\neq})$, 엔트로피$({\Delta}S^{\neq})$ 그리고 활성화부피$({\Delta}V^{\neq})$를 구하였다. 이 반응에서 압력변화에 대한 $({\Delta}H^{\neq})$와 $({\Delta}S^{\neq})$사이에 등속관계가 성립하였으며 등속온도는 $342^{\circ}K$였다. 이상의 결과로 본 반응은 전이상태에서 $C{\cdots}N$ 결합형성이 주로 반응속도를 결정하는 $S_N2$ 반응 메카니즘으로 진행된다는 것을 알았다.

• 대한화학회지
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• 제35권1호
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• pp.64-69
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• 1991

아세토니트릴 용매 중에서 p-methylphenacyl arenesulfonate와 피리딘의 반응을 1∼2000 bars 및 35∼55$^{\circ}C$에서 전기전도도법으로 측정하였다. 반응속도는 온도와 압력의 증가에 따라 증가하였으며, 이탈기에 전자받개 치환기가 도입됨에 따라 증가하였다. 활성화엔탄피, 엔트로피 및 부피로부터 이 반응은 전반적으로 S$_N$2 반응으로 진행되나 압력이 증가함에 따라 C${\cdots}$O 결합분열이 더욱 진전된 dissociative S$_N$2 반응으로 진행됨을 알 수 있었다.

• 대한화학회지
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• 제37권6호
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• pp.577-584
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• 1993

아세토니트릴 용매내에서 파라치환 염화벤조일류와 피리딘류의 반응속도를 온도와 압력변화에 따라 전기전도도법으로 측정하여 유사1차반응속도상수와 2차반응속도상수를 구하였다. 이들 반응속도상수로부터 활성화파라미터들(${\Delta}V^\neq, {\Delta}{\beta}^{\neq}, {\Delta}H^{\neq}, {\Delta}S^{\neq} {\Delta}G^{\neq}$)과 Hammett ρ를 구하였다. 이때 ${\Delta}V^\neq, {\Delta}{\beta}^{\neq}및 {\Delta}S^{\neq}$는 모두 음의 값을 나타내었으며, 모든 압력 조건에서 친핵체의 치환기 효과 ρ$_X$는 음의 값을 기질의 치환기효과 ρ$_Y$는 양의 값을 나타내었다. 압력과 치환기 변화에 따른 속도론적 연구를 종합하면, 전체적인 반응은 전형적인 S$_N$2 반응메카니즘을 따르며, 압력 증가에 따라 결합형성이 더욱 촉진된 반응메카니즘으로 진행됨을 알 수 있다.

• 한국도로학회논문집
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• 제6권1호
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• pp.47-56
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• 2004

신 구 콘크리트의 부착강도 시험시 두 재료의 계면에서 파괴가 유도되어 순수한 부착강도를 측정할 수 있도록 계면에 원형의 비부착면을 삽입하여 직접인발시험에 의해 부착강도를 측정하는 실험방법을 제시하였다. 먼저, 새로 제안한 실험방법에 의해 계면에서 응력이 집중되는 정도를 파악하기 위해 유한요소해석을 수행하여 두 재료의 탄성계수비 및 비부착면의 면적 (균열률)에 따른 계면에서의 파괴에너지를 산정하였으며, 부재의 크기 및 하중에 대한 보정을 감안하여 무차원함수로 환산하였다. 그리고 본 연구에서 제시된 부착강도 시험방법의 신뢰성을 입증하기 위해, 3가지 크기의 원형 비부착면(균열률 0.2, 0.4. 0.6)이 삽입된 신 구 콘크리트 복합시편(유황 폴리머 콘크리트+보통 콘크리트)을 사용하여 부착강도를 측정하였고 앞서 전개된 무차원함수로부터 계면 파괴에너지를 역산하였다. 시험결과, 모든 시편이 계면에서 파괴가 유도되었다. 또한 실험 데이터 및 해석결과를 분석하여 균열률이 0.4$\sim$0.6인 경우에 부착강도의 오차가 가장 적게 발생될 수 있음을 파악하였다.

• 한국조리학회지
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• 제22권5호
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• pp.339-351
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• 2016

본 연구에서는 2016년 3월 1일부터 3월 30일까지 시행하였으며, 설문 대상은 서울 소재 특1급 호텔 무작위 10곳을 선정하여 뷔페주방과 일식주방, 카페주방에 종사하는 조리사를 대상으로 257부를 자료 처리하였다. 호텔 조리사의 라포르의 하위변수인 즐거운 관계, 대인적유대감 2가지를 변수로 설정하였고, 종속변수는 감정노동을 표면행위, 감정행위, 내면행위로 3가지 변수로 설정하고, 회귀분석으로 실시하였다. 회귀분석의 즐거운 관계(${\beta}=.236$, p<.001), 대인적유대감(${\beta}=.553$, p<.001)으로 종속변수인 감정노동의 표면행위에 대하여 모두 유의한 정(+)의 영향관계가 있는 것으로 분석되었다. 둘째, 즐거운 관계 (${\beta}=-.020$, p<.001), 대인적유대감(${\beta}=.002$, p<.001)으로 종속변수인 감정노동의 감정행위에 대하여 모두 영향관계가 없는 것으로 분석되었다. 셋째, 즐거운 관계 (${\beta}=.075$)으로 영향관계가 없는 것으로 나타났으나, 대인적유대감(${\beta}=.730$, p<.001)으로 종속변수인 감정노동의 내면행위에 영향관계가 있는 것으로 분석되었다. 넷째, 표면행위(${\beta}=-.109$)로 영향관계가 없는 것으로 나타났으나, 감정행위(${\beta}=.289$, p<.001)는 종속변수인 직무소진에 정(+)의 영향관계가 있는 것으로 분석되었으나, 내면행위(${\beta}=-.306$, p<.001)로 부(-)의 영향관계가 있는 것으로 분석되었다. 다섯째, 표면행위(${\beta}=-.049$)로 영향관계가 없는 것으로 나타났으나, 감정행위(${\beta}=-.080$, p<.001)와 내면행위(${\beta}=.668$, p<.001)는 종속변수인 조직만족에 정(+)의 영향관계가 있는 것으로 분석되었다.

