• Proceedings of the Korean Magnestics Society Conference
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• 2003.12a
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• pp.194-194
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• 2003

• Proceedings of the Korean Vacuum Society Conference
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• 2004.08a
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• pp.205-205
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• 2004

• Proceedings of the Korean Vacuum Society Conference
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• 2005.08a
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• pp.193-193
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• 2005

• Korean Journal of Crystallography
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• v.6 no.1
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• pp.1-13
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• 1995

Cr:A12O3 and Ti:A12O3 single crystals were grown by Czochralski method, and the effects of crystal growth parameters such as pulling rate, rotation rate, dopant and growth atmosphere on crystal quality were investigated. And spectroscopic properties including lasing efficiency were also measured. Single crystals, sized of 20mm in diameter and 100-135mm in length, were successfully grown from the seed of <001> direction. With the doping level of 0.5w/o Cr2O3, pulling rate 2.0mm/hr, rotation rate of 30rpm and inert atmosphere by nitrogen gas, high quality crystals of Cr:A12O3 were grown. While in case of Ti:A12O3 crystals, high quality crystals were grown under the conditions of the doping level of 0.25w/o TiO2, pulling rate of 1.5mm/hr, rotation rate of 30rpm and reducing atmosphere by hydrogen - nitrogen mixed gas. It was confirmed that Cr3+ ion which maintains its ionoc valence during growth easily de-bubbled than Ti4+ ion which changes its valence, Fe3+ ion also has do-bubbling effect to Ti:A12O3 crystal and the reducing atmosphere by 90% N2 - 10% H2 mixed gas gave effective result on the changing of Ti4+ to Ti3+ and de-bubbling. As a result of spectroscopic measurements of Cr:A12O3 crystal, 4A2 →4F2 and 4F1 absorption transitions and E →4A2(R1) and 2A →4A2(R2) fluorenscence transitions were confirmed. And it was measured that wavelengths of laser R1 and R2 transitions were 696±5nm and 692±5nm respectively, line width of these transitions were 12A, and life-time of fluorenscence was 152μsec. In case of Ti:A12O3 crystals, it was confirmed that absortion transition of 4T2→4E and fluorescence transition of 4E→4T2 with wide range of 650-1050nm was occured. And 147μsec of life-time of fluorescence, 125.4 of figure of merit and 9% of laser efficience were also measured.

• Analytical Science and Technology
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• v.12 no.2
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• pp.141-150
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• 1999

Twenty organic chemical substances, tetrachloroethylene, toluene, ethylbenzene, p-xylene, m-xylene, isopropyl benzene, stylene, bromobenzene, 1,3,5-trimethylbenzene, 2-chlorotoluene 1,2,4-trimethylbenzene, p-isopropyltoluene, 4-chlorotoluene, n-butylbenzene, 1,2,4-trichlorobenzene, naphthalene, tert-butylbenzene, sec-butylbenzene, phenol, isopropyl benzene hydroperoxide were isolated from untreated and treated wastewater collected at 76 companys of 9 types industry in the basin of Young San River. Their organic compounds were elucidated by Gas Chromatography/Mass Spectrometry (GC/MS) and by comparison with each standard reagents. Especially, phenol compound is detected from effluent water but not detected from plant wastewater in the chemical industry. Heavy metal, which are Cr, Mn, Cu, Zn, Cd, Pb, As, Al and Fe, are contained in the plant wastewater of all industry, Fe, Al of them is more detected than the other metals in plant wastewater. Cr, Cd, Pb, As is contained much in plant wastewater of electricity and electron, metal molding industry. Nine metals is nearely treated when plant wastewater is treated, and then the concentration of each other metals is detected below water quality standard or not detected by using AA.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1995.05a
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• pp.85-92
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• 1995

HTPB/AP/Al이 기본 조성인 ADP 302 혼합형 추진제를 대상으로 4종의 금속선(Ag, Cu, Al, Ni-Cr)을 삽입하여 금속선 직경(0.1mm~0.8mm)별로 압력에 따른 금속선과 인접한 추진제의 연소 속도($r_w)를 측정하여 금속선 삽입 추진제의 연소 속도 증가비($r_w$/$r_sb$)와 압력 지수( n )의 변화를 고찰한 결과 금속선 종류에 따른 연소 속도 증가비($r_w$/$r_sb$)는 Ag> Cu>Al>Ni-Cr선을 삽입한 추진제의 순으로 나타났고 금속선의 열확 산 계수의 크기순과 일치하였다. Buckingham $\pi$ 이론을 적용한 무차원 해석으로부터 실험식을 구하여, 이 실험식에 의해 계산된 ($r_w)와 실험으로부터 얻어진 ($r_w)를 서로 비교하여 본 결과 잘 부합됨을 알 수 있었다. 또한 금속선 수에 따른 추진제 그레인의 연소 면적을 해석적으로 계산하여,($r_w$/$r_sb$)가 2, 3, 4, 5 배로 증가함에 따른 시간에 따른 연소 면적 증가비의 변화를 금속선 수에 따라서 비교하여 본 결과 정상 상태에서의 그레인의 연소 면적의 증가비($A_b$/$A_0$)는 금속선에 인접한 추진제의 연소 속도 증가비($r_w$/$r_sb$)와 일치했으며, 정상 상태의 연소 면적 증가비는 삽입된 금속선의 수와는 무관하며 정상 상태에 도달하는 시간에만 영향을 주는 것으로 나타났다.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2001.11a
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• pp.69-69
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• 2001

