• Title/Summary/Keyword: Alkali sulfate

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The Antimutagenic Activity of Sulfated Alginate and Its Effect on the Growth of Lactobacillus acidophillus (황 흡착 알긴산의 Lactobacillus acidophillus 성장에 미치는 영향 및 항 돌연변이 작용)

  • 강경금;박난희;김정목
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.4
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    • pp.757-761
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    • 2004
  • The alginate extracted from Hizikia fusiform by the acid alkali soluble alginate (AASA) extraction method was reacted with Na$_2$SO$_4$. The amount of sulfate absorbed in the 3% alginate solution was determined about 18,435 ppm by inductively coupled plasma-atomic emission spectrometry. Both alginate and S-alginate stimulated the growth of Lactobacillus acidophilus in MRS broth and peptone water medium. The addition of S-alginate to the media showed the higher bacterial numbers than alginate supplement. There was no mutagenic activity of S-alginate in the Ames test using the Salmonella Typhimurium TA98 and TA100 strains. The S-alginate showed suppressive effect against 2-NF and MMS of mutagens.

Remediation of Oil Contaminated Soils by Rice Straw Ash (Rice Straw Ash를 이용한 유류오염토양 정화)

  • 정경원;장성호
    • Journal of Environmental Science International
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    • v.12 no.7
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    • pp.783-789
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    • 2003
  • This study was conducted to reuse the rice straw ash as washing agent for oil contaminated soils. The results are summarized as follows. The physical characteristics of rice straw before and after burning were as follows ; In case of burning rice straw 1g, the rice straw ash was generated 0.14g and pH was changed neutrality into alkali(pH 10.9) and specific surface area was increased to five times and particle distribution was corresponded to fine silt.(under 0.05mm) The physical characteristics of rice straw ash were Carbon 10.9%, Hydrogen 1.5%, Oxygen 23.4%, Nitrogen 5.2%, Sulfate 1.2% and chemical characteristics were Si 189.2ppm, Ca 10.2ppm, Mg 4.7ppm. Oil cleanup ratio by pH variation were about 40∼50% of initial concentration of oil by pH 10∼11. As the result of cleanup comparative experiment, the rice straw ash was about 20∼30%, the tritonX-100 about 40∼50% of washing efficiency, and then in the future it will be possibility of substitute washing agent.

Hydration Reaction of Non-Sintering Cement using Waste Gypsum and Waste Lime with Activators (폐석고 및 폐석회를 자극제로 이용한 비소성 시멘트의 수화반응)

  • Mun, Kyoung-Ju;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.232-235
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    • 2004
  • This study aims to manufacture non-sintering cement(NSC) by adding phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators. This study also investigates the basic physical properties and hydration reaction of NSC, and evaluates its reusing possibility as construction material. Results obtained from this study have shown that GBFS was affected by $So_4^{2-}$ in waste PG and stimuli under wet condition, left slag components, created Ettringite and CSH gels, and eventually started being hydrated. These hydrated creations formed dense structures like CSH based on Ettringite and contributed in allowing the mortar to reveal high strength.

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Chemical resistance of Non-Sintered Cement Mortar using Inorganic Industrial Wastes as activator (무기계 산업폐기물을 자극제로 이용한 비소성 시멘트 모르타르의 내화학성)

  • Mun Kyoung Ju;Lee Chol Woong;Park Won Chun;Soh Yang Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.607-610
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    • 2005
  • If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages, including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by $CO_2$ discharge, and reduction of the production cost. This research investigates the chemical resistance of NSC mortar added PG and WL to GBFS as sulfate and alkali activators. The result of experiment of chemical resistance, showed that NSC is very excellent in acid resistance and seawater resistanc. Such a reasons are that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

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Chloride ion Permeability of Non-Sintered Cement Concrete using Inorganic Industrial Wastes as activator (무기계 산업폐기물을 자극제로 이용한 비소성 시멘트 콘크리트의 염소이온 침투 저항성)

  • Mun, Kyoung-Ju;Lee, Chol-Woong;Park, Won-Chun;So, Seung-Young;Soh, Yang-Seob
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.453-456
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    • 2006
  • If cement can be manufactured with industrial byproducts such as granulated blast furnace slag(GBFS), phosphogypsum(PG), and waste lime(WL) instead of clinker as its counterproposal, there would be many advantages, including maximum use of these industrial byproducts for high value-added resources, conservation of natural resources and energy by omitting the use of clinker, minimized environmental pollution problems caused by CO2 discharge, and reduction of the production cost. This research investigates the chloride ion permeability of NSC concrete added PG and WL to GBFS as sulfate and alkali activators. The result of experiment of chloride ion permeability, showed that NSC is very excellent in seawater resistance. Such a reasons are that the hydrate like CSH gel and ettringite formed dense pore structure of NSC matrix.

