• Title/Summary/Keyword: Al-bound

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A Study of Growth and Properties of GaN films on Si(111) by MOCVD (Si(111) 기판을 이용한 crack-free GaN 박막 성장과 PL특성)

  • Kim, Deok-Kyu;Jin, Hu-Jie;Song, Min-Jong;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.187-188
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    • 2005
  • The characteristics of GaN epitaxial layers grown on silicon (111) substrates by metalorganic vapor phase epitaxy have been investigated. The only control of AlN thickness was found to decrease the stress sufficiently for avoiding crack formation in an overgrown thick ($2.6{\mu}m$) GaN layer. X-ray diffraction and photoluminescence measurements are used to determine the effect of AlN thickness on the strain in the subsequent GaN layers. Strong band edge photoluminescence of GaN on Si(111) was observed with a full width at half maximum of the bound exciton line as low as 17meV at 13K.

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Thermal and Dynamical Evolution of a Gaseous Medium and Star Formation in Disk Galaxies

  • Kim, Chang-Goo;Kim, Woong-Tae;Ostriker, Eve C.
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.54.1-54.1
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    • 2011
  • Formation of self-gravitating gas clouds and hence stars in galaxies is a consequence of both thermal and dynamical evolution of a gaseous medium. Using hydrodynamics simulations including cooling and heating explicitly, we follow simultaneously thermal and dynamical evolution of galactic gas disks to study dynamics and structures of galactic spiral shocks with thermal instability and regulation of the star formation rates (SFRs). We first perform one-dimensional simulations in direction perpendicular to spiral arms. The multiphase gas flows across the arm soon achieve a quasi-steady state characterized by transitions from warm to cold phases at the shock and from cold to warm phases in the postshock expansion zone, producing a substantial fraction of intermediate-temperature gas. Next, we allow a vertical degree of freedom to model vertically stratified disks. The shock front experiences unsteady flapping motions, driving a significant amount of random gas motions, and self-gravity promotes formation of bound clouds inside spiral arms. Finally, we include the star formation feedback in both mechanical (due to supernova explosion) and radiative (due to FUV heating by young stars) forms in the absence of spiral arms. At saturation, gravitationally bound clouds form via thermal and gravitational instabilities, which are compensated by disruption via supernova explosions. We find that the FUV heating regulates the SFRs when gas surface density is low, confirming the prediction of the thermal and dynamical equilibrium model of Ostriker et al. (2010) for star formation regulation.

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Effect of Multiple Copies of Cohesins on Cellulase and Hemicellulase Activities of Clostridium cellulovorans Mini-cellulosomes

  • Cha, Jae-Ho;Matsuoka, Satoshi;Chan, Helen;Yukawa, Hideaki;Inui, Masayuki;Doi, Roy H.
    • Journal of Microbiology and Biotechnology
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    • v.17 no.11
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    • pp.1782-1788
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    • 2007
  • Cellulosomes in Clostridium cellulovorans are assembled by the interaction between the repeated cohesin domains of a scaffolding protein (CbpA) and the dockerin domain of enzyme components. In this study, we determined the synergistic effects on cellulosic and hemicellulosic substrates by three different recombinant mini-cellulosomes containing either endoglucanase EngB or endoxylanase XynA bound to mini-CbpA with one cohesin domain (mini-CbpAl), two cohesins (mini-CbpA12), or four cohesins (mini-CbpAl234). The assembly of EngB or XynA with mini-CbpA increased the activity against carboxymethyl cellulose, acid-swollen cellulose, Avicel, xylan, and com fiber 1.1-1.8-fold compared with that for the corresponding enzyme alone. A most distinct improvement was shown with com fiber, a natural substrate containing xylan, arabinan, and cellulose. However, there was little difference in activity between the three different mini-cellulosomes when the cellulosomal enzyme concentration was held constant regardless of the copy number of cohesins in the cellulosome. A synergistic effect was observed when the enzyme concentration was increased to be proportional to the number of cohesins in the mini-cellulosome. The highest degree of synergy was observed with mini-CbpAl234 (1.8-fold) and then mini-CbpAl2 (1.3-fold), and the lowest synergy was observed with mini-CbpAl (1.2-fold) when Avicel was used as the substrate. As the copy number of cohesin was increased, there was more synergy. These results indicate that the clustering effect (physical enzyme proximity) of the enzyme within the mini-cellulosome is one of the important factors for efficient degradation of plant cell walls.

