• Title/Summary/Keyword: All Solid State.

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Study on Electrochemical Performances of PEO-based Composite Electrolyte by Contents of Oxide Solid Electrolyte (산화물계 고체전해질 함량에 따른 PEO 기반 복합전해질 전기화학 성능 연구)

  • Lee, Myeong Ju;Kim, Ju Young;Oh, Jimin;Kim, Ju Mi;Kim, Kwang Man;Lee, Young-Gi;Shin, Dong Ok
    • Journal of the Korean Electrochemical Society
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    • v.21 no.4
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    • pp.80-87
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    • 2018
  • Safety issues in Li-ion battery system have been prime concerns, as demands for power supply device applicable to wearable device, electrical vehicles and energy storage system have increased. To solve safety problems, promising strategy is to replace organic liquid electrolyte with non-flammable solid electrolyte, leading to the development of all-solid-state battery. However, relative low conductivity and high resistance from rigid solid-solid interface hinder a wide application of solid electrolyte. Composite electrolytes composed of organic and inorganic parts could be alternative solution, which in turn bring about the increase of conductivity and conformal contact at physically rough interfaces. In our study, composite electrolytes were prepared by combining poly(ethylene oxide)(PEO) and $Li_7La_3Zr_2O_{12}$ (LLZO). The crystallinity, morphology and electrochemical performances were investigated with the control of LLZO contents from 0 wt% to 50 wt%. From the results, it is concluded that optimum content and uniform dispersion of LLZO in polymer matrix are significant to improve overall conductivity of composite electrolyte.

Microwave Properties of Co2 Ferrite for Miniaturization of Antenna (안테나 소형화를 위한 Co2 페라이트의 마이크로파 특성)

  • Kim, Jae-Sik;Choi, Eui-Sun;Kim, Kang;Lee, Young-Hie;Song, Sung-Ho;Ahn, Jong-Bok;Kim, Byung-Hwan;Choi, Ji-Young
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.60 no.12
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    • pp.2270-2275
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    • 2011
  • The sintering behavior and microwave properties of ferrite ($Ba_3Co_{2-2x}Zn_{2x}Fe_{24}O_{41}$ ceramics) were investigated for microwave applications. Also PIFA type antenna with ferrite was simulated. All samples were prepared by the solid state reaction method and sintered at $1350^{\circ}C$. All ceramics had relatively density above of 92% compare with theoretical density of $Ba_3Co_2Fe_{24}O_{41}$ ceramics. From the XRD pattens, the Z-type phase was existed as main phase in $Ba_3Co_{2-2x}Zn_{2x}Fe_{24}O_{41}$ ceramics. The permittivity and permeability of $Ba_3Co_{2-2x}Zn_{2x}Fe_{24}O_{41}$ ceramics were increased with Zn additions and decreased rapidly over frequency of 200~600 MHz. Several PIFA type antennas with ferrite and FR4 were simulated. All antenna structure had return loss of less than -10 dB at each resonant frequency. Simulated antenna using both ferrite and FR4 showed size reduction of 25% without a significant decrement of efficiency.

Microstructure and Dielectric Properties of Low Temperature Sintering (Ba0.86Ca0.14)(Ti0.85Zr0.12Sn0.03)O3 System Ceramics (저온소결 (Ba0.86Ca0.14)(Ti0.85Zr0.12Sn0.03)O3계 세라믹스의 미세구조와 유전 특성)

  • Yoo, Ju-Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.7
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    • pp.404-407
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    • 2016
  • In this study, to develop low temperature sintering capacitor composition ceramics with the good dielectric properties, $(Ba_{0.86}Ca_{0.14})(Ti_{0.85}Zr_{0.12}Sn_{0.03})O_3$ (BCTZ) ceramics were prepared by the conventional solid-state reaction method. The effects of $B_2O_3$ addition on the dielectric properties and microstructure was investigated. The XRD patterns demonstrated that all the specimens showed Perovskite phase, and secondary phases are indicated in the measurement range of XRD. And also, temperature coefficient of capacitance(TCC) of all the specimen sintered at $1,180^{\circ}C$ showed +3~-56% except for x=0.006. For all the specimens, observed one peak was tetragonal cubic difuse phase transition temperature(Tc), which is located in the vicinity of room temperature.