• Restorative Dentistry and Endodontics
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• 제12권1호
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• pp.131-147
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• 1986

The purpose of this study was to observe the color matching of lining or filling materials according to the remaining tooth material. Twenty-seven freshly extracted human central incisors were used in this experiments. The teeth were stored in saline solution at room temperature after extraction. All teeth were cut parallel to the tangent to height of contour on labial surface from the lingual surface until the pulp were completely removed. Then 27 teeth were devided into 0.5mm, 1.0mm and 1.5mm reduction groups according to the thickness of cutting the lingual surfaces of teeth. The specimens of control group were three teeth of 27 teeth with cutting the lingual surface same mode as above described. In the specimens of experimental groups, 8 kinds of lining and filling materials; FUJI IONOMER TYPE II (G-C Co. Japan), LINING CEMENT (G-C Co. Japan), Dycal (Caulk, U.S.A.), CLEARFIL F II (Kuraray Co. Japan), Crown Bridge & Inlay Cement (G-C Co. Japan), Copalite (Harry J. Bosworth Co. U.S.A.), HY-BOND (G-C Co. Japan) and LIV-CENERA (G-C Co. Japan); applied on the back of 24 teeth with 0.5mm, 1.0mm and 1.5mm cut thickness of lingual surfaces. Three teeth of control group did not applied linging or filling materials on the back of 3 kinds of different thickness of cutting the lingual surfaces. The absorbances of total 27 specimens were obtained by reflection spectrophotometer. (Cary 17 D, Varian Co, U.S.A.) The following conclusions were drawn from above the results; 1. The absorbance patterns in both experiment and control groups were gradually decreased with increasing wavelength of spectra. 2. The absorbance patterns were not decreased in relation to the kinds of lining or filling materials, but the amount of the remaining tooth materials. 3. In 0.5mm reduction group, FUJI IONOMER TYPE II, LINING CEMENT, LIV-CENERA and Copalite applied on the back of cut lingual surface showed similar absorbance patterns as control group. 4. The specimens which were reduced up to 1.0mm thickness and lined with FUJI IONOMER TYPE II and LINING CEMENT showed the comparable absorbance patterns to the control group. 5. In case of HY-BOND application after 1.5mm reduction were observed the similar absorbance pattern as compared with control group. 6. When Dycal, CLEARFIL and Crown Bridge & Inlay Cement were applied to cut teeth surfaces, there were much differences of absorbance between control groups and experimental groups.

• The Journal of Advanced Prosthodontics
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• 제8권1호
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• pp.1-8
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• 2016

PURPOSE. The purpose of this study was to evaluate the efficacy of two different metal conditioners for non-precious metal alloys for the bonding of porcelain to a cobalt-chromium (Co-Cr) alloy. MATERIALS AND METHODS. Disk-shaped specimens ($2.5{\times}10.0mm$) were cast with Co-Cr alloy and used as adherend materials. The bonding surfaces were polished with a 600-grid silicon carbide paper and airborne-particle abraded using $110{\mu}m$ alumina particles. Bonding specimens were fabricated by applying and firing either of the metal conditioners on the airborne-particle abraded surface, followed by firing porcelain into 5 mm in diameter and 3 mm in height. Specimens without metal conditioner were also fabricated. Shear bond strength for each group (n=8) were measured and compared (${\alpha}=.05$). Sectional view of bonding interface was observed by SEM. EDS analysis was performed to determine the chemical elements of metal conditioners and to determine the failure modes after shear test. RESULTS. There were significant differences among three groups, and two metal conditioner-applied groups showed significantly higher values compared to the non-metal conditioner group. The SEM observation of the sectional view at bonding interface revealed loose contact at porcelain-alloy surface for non-metal conditioner group, however, close contact at both alloy-metal conditioner and metal conditioner-porcelain interfaces for both metal conditioner-applied groups. All the specimens showed mixed failures. EDS analysis showed that one metal conditioner was Si-based material, and another was Ti-based material. Si-based metal conditioner showed higher bond strengths compared to the Ti-based metal conditioner, but exhibited more porous failure surface failure. CONCLUSION. Based on the results of this study, it can be stated that the application of metal conditioner is recommended for the bonding of porcelain to cobalt-chromium alloys.