Shear Friction Strength Model of Concrete considering Transverse Reinforcement and Axial Stresses (축응력 및 횡보강근을 고려한 콘크리트의 전단마찰내력 평가모델)

  • Hwnag, Yong-Ha;Yang, Keun-Hyeok
    • Journal of the Korea Concrete Institute
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    • v.28 no.2
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    • pp.167-176
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    • 2016
  • Shear friction strength model of concrete was proposed to explain the direct friction mechanism at the concrete interfaces intersecting two structural elements. The model was derived from a mechanism analysis based on the upper-bound theorem of concrete plasticity considering the effect of transverse reinforcement and applied axial loads on the shear strength at concrete interfaces. Concrete was modelled as a rigid-perfectly plastic material obeying modified Coulomb failure criteria. To allow the influence of concrete type and maximum aggregate size on the effectiveness strength of concrete, the stress-strain models proposed by Yang et al. and Hordijk were employed in compression and tension, respectively. From the conversion of these stress-strain models into rigidly perfect materials, the effectiveness factor for compression, ratio of effective tensile strength to compressive strength and angle of concrete friction were then mathematically generalized. The proposed shear friction strength model was compared with 91 push-off specimens compiled from the available literature. Unlike the existing equations or code equations, the proposed model possessed an application of diversity against various parameters. As a result, the mean and standard deviation of the ratios between experiments and predictions using the present model are 0.95 and 0.15, respectively, indicating a better accuracy and less variation than the other equations, regardless of concrete type, the amount of transverse reinforcement, and the magnitude of applied axial stresses.

Preparation of A and Y type zeolite film by hydrothermal crystallization (수열결정화법에 의한 A 및 Y형 제올라이트 박막의 제조)

  • 김건중;박노춘;안화승;남세종
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.55-63
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    • 1998
  • A and Y type zeolitic crystal films were synthesized on porous supports from the reaction mixture of 1.9 $SiO_2-1.5\;Na_2O-Al_2O_3-40\;H_2O$ and 10 $SiO_2-7\;Na_2O-Al_2O_3-280\;H_2O$ composition, respectively. The zeolite film was characterized by XRD and SEM. The crystals grown on the porous matrix were very closely bound together and the thickness of membrane was about 8-15$\mu \textrm{m}$. The densely intergrown crystals could be also synthesized by the hydrothermal treatment at $100^{\circ}C$ after pressing the reaction mixture without addition of water. A zeolite membrane crystallized as a thin film showed the selective permeability of water from water and methanol mixture through the molecular sieving activity of micropores.

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Chemical Speciations of Elements in the Fe-Mn Crusts by Sequential Extraction (단계별 추출법을 이용한 망간각 구성 원소의 존재 형태)

  • Kim, Jong-Uk;Moon, Jai-Woon;Chi, Sang-Bum;Ko, Young-Tak;Lee, Hyun-Bok
    • Ocean and Polar Research
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    • v.26 no.2
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    • pp.231-243
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    • 2004
  • Sequential extraction was carried out on twenty two subsamples of three ferromanganese crusts from three seamounts (Lemkein, Lomilik, and Litakpooki) near the Marshall Islands in the western Pacific. The extraction was designed to fractionate Fe-Mn crust forming elements into low defined groups: (1) exchangeable and carbornate, (2) Mn-oxide, (3) Fe-oxyhyd.oxide, and (4) residual fraction. X-ray diffraction result shows that target material were well removed by each extraction step except for CFA in phosphatized crusts generation. According to chemical analysis of each leachate, most of elements in the Fe-Mn crusts are bound with two major phases. Mn, Ba, Co, Ni, Zn, (Fe, Sr, Cu, and V) are strongly bounded with Mn-oxide $({\delta}-MnO_2)$ phase, whereas Fe, Ti, Zr, Mo, Pb, Al, Cu,(V, P, and Zn) show chemical affinity with Fe-oxyhydroxide phase. This result indicates that significant amount of Al, Ti, and Zr can not be explained by detrital origin. Ca, Mg, K, and Sr mainly occur as exchangeable elements and/or carbonate phase. Outermost layer 1 and inner layer 2 which are both young crusts generations are similar in chemical speciations of elements. However, some of Fe-oxyhydroxide bounded elements (Pb, Y, Mo, Ba, Al, and V) in phosphatized innermost layer 3 are released during phosphatization and incorporated into phosphate (Pb, Y, Mo, and Ba) or Mn-oxide phase (Al and V). Our sequential extraction results reveal that chemical speciations of elements in the hydrogenetic crusts are more or less different from interelemental relationship calculated by statistical method based on bulk chemistry.

Two-Dimensional Analysis of the Characteristics at Heterojunction of MODFET Using FDM (유한 차분법을 이용한 MODFET의 이차원적 해석)

  • Jung, Hak-Gi;Lee, Moon-Key;Kim, Bong-Ryul
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.25 no.11
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    • pp.1373-1379
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    • 1988
  • This paper describes a two-dimensional analysis of the potential distribution and electron concentration of the MODFET at channel using FDM. More exact analysis can be obtained by two-dimensional analysis which considers parasitic effects ignored in one-dimensional analysis. Using Poisson and Shrodinger equations, the potential distribution and the wave function are calculated within a constant error bound. As a result, the relations between the thickness of spacer, doping concentration of (n) AlGaAs layer, and the sheet density of the 2DEG (2 Dimensional Electron Gas) of MODFET at channel are suggested quantitively. The sheet density of the 2DEG is increased as the thickness of the spacer is decreased of the doping concentration of the (n)AlGaAs layer is lowered.