Microstructure and Dielectric Properties of (Ba1-xCax)(Ti0.85Zr0.12Sn0.03)O3 Ceramics ((Ba1-xCax)(Ti0.85Zr0.12Sn0.03)O3계 세라믹스의 미세구조 및 유전 특성)

  • Shin, Sang-Hoon;Yoo, Ju-Hyun;Shin, Dong-Chan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.12
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    • pp.797-802
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    • 2014
  • In this study, in order to develop the capacitor composition ceramics with the good dielectric properties, $(Ba_{1-x}Ca_x)(Ti_{0.85}Zr_{0.12}Sn_{0.03})O_3$ (abbreviated as BCTZ) ceramics were prepared by the conventional solid-state reaction method. The effects of Ca substitution on the microstructure and dielectric properties was investigated. The X-ray diffraction patterns demonstrated that all the specimens showed perovskite phase, and secondary phases are indicated in the measurement range of X-ray diffraction. Also, all the specimens indicated an rhombohedron phase structure. It was identified from the X-ray diffraction patterns that the secondary phase formed in grain boundaries and then decreased the dielectric properties. For all the specimens, observed one peak was tetragonal cubic phase transition temperature($T_c$), which is located in the vicinity of room temperature.

CAWR: Buffer Replacement with Channel-Aware Write Reordering Mechanism for SSDs

  • Wang, Ronghui;Chen, Zhiguang;Xiao, Nong;Zhang, Minxuan;Dong, Weihua
    • ETRI Journal
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    • v.37 no.1
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    • pp.147-156
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    • 2015
  • A typical solid-state drive contains several independent channels that can be operated in parallel. To exploit this channel-level parallelism, a variety of works proposed to split consecutive write sequences into small segments and schedule them to different channels. This scheme exploits the parallelism but breaks the spatial locality of write traffic; thus, it is able to significantly degrade the efficiency of garbage collection. This paper proposes a channel-aware write reordering (CAWR) mechanism to schedule write requests to different channels more intelligently. The novel mechanism encapsulates correlated pages into a cluster beforehand. All pages belonging to a cluster are scheduled to the same channels to exploit spatial locality, while different clusters are scheduled to different channels to exploit the parallelism. As CAWR covers both garbage collection and I/O performance, it outperforms existing schemes significantly. Trace-driven simulation results demonstrate that the CAWR mechanism reduces the average response time by 26% on average and decreases the valid page copies by 10% on average, while achieving a similar hit ratio to that of existing mechanisms.

Detecting of Scuffing Faliure using Acoustic Emission (AE센서를 이용한 스커핑 손상의 감시)

  • Kim, Jae-Hwan;Kim, Tae-Wan;Cho, Yong-Joo
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.05a
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    • pp.34-39
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    • 2002
  • The surfaces of machine components in sliding contact such as bearing, gears and pistons etc. frequently operate under the condition of mixed lubrication due to high load, high speed and slip. These machine components often undergo the inception of scuffing in practical application. The scuffing failure is a critical problem in modern machine components, especially for the requirement of high efficiency and small size. However, it is difficult to find a universal mechanism to explain all scuffing phenomena because there are so many factors affecting the onset of scuffing. In this study, scuffing experiments are conducted using Acoustic Emission(AE) measurement by an indirect sensing approach to detect scuffing failure. Acoustic Emission(AE) signal has been widely utilized to monitor the interaction at the friction interface. Using AE signals we can get an indication about the state of the friction processes, about the quality of solid and liquid layers eon the contacting surfaces in real time. The FFT(Fast Fourier Transform)analyses of the AE signal are used to understand the interfacial interaction and the relationship between the AE signal and the state of contact is presented

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Detecting of Scuffing Failure Using Acoustic Emission (AE 센서를 이용한 스커핑 손상의 감시)

  • Cho, Yong-Joo;Kim, Jae-Hwan;Kim, Tae-Wan;Cho, Yong-Joo
    • Tribology and Lubricants
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    • v.18 no.5
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    • pp.351-356
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    • 2002
  • The surfaces of machine components in sliding contact such as bearing, gears and pistons etc. frequently operate under the condition of mixed lubrication due to high load, high speed and slip. These machine components often undergo the inception of scuffing in practical application. The scuffing failure is a critical problem in modern machine components, especially for the requirement of high efficiency and small size. However, it is difficult to find a universal mechanism to explain all scuffing phenomena because there are so many factors affecting the onset of scuffing. In this study, scuffing experiments are conducted using Acoustic Emission(AE) measurement by an indirect sensing approach to detect scuffing failure. Acoustic Emission(AE) signal has been widely utilized to monitor the interaction at the friction interface. Using AE signals we can get an indication about the state of the friction processes, about the quality of solid and liquid layers on the contacting surfaces in real time. The FFT(Fast Fourier Transform) analyses of the AE signal are sued to understand the interfacial interaction and the relationship between the AE signal and the state of contact is presented.

