• Title/Summary/Keyword: Alkaline resistant

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Hydrolysis of the Ester Crosslinking on Cotton Fabric Treated with Polycarboxylic Acid(I) (polycarboxylic acid 처리면포의 Ester 가교결합의 가수분해 (I))

  • 강인숙;배현숙
    • Textile Coloration and Finishing
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    • v.15 no.4
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    • pp.24-31
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    • 2003
  • In this research, we applied FT-IR spectroscopy to study the hydrolysis of the ester-crosslinking formed by various polycarboxylic acids on the cotton fabric. We observed the following; (1) the ester-crosslinking is less durable to hydrolysis than ether-crosslinking under all conditions; (2) the ester-crosslinking formed by polycarboxylic acids having more than three carboxyl groups, such as butanetetracarboxylic acid (BTCA), are substantially more durable to hydrolysis than the acids having two or three carboxyl groups, such as maleic and citric acid; (3) alkaline conditions drastically accelerate the hydrolysis of both urea- and ester-crosslinking; and (4) the ester-crosslinking formed by poly(maleic acid) is more resistant to hydrolysis at alkaline conditions than BTCA. (5) polycarboxylic acid molecules were removed from the fabric at same rate as the hydrolysis of the ester linkage. FT-IR spectroscopy has proved to be a useful analytical technique for evaluating the hydrolysis of the crosslinked cotton fabric.

Recent Advances in Catalyst Materials for PEM Water Electrolysis

  • Paula Marielle Ababao;Ilwhan Oh
    • Journal of the Korean Electrochemical Society
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    • v.26 no.2
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    • pp.19-34
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    • 2023
  • Due to the intermittency of renewable energy sources, a need to store and transport energy will increase. Hydrogen production through water electrolysis will provide an excellent way to supplement the intermittency of renewable energy sources. While alkaline water electrolysis is currently the most mature technology, it has drawbacks of low current density, large footprint, gas crossover, etc. The PEM water electrolysis has potential to replace the alkaline electrolysis. However, expensive catalyst material used in the PEM electrolysis has been the bottleneck of widespread use. In this review, we have reviewed recent efforts to reduce catalyst loading in PEM water electrolysis. In core-shell nanostructures, the precious metal catalyst forms a shell while heteroatoms form a core. In this way, the catalyst loading can be significantly reduced while maintaining the catalytic activity. In another approach, a corrosion-resistant support is utilized, which provides a stable platform to impregnate precious metal catalyst.

Epidemiological aspects of Salmonella spp infections of domestic animals in Gyeongbuk province (경북지역 가축에서 Salmonella속 균 감염증에 대한 역학적 특성)

  • Kim, Sang-Yun;Lee, Hee-Moo;Kim, Sin;Hong, Hyon-Pyo;Kwon, Heon-Il
    • Korean Journal of Veterinary Service
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    • v.24 no.1
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    • pp.51-68
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    • 2001
  • The result of studying the epidemiological characteristics of Salmonella strains which have been isolated from the domestic animals in Gyeongbuk province from February 1998 to August 2000 were summarized as follows. The isolation rates of Salmonella strains were 2.0% from cattle feces, 6.3% from cattle lymph node, 9.5% from pig feces, and 25.1% from pig lymph node. In poultry, the isolation rates were 30.3%. The isolates of Salmonella showed positive reaction for MUCAP test, methyl red test, but showed negative reaction for urea test, indole test, Voges Proskauer test. On TSI agar, the isolates showed acid butt, alkaline slant. Also, the isolates were identified as Salmonella strain by API 20E kit. Non H$_2$S Production Salmonella strains isolated from poultry were identified as S gallinarum. As a result of serotyping, B group were the most common in cattle and pig, Dl in chickens. 21 serovars were found. the common serovar from the domestic animals was S typhimurium, S derby, S agona, S schwarzenground, S enteritidis and S gallinarum. The most commonly encountered serovars in cattle were S agona and S typhirimurium in pig, S gallinarum in chicken. As a result of antimicrobial susceptibility test, all Salmonella isolates were susceptible to amikacin, ciprofloxacin, norfloxacin; cefotaxime and polumcin B. The resistance rates to tetracycline and streptomycin was 58% and 56%, respectively. 69.3% of all isolates were resistant to more than one antimicrobial agent. Out of the resistant isolates, the isolates resistant to streptomycin and tetracycline was 36%. There were 24 strains of multiresistant isolates resistant to more than 5 antimicrobial agents. S typhimurium were resistant to all antimicrobial agents, also had a lot of multiresistant strains. Therefore, S typhimurium was considered as a major agent of antimicrobial resistance.