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Newly discovered galaxy overdensities and large scale structures at z~1

  • Hyun, Minhee;Im, Myungshin;Kim, Jae-Woo;Lee, Seong-Kook
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.1
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    • pp.39.2-39.2
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    • 2019
  • Galaxy clusters are the largest gravitationally bound structures in the universe and located in the densest peak of the dark matter. They can constraint cosmologicals model from their dark matter halo distribution and they are good laboratories to study how galaxy evolution varies with their environment. Especially, studies of galaxy clusters at $z{\geq}1$ are important because (i) galaxy evolution at z >1 is still controversial (Elbaz et al. 2007; Faloon et al. 2013) and (ii) some studies show that mass of galaxy clusters at z>1 seems to be higher than expected value from the concordance LCDM cosmological model (Kang & Im 2009; Gonzales et al. 2012). In spite of their significance, there have not been many studies of galaxy clusters at $z{\geq}1$ because of the lack of wide and deep multi-wavelength data. We newly found galaxy cluster candidates at 0.2 < z < 1.4 and a LSS spanning over 100Mpc at z~0.9 in the ELAIS-N1 field which is one of the IMS (Infrared Medium-deep Survey; Im et al. 2019, in preparation) fields. Thanks to K-GMT science program, we performed spectroscopic follow-up observation for a z~1 galaxy cluster candidates with GMOS of Gemini North and for z~0.9 supercluster candidates with Hectospec of MMT in 2018A and confirmed the large scale structures. We present the newly discovered galaxy overdensities from the observation and the analysis result.

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Increased Available Phosphate by Shell Meal Fertilizer Application in Upland Soil (밭 토양에서 패화석비료 시용에 따른 유효인산의 증대)

  • Lee, Chang-Hoon;Lee, Ju-Young;Ha, Byung-Hyun;Kim, Pil-Joo
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.1
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    • pp.52-57
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    • 2005
  • Previous studies showed that shell meal fertilizer from the oyster farming industry could be a potential inorganic soil amendment to increase Chinese cabbage productivity and to restore the soil nutrient balance in upland soil (Lee et al., 2004). Herein, shell meal fertilizer was applied at rates of 0, 4, 8, 12, and $16Mg\;ha^{-1}$ to upland soil (Pyeontaeg series, Fine silty, Typic Endoaquepts) for Chinese cabbage cultivation. We found available phosphate increased significantly with shell meal fertilizer application, due to high content of phosphate ($1.5g\;P_2O_5\;kg^{-1}$) in the applied shell meal fertilizer. In addition, high pH of shell meal fertilizer contributed to increase available phosphate content by neutralization of acidic soil. Total and residual P contents increased significantly with increasing shell meal fertilizer application, but we could not find any tendency in organic and inorganic P fraction. Of extractable P fraction, water-soluble phosphorus (W-P) and calcium-bound P (Ca-P) contents increased significantly with increasing application level. By contrast, aluminum and iron-bound P (Al-P and Fe-P) decreased slightly with shell meal application. The present experiment indicated that shell meal fertilizer had a positive benefit on increasing available phosphate content in arable soil. And so the increased available phosphate by shell meal fertilizer may decrease phosphate application level and then reduce phosphorus loss in arable soil.

New candidates of 1 < z < 2 galaxy clusters in 13.6 $deg^2$ of ELAIS-N1/N2 fields with a new colour-colour selection technique

  • Hyun, Minhee;Im, Myungshin;Kim, Jae-Woo;Lee, Seong-Kook
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.50.2-50.2
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    • 2013
  • Galaxy clusters, the largest gravitationally bound systems, are an important means to place constraints on cosmological models. Moreover, they are excellent places to test galaxy evolution models in connection to the environments. To this day, massive clusters have been found unexpectedly at high redshfit (Kang & Im 2009, Durret et al. 2011, Tashikawa et al. 2012), and evolution of galaxies in cluster has not been fully understood. Finding galaxy cluster candidates at z > 1 in wide, deep imaging survey data will enable us to solve such issues of modern extragalactic astronomy. We report new candidates of galaxy clusters in the wide and deep survey fields, European Large Area ISO Survey North1(ELAIS-N1) and North2(ELAIS-N2) fields, covering sky area of $8.75deg^2$ and $4.85deg^2$ each. We also suggest a new useful colour-colour selection technique to separate 1 < z < 2 galaxies from low-z galaxies by combining multi-wavelength data from the UKIRT Infrared Deep Sky Survey Deep Extragalactic Survey (UKIDSS DXS, JK bands), Spitzer Wise-area InfraRed Extragalactic survey (SWIRE, Optical-Infrared bands), Canada France Hawaii Telescope (CFHT, z band) and Infrared Medium-deep Survey(IMS, J band).

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