• Title/Summary/Keyword: Al-Fe

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Mechanical Properties and Microstructure of Aluminum Alloys with Dispersed Nanoscale Quasicrystalline Particles

  • Fujita, Masashi;Kimura, Hisamichi;Inoue, Akihisa
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.708-709
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    • 2006
  • New Al-based alloys with very high ultimate tensile strength were developed in high Al concentration range of 91-95 at.% for Al-Fe-Cr-Ti-M (M: Co and Mo) systems and Al-Fe-Cr-Mo-Ti-Co system by the dispersion of nanoscale quasicrystalline particles in Al phase. The effect of adding elements, M was discussed in the viewpoint of stability of super-cooled liquid state and formation ability of quasicrystalline phase. The P/M Al-Fe-Cr-Ti-M alloys with dispersed nanoscale quasicrystalline particles exhibited ultimate tensile strength of 350MPa at 573K and 200MPa at 673K.

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Electrical conductivity of olivine type LiFe0.965Cr0.03B0.005PO4 and LiFe0.965Cr0.03Al0.005PO4 powders (올리빈형 LiFe0.965Cr0.03B0.005PO4 and LiFe0.965Cr0.03Al0.005PO4 분말의 전기전도도)

  • Kim, Chang-Sam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.3
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    • pp.141-146
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    • 2010
  • $LiFePO_4$ doped with Cr showed improved electrochemical properties as a cathode material of lithium-ion batteries compared to the undoped. The improvement was thought that the doping would raise the electronic conductivity of the compounds. The electrical conductivity of $LiFe_{0.965}Cr_{0.03}B_{0.005}PO_4$ and $LiFe_{0.965}Cr_{0.03}Al_{0.005}PO_4$ powder was measured in the temperature range from 30 to $80^{\circ}C$. The doped powders were synthesized via mechanochemical milling and subsequent heat treatment at 675~$750^{\circ}C$ for 5~10h. The doping enhanced grain growth and electrical conductivity. The electrical conductivity of the $LiFe_{0.965}Cr_{0.03}Al_{0.005}PO_4$ powder at $30^{\circ}C$ was $1{\times}10^{-8}S/cm$, which was higher two orders of magnitude than that of the undoped.

Effects of the Solid Solution Treatment Conditions and Casting Methods on Mechanical Properties of Al-Si-Cu Based Alloys (Al-Si-Cu계 합금의 주조법과 용체화처리 조건이 기계적 특성변화에 미치는 영향)

  • Moon, Min-Kook;Kim, Young-Chan;Kim, Yu-Mi;Choi, Se-Weon;Kang, Chang-Seog;Hong, Sung-Kil
    • Journal of Korea Foundry Society
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    • v.38 no.6
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    • pp.111-120
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    • 2018
  • In this study, the effects of two different casting methods (gravity casting and, diecasting) and various solid-solution conditions on the mechanical properties of ASC (Al-10.5wt%Si-1.75wt%Cu) and ALDC12 (Al-10.3wt%Si-1.72wt%Cu-0.76wt%Fe-0.28wt% Mn-0.32wt%Mg-0.9wt%Zn) alloys were investigated. A thermodynamic solidification analysis program (PANDAT) was used to predict the liquidus, solidus, and phases of the used alloys. In the results of an XRD analysis, ${\beta}$-AlFeSi peaks were observed only in the ALDC12 alloy regardless of the casting method or SST (solid-solution treatment) conditions. However, according to the results of a FE-SEM observation, both ${\theta}(Al_2Cu)$ and ${\beta}$-AlFeSi were found to exist besides ${\alpha}$-Al and eutectic Si in the gravity-casted ASC alloy at $500^{\circ}C$ after a SST of 120min. The ${\alpha}$-AlFeSi and ${\beta}$-AlFeSi phases including the eutectic phases were also found to exist in the ALDC12 alloy. The results of a microstructural observation and analyses by XRD, FE-SEM and EDS were in good agreement with the PANDAT results. The gravity-casted ALDC12 and ASC specimens showed the highest Y.S. and UTS values after aging for three hours at $180^{\circ}C$ after a SST at $500^{\circ}C$ for 30min. At longer solid-solution treatment times at $500^{\circ}C$ in the gravity-casted ALDC12 and ASC specimens, the elongations of the ASC alloys increased, whereas they decreased slightly in the ALDC12 alloys.