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Phenotypic characteristics and antimicrobial susceptibilities of motile aeromonads isolated from freshwater fish in Korea and Japan (한국과 일본의 담수어에서 분리되는 운동성 aeromonads의 표현형적 특성과 약제감수성)

  • Han, Hyun-Ja;Govindasami, Vivekanandhan;Hirono, Ikuo;Aoki, Takahashi
    • Journal of fish pathology
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    • v.20 no.3
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    • pp.249-255
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    • 2007
  • We investigated the phenotypic characteristics by using API20E, APIZYM and determined minimum inhibitory concentrations (MICs) of 7 antibiotics in motile aeromonads isolated from freshwater fishes in Korea and Japan, and 4 American Type Culture Collection (ATCC) strains. All isolates (n=7) were identified as motile Aeromonas species according to API20E test. Lysine decarboxylase activity and acid production from 4 different carbohydrates including mannitol, rhamnose, amygdalin and arabinose were observed in various strains. In enzymatic activities by APIZYM, all isolates showed negative reactions in valine and cystine arylamidases, α-chymotrypsin, α-galactosidase, β-glucuronidase, α-glucosidase, α-mannosidase and α-fucosidase. Although the intensities of each enzymatic activity were diverse in alkaline phosphatase, esterase-lipase, leucine arylamidase, β-galactosidase and N-acetyl-β-glucosaminidase, all isolates showed positive reactions. All isolates were resistant to ampicillin sodium (MIC>100㎍/ml), but sensitive to chloramphenicol (MIC≤1.6㎍/ml). However, recently isolated strains (AC9804, AC0202 and GMA0361) were commonly resistant to tetracycline (MIC=50㎍/ml). Furthermore, AC9804 was resistant to oxolinic acid (MIC=12.5㎍/ml). GMA0361 was resistant to kanamycin sulfate (MIC>100㎍/ml) and streptomycin sulfate (MIC>100 ㎍/ml).

Effect of Milk Peptide on Bone Metabolism (우유단백질 유래 펩타이드가 골 대사에 미치는 영향)

  • Imm, Jee-Young
    • 한국유가공학회:학술대회논문집
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    • 2007.09a
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    • pp.39-47
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    • 2007
  • Bone undergoes continuous remodeling throughout the life and bone health is governed by the balance of bone resorbing osteoclast and bone forming osteoblast. Bone resorption is reflected in tartrate resistant acid phosphatase, pyridinium cross link and collagen telopeptide, whereas bone formation activity can be expressed as bone specific alkaline phosphatase, osteocalcin and procollagen I extension peptide. Milk basic protein and lactoferrin have been reported as active proteins to modulating bone metabolism. In addition to these proteins, some bioactive milk peptides released during lactic fermentation may provide beneficial effect on bone metabolism. The effects of fermented products of Lactobacillus casei ATCC 393 on bone metabolism were investigated using a variety of biochemical markers in osteoblastic MC3T3-E1 cells and ovariectomized rats. Based on the results, the fermented products of Lactobacillus casei ATCC 393 played an functional role in bone metabolism by suppressing bone resorption and by increasing bone formation.

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BIOCHEMICAL CHARACTERIZATION OF EMBRYONIC CHICK CALVARIAL CELLS

  • Yu, Jae-Hyung;Kim, Jung-Kun;Cha, Kyung-Suk
    • The korean journal of orthodontics
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    • v.25 no.6 s.53
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    • pp.697-704
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    • 1995
  • Chicken calvarial bone is known to contain various cell types, but their exact composition is unknown. By characterizing the chicken calvarial bone biochemically, it can be used to study biochemical, histochemical actions of bone cells in general. Calvaria of 18-day-old white leg horn embryo was aseptically dissected and bone cell populations were isolated by sequential enzymatic digestion. Histochemical study for osteoclast-like bone cell. population was performed with tartrate resistant acid phosphatase(TRAP) stain and for osteoblast-like bone cell population, alkaline phosphatase(ALP) stain was performed. Biochemical study for osteoblast-like bone cell population was performed using alkaline phosphatase(ALP) assay. Following conclusions were obtained from this study. 1. TRAP positive multi and mononuclear cells were mostly observed in group I and II, indicating that osteoclast-like bone cell population is mostly found in these groups. 2. All the cultured groups showed almost equal ALP activities and were positive for ALP stain, indicating that osteoblast-like bone cell population is evenly dispersed in all culture groups. 3. Experimental group treated with $1,25(OH)_{2}D_3$ showed increase in ALP activity in contrast to the control group, confirming previous studies that $1,25(OH)_{2}D_3$ increases ALP activities in in vitro bone cultures. 4. Results from von Kossa's stain indicated that in vitro bone formation had occured after 3 weeks of culture with beta-glycero phosphate.