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Effects of Calcium Aluminate Compounds on Hydration of BFS

  • Song, Hyeon-jin;Kang, Seung-Min;Jeon, Se-Hoon;Kim, Jung-Won;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.52 no.6
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    • pp.483-488
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    • 2015
  • Blast furnace slag(BFS) is well known for its hardening mechanism in ordinary Portland cement with alkali activation due to its latent hydraulic property. The possibility of using calcium compound as activator for BFS has been investigated in this study. The hydration properties of calcium compound activated BFS binders were explored using heat of hydration, powder X-ray diffraction and compressive strength testing. Heat of hydration results indicate that the hydration heat of BFS is lower than OPC paste by about 50%. And ettringite as hydration product was formed continuously as the calcium sulfate was decreased. The maximum compressive strength of hardened BFS mortar at 28 days is confirmed to be 83% as compared with hardened OPC mortar.

A Comparison Study on Quality Regulation of China and Korea Cement (중국과 한국 시멘트의 품질규정에 대한 비교 연구)

  • Pei, Chang-Chun;Jin, Hu-Lin;Li, Bai-Shou;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.05a
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    • pp.159-162
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    • 2006
  • This study generally compared and investigated cement type and quality of China and Korea. Cement in Korea is divided into five such as ordinary, high early strength, moderate heat, low heat and sulfate resistance portland cement. However cement in China is divided into portland cement($P{\cdot}I,\;P{\cdot}II$) and ordinary portland cement($P{\cdot}O$) with admixture displacement ratio and it is again divided into 6 level and 7 level with 28 days compressive strength. In addition China classified cement into several standards, such as Mgo, SO3,, igloss, blame, setting time, stability, strength, alkali and sampling test. Therefore it should be careful to conclude so quickly without right understanding whether quality of China cement is bad or good. The better way to evaluate China cement is synthetically understanding a value engineering and consumer awareness.

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Studies on the Combustion of Anthracite (II). The Combustion of Sulfide in Anthracite (無燃炭 燃燒에 關한 硏究 (第 2 報). 無煙炭中의 黃化物의 燃燒)

  • Shin Byoung Sik;Shin Sei Kun
    • Journal of the Korean Chemical Society
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    • v.19 no.3
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    • pp.193-197
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    • 1975
  • In the combustion process, it is found that the addition of small amount of hydroxide of alkali and alkaline earth metal to the anthracite is more effective in order to suppress the evolution of $SO_2 gas, since the large portion of sulfur contained in anthracite is remained in the ash with a form of sulfide and sulfate. Under this experimental condition, however, it was observed that the SO_2$ gas corresponding to about 20 % of sulfur content in anthracite was released at $1000^{\circ}C$.

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A Study on the Improvement of an Early-age Quality of Blast-Furnace Slag Concrete (고로슬래그 콘크리트의 초기 품질 하락 극복을 위한 연구)

  • 반성수;최봉주;유득현;전영환;조현태
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.1215-1220
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    • 2000
  • Blast-Furnace Slag, a by-product of the iron or steel industry, has potential sa a cementitious material. The addition of a Blast-Furnace Slag generally reduces the heat of hydration and can confer significant improvements in resistance to sulfate attack and alkali-aggregate reaction, as well as increases in ultimate strength. But it also reduces early-age strength. In this study, for the purpose of improvement of early-age quality of Blast-Furnace Slag concrete, we choose blaine fineness of $6, 000~8, 000cm^2/g$ of Blast-Furnace Slag, and investigate the various properties of concrete. As a result, workability and early-age strength of Blast-Furnace Slag concrete were improved according to the increase of blaine fineness of Blast-Furnace Slag.

Study on Mock-up test for field application of High Strength Concrete using Non-Sintered Cement (비소성시멘트를 사용한 고강도 콘크리트의 현장적용을 위한 모의부재에 관한 연구)

  • Kim, Han-Sik;Han, Da-Hee;Kim, Kwang-Ki;Paik, Min-Su;Mun, Kyoung-Ju;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.33-36
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    • 2006
  • This Study is based on manufacture non-sintering cement(NSC) by adding phosphogysum and waste lime to GBFS as sulfate and alkali activators. This study also investigates the basic physical properties and duality of NSC, and evaluates its reusing possibility as construction materials. Therefore, we design 40MPa and 60MPa for compressive strength using OPC and NSC by binder. And There is a purpose to present fundamental data, applying in field and analyzing quality control of concrete using NSC according to rate of replace between OPC and NSC.

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