We report a study of the nitriding of the martensitic grade of stainless steel AKSK 420 in a low-pressure rl discharge using pure nitrogen. Much studied samples of the austenitic grade AISI 304 were treated at the same time to provide a comparison. With a treatment time of 4.0 h at $400^{\circ}C$, the nitrogen-rich layer on MSK 420 is 20pm thick and has a hardness about 4.3 times higher than that of the untreated material. The layer thickness is much greater than that obtained on AISI 304 under identical treatment conditions, reflecting the different Cr content of the two alloys. The alloy AlISI 420 is more susceptible than AISI 304 to the formation of CrN and ferrite, and this has a deleterious effect on the hardnes, gain. Below the temperature at which CrN forms, the treated layer retains its martensitic structure, but with a larger lattice parameter than the bulk, a phase that we term expanded martensite, by analogy with the situation with austenitic stainless steel. The fact that the treated layer retains a martensitic structure is interesting in view of previous evidence that nitrogen is an austenite stabilizer.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.10 no.2
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• pp.117-123
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• 2011

The purpose of this study is to show the friction and wear characteristics on the vapor deposited coating layers on the SCM415 steel. In this research, frictional wear characteristic of coating materials such as Ti-series, Cr-series & WC/C and TiAlN+WC/C multilayer coating was investigated under room temperature, normal air pressure and no lubricating condition. Therefore, this study carried out research on the friction coefficient, micro hardness(Hv), surface roughness and wear quantity on the vapor deposited coating layers on the SCM415 steel. As the wear experimental result, the excellence of TiAlN+WC/C multilayer coating has been proven by high micro-hardness, low friction coefficient and wear quantity.

• Korean Journal of Metals and Materials
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• v.47 no.2
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• pp.129-137
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• 2009

Corrosion behaviors of TiN coated dental casting alloys have been researched by using various electrochemical methods. Three casting alloys (Alloy 1: 63Co-27Cr-5.5Mo, Alloy 2: 63Ni-16Cr-5Mo, Alloy 3: 63Co-30Cr-5Mo) were prepared for fabricating partial denture frameworks with various casting methods; centrifugal casting(CF), high frequency induction casting(HFI) and vacuum pressure casting(VP). The specimens were coated with TiN film by RF-magnetron sputtering method. The corrosion behaviors were investigated using potentiostat (EG&G Co, 263A. USA) in 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. The corrosion morphologies were analyzed using FE-SEM and EDX. Alloy 1 and Alloy 2 showed the ${\alpha}-Co$ and ${\varepsilon}-Co$ phase on the matrix, and it was disappeared in case of TiN coated Alloy 1 and 2. In the Alloy 3, $Ni_2Cr$ second phases were appeared at matrix. Corrosion potentials of TiN coated alloy were higher than that of non-coated alloy, but current density at passive region of TiN coated alloy was lower than that of non-coated alloy. Pitting corrosion resistances were increased in the order of centrifugal casting, high frequency induction casting and vacuum pressure casting method from cyclic potentiodynamic polarization test.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.20 no.4
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• pp.159-168
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• 2015

Forty-four surface sediments from Doam Bay were analyzed for total organic carbon (TOC), total nitrogen (TN), total metal (Al, Fe, Mn, Cr, Cu, Ni, Pb, Zn) and further chemical partitioning of metals were carried out in some samples. The TOC (0.32~3.10%) and TN (0.03~0.26%) values of the samples were similar to those of other coastal area. The C/N ratios ranged from 7.9 to 11.9 with an average 9.3 which revealed that contribution of terrestrial organic matters was relatively rare. Contents of analysed metals showed a level lower than threshold effects level (TEL) in sediment quality guidelines. Based on the chemical speciation of metals, the lattice fractions were found in the order Cr > Cu > Ni > Zn > Pb > Mn, while Mn and Pb are the ratio of the non-lattice fractions accounted for more than 50%. The average baseline values were obtained relative cumulative frequency curves and linear regression analysis. The respective baseline concentrations for Cu, Ni, Pb, Zn, Cr and Mn were 11.8, 23.1, 26.8, 76.6, 56.7, 585 mg/kg, respectively. Based on geoaccumulation index ($I_{geo}$) with a baseline values of Mn showed that face the contamination phase from estuarine stations. However, in case of Zn and Pb, although there is no sign of contamination, it could be release from sediment when there is a change in the environment, which is caused from the high ratio of non-lattice fractions.