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A Study on the Formaldehyde Release from Durable Press Finished Rayon Fabrics (DP 가공된 레이온 직물의 포름알데하이드 방출에 관한 연구)

  • Yeo Sook-Young;Kim Eun-Ae
    • Journal of the Korean Society of Clothing and Textiles
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    • v.13 no.1 s.29
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    • pp.59-66
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    • 1989
  • This paper is concerned with formaldehyde release from durable press finished rayon fabrics. $100\%$ rayon fabrics were treated with 3 kinds of commercial N-methylol crosslinking agents using a pad-dry cure technique. Aqueous extractions of fabric samples were carried out at $40^{\circ}C$ under pH's of 4, 7, 10. Formaldehyde release was evaluated for the types of resins, catalyst concentrations and extraction conditions. Results indicated that the higher concentration of catalyst leads to the more fixation of resin on the fabric. Total formaldehyde released to the extract was decreased as the catalyst concentration increased. For the resin types, the amount of formaldehyde released was in the order of DMU>MDMDHEU>DMDHEU. Free formaldehyde content in the extract was in the order of pH10>pH4>pH7. This result proved that resins are least resistant to alkaline hydrolysis and the N-C bond cleavage under alkaline condition. Under acidic condition, however, N-methylol formaldehyde was accumulated before the release of free formaldehyde. This suggested the C·0 bond cleavalge to form carbonium - immonim intermediate.

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Service Life Estimation of ACQ-treated Wood Based on Biodeterioration Resistance

  • Pang, Sung-Jun;Hong, Jung-Pyo;Lee, Jun-Jae;Oh, Jung-Kwon
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.5
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    • pp.641-651
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    • 2015
  • The aim of this study was to estimate the service life of alkaline copper quaternary (ACQ)-treated wood. The service life of preservative-treated wood was estimated by comparing a residual quantity of ACQ in wood with toxic threshold to fungi. Indoor and outdoor leaching tests were carried out in order to predict residual ACQ quantity within wood. As a result, the leaching ratio of ACQ from treated wood above ground via precipitation was 18.1% for 50 years. When the H4 treated wood, which is traditionally used in contact with the ground and fresh water, is used above-ground, the leaching ratio of ACQ for 50 years is 18.1% and the residual quantity of ACQ is $4.2kg/m^3$, which is higher than the toxic threshold of ACQ. Thus, the H4 treated wood used above-ground will be resistant to biodeterioration for at least 50 years.

An option to provide water and fertilization for rice production in alkaline soil: fertigation with slow release fertilizers (SRFs)

  • Young-Tae Shin;Kangho Jung;Chung-Keun Lee;Jwakyung Sung
    • Korean Journal of Agricultural Science
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    • v.49 no.4
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    • pp.923-931
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    • 2022
  • An increasing global population requires a greater food supply, and accordingly there is demand for enhanced production of rice, as a major crop plant that covers half of the world's population. Rice production in arid area is extremely difficult due to poor soil fertility, salinity, deficit of irrigation water, and weather conditions. The aim of the present study was to determine whether various fertilization recipes could provide a countermeasure to allow rice production while also providing soil amendment such as soil pH adjustment. The study was conducted at an experimental field of the United Arab-Emirates (UAE) from January to April, 2022. Rice seedlings (cv. Asemi, alkaline-resistant) were transplanted in plastic containers, and different types of water and nutrient managements were employed as follows: water management (flooding and aerobic for NPKs treatment group) and nutrient management (NPKs, slow release fertilizers [SRFs] and SRFs + NPK-1 treatment groups with flooding). Water and nutrient management did not show any effect on soil pH adjustment. Rice growth was significantly enhanced in the flooding compared to the aerobic condition, whereas the effect of nutrient management clearly differed among the treatment groups, with SRFs + NPK-1 showing the best results followed by SRFs and NPKs. Most of the fertilization groups markedly accumulated soluble sugars in the shoots and grains of rice plants, but concomitantly a decrease in the roots. Overall, the level of starch showed a tendency of relatively slight perturbation by fertilization. Taken together, the results indicate that soil physical structure should be preferentially amended to find the key for suitable rice production.

Purification and Characterization of Alkali-resistant Amylases from Pseudomonas sp. (Pseudomonas sp.로부터 알칼리내성 amylase의 정제 및 특성 확인)

  • Lee, Jeong-Eun;Jhon, Deok-Young
    • Korean Journal of Food Science and Technology
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    • v.40 no.1
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    • pp.70-75
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    • 2008
  • Two extracellular amylase isozymes were purified and characterized from alkalophilic Pseudomonas sp. KFCC 10818 for the production of maltooligosaccharides. The molecular weights of the homogeneous proteins were 50 kDa and 75 kDa, respectively. The 50 and 75 kDa amylases showed optimum temperatures at 35 and $40^{\circ}C$, respectively. The optimum pH of the enzymes ranged from pH 6-8, and the enzymes were resistant to an alkaline condition of pH 12. Via the enzyme's actions, the final products from maltooligosaccharides or soluble starch were maltose and maltotriose. Calcium was a potent activator of the 50 kDa amylase. Finally, the N-terminal amino acid sequences of the 50 and 75 kDa amylases were QTVPKTTFV and DTVPGNAFQ, respectively.