Preparation of Sintering Aid for Li7La3Zr2O12 Solid Electrolyte by Heat-treatment of Polymeric Precursors Containing Li and B (Li과 B이 포함된 폴리머 전구체의 열처리에 의한 Li7La3Zr2O12 고체전해질의 소결조제 합성)

  • Shin, Ran-Hee;Ryu, Sung-Soo
    • Journal of Powder Materials
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    • v.25 no.2
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    • pp.151-157
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    • 2018
  • In this study, the compound $Li_3BO_3$ (LBO) is intended to be prepared by a polymeric complex method as a sintering aid for the densification of $Li_7La_3Zr_2O_{12}$ (LLZ) solid electrolyte. A polymeric precursor containing Li and B is heat-treated in an air atmosphere at a temperature range between $600^{\circ}C$ and $800^{\circ}C$. Instead of LBO, the compound $Li_{2+x}C_{1-x}B_xO_3$ (LCBO) is unexpectedly synthesized after a heat-treatment of $700^{\circ}C$. The effect of LCBO addition on sintering behavior and ion conductivity of LLZ is studied. It is found that the LCBO compound could lead to significant improvements in the densification and ionic conductivity of LLZ compared to pure LLZ. After sintering at $1100^{\circ}C$, the density of the LLZ-12wt%LBO composite is $3.72g/cm^3$, with a high Li-ion conductivity of $1.18{\times}10^{-4}Scm^{-1}$ at $28^{\circ}C$, while the pure LLZ specimen had a densify of $2.98g/cm^3$ and Li-ion conductivity of $5.98{\times}10^{-6}Scm^{-1}$.

The study on the thermal deformation of the rotating rollers in strip continuous casting process (박판 연속 주조과정에 있어서 회전 로울러의 열변형에 관한 연구)

  • 백남주;이상매
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.6
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    • pp.913-922
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    • 1987
  • In this paper the solidification phenomena at the molten pool has been modeled and simulated in terms with the one dimensional unsteady-state heat transfer of the solid and molten phase and the pressure distribution in the solid phase for the twin-roller continuous casting of Sn-15% Pb. The further purpose of this study was to effectively analyze the thermal and mechanical deformation of roll applying the results of the heat transfer and the pressure distribution to the boundary conditions. The strip thickness of rapidly solidified metallic strip decreases with increasing angular velocity of the roller and with increasing initial roll gap. For this reason the roll spacing and angular velocity of the rolls are considered to be main variables. The recommended optimal casting regimes for continuous strip dimensions is near 0.8mm-1.0mm in thickness at the given angular velocity .omega.=2.0 rad/sec. Results of the experiment using Sn-15% Pb are compared with model predictions. The calculated roll deformation has been in good agreement with the observed value of roll deformatiion. All the deformation. All the deformation of the roller is within the elastic range, the plastic yielding are not occured. However, these elastic stresses are sufficient to take place of the shortened roller life by the thermal fatigue and a notch fatigue. The higher cooling rates were obtained by a twin-roller quenching technique. Also the quenched microstructure of the rapidly solidified shell was verified.

Cavity Design Method for Injection-Molded Spur Gears

  • Kim, Choong-Hyun;Lee, Sung-Chul;Ahn, Hyo-Sok;Chong, Tae-Hyong
    • Journal of Mechanical Science and Technology
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    • v.14 no.1
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    • pp.65-71
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    • 2000
  • Mold cavities of gears should be made larger than the product specification since plastics shrink when changing from a molten to a solid state. For injection molded spur gears, two design methods for the compensation of shrinkage are widely used. One is the module correction method and the other is the pressure angle correction method. Both methods are based on the assumption that shrinkage occurs toward the center of a molded gear. This paper deals with the shrinkage rate and proposes a method of designing gear cavity derived from the measured shrinkage rates which govern the outside diameter, the tooth depth and the tooth thickness of a molded gear. The proposed method imposes no restriction on the shrinkage direction and provides a cavity with all of the fundamental gear design parameters.

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