The Properties of Mn, Ni, and Al Doped Cobalt Ferrites Grown by Sol-Gel Method

  • Choi, Seung Han
    • Korean Journal of Materials Research
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    • v.28 no.7
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    • pp.371-375
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    • 2018
  • The manganese-, nickel-, and aluminum-doped cobalt ferrite powders, $Mn_{0.2}Co_{0.8}Fe_2O_4$, $Ni_{0.2}Co_{0.8}Fe_2O_4$, and $Al_{0.2}CoFe_{1.8}O_4$, are fabricated by the sol-gel method, and the crystallographic and magnetic properties of the powders are studied in comparison with those of $CoFe_2O_4$. All the ferrite powders are nano-sized and have a single spinel structure with the lattice constant increasing in $Mn_{0.2}Co_{0.8}Fe_2O_4$ but decreasing in $Ni_{0.2}Co_{0.8}Fe_2O_4$ and $Al_{0.2}CoFe_{1.8}O_4$. All the $M{\ddot{o}}ssbauer$ spectra are fitted as a superposition of two Zeeman sextets due to the tetrahedral and octahedral sites of the $Fe^{3+}$ ions. The values of the magnetic hyperfine fields of $Ni_{0.2}Co_{0.8}Fe_2O_4$ are somewhat increased in the A and B sites, while those of $Mn_{0.2}Co_{0.8}Fe_2O_4$ and $Al_{0.2}CoFe_{1.8}O_4$ are decreased. The variation of $M{\ddot{o}}ssbauer$ parameters is explained using the cation distribution equation, superexchange interaction and particle size. The hysteresis curves of the ferrite powders reveal a typical soft ferrite pattern. The variation in the values of saturation magnetization and coercivity are explained in terms of the site distributions, particle sizes and the spin magnetic moments of the doped ions.

Effect of Initial Microstructures on Hot Formability of Ti-10V-2Fe-3Al Alloy (Ti-10V-2Fe-3Al 합금의 열간성형성에 미치는 초기미세조직의 영향)

  • 신동혁
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1999.03b
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    • pp.153.2-158
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    • 1999
  • A study has been made to investigate how the fomability of Ti-10V-2Fe-3Al alloy is related to the initial microstructure and process variables such as temperature and strain rate. It has been found that the deformation resistance at high temperature is increased with the increase in the thickness of grain boundary a (GB)a and/or acicular a phase and however the effect of a morphology on the hot formability is considered insignificant due to the breakage of GB a and/or acicular a into several equiaxed a particles

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Fabrication of Sintered Thermistor Body of Fe-Al-Si-O System by Solid Reaction Method (고상반응법에 의한 Fe-Al-Si-Ti-O계 써어미스터 소결체 합성)

  • Gam, Kee-Sool;Gang, Gi-Hun
    • Korean Journal of Materials Research
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    • v.1 no.4
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    • pp.198-205
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    • 1991
  • Sintered thermistor body was fabricated by solid reaction method using $Fe_2O_3, \;Al_2O_3, \;TiO_2$ and Si powder. Surface matrix of sintered body was investigated by SEM and $\beta$-constant was obtained from measurement of resistance variation in liquid bath. The values of thermistor constant $\beta$ of samples in the temperature range $-50~+50^{\circ}C$ were distributed from 927 to 4005k. This thermistor body can be used as temperature sensor for radiosonde.

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Electronic Structure and Magnetism of Alloying Elements Substituted B2 FeAl Intermetallic Compounds: A Density Functional Study

  • Yun, Won Seok;Lee, Jee Yong;Kim, In Gee
    • Proceedings of the Korean Magnestics Society Conference
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    • 2012.11a
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    • pp.130-131
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    • 2012
  • In this study, the thermodynamic and magnetic properties of alloying element substituted B2 FeAl systems have been investigated using the all-electron FLAPW method based on the GGA. It was shown that the important changes take place in the structural properties as well as in the magnetism when alloying element is substituted by Fe or Al site in B2 FeAl. Detailed discussion on the thermodynamic and magnetic properties and electronic structure of these intermetallic compounds will be given.

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Effect of Alloying Elements on the Microstructure and High Temperature Oxidation Behavior of the Electro-Slag Remelted Fe-22Cr-5Al Alloy (일렉트로 슬래그로 재용해한 Fe-22Cr-5Al 합금의 미세조직 및 고온 산화 거동에 미치는 첨가 원소의 영향)

  • Kim, Moon-Hyun;Lee, Jeong-Keun;Joo, Dae-Heon;Kim, Myung-Ho
    • Journal of Korea Foundry Society
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    • v.22 no.6
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    • pp.293-298
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    • 2002
  • The effects of alloying elements added on the microstructure and high temperature oxidation behavior of the electro-slag remelted Fe-22Cr-5Al alloy were investigated. The amount of casting defect was makedly reduced by the electro-slag remelting. The electro-slag remelted ingot had a directionally solidified structure and cleaner surface than that of air-melted one. The high temperature oxidation reststance was greatly improved by the addition of Be and Zr.

Determination and Analysis of Interface Heat Transfer Coefficients in Hot Forming of Ti-6Al-4V (Ti-6Al-4V 합금의 열간성형에 대한 계면열전달계수의 결정 및 분석)

  • 염종택;임정숙;박노광;신태진;황상무;홍성석
    • Transactions of Materials Processing
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    • v.12 no.4
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    • pp.370-375
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    • 2003
  • Determination of the interface heat transfer coefficient was investigated in non-isothermal bulk forming of glass-coated Ti-6Al-4V. FE analysis and experiments were conducted. Equipment consisting of AISI Hl3 die was instrumented with thermocouples located at sub-surface of the bottom die. Die temperature changes were investigated in related to the process variables such as reduction, lubricant and initial die temperature. The calibration approach based on heat conduction and FE analysis using an inverse algorithm were used to evaluate the interface heat transfer between graphite-lubricated die and glass-coated workpiece. The coefficients determined were affected mainly by the contact pressure. The validation of the coefficients was made by the comparison between experimental data and FE analysis results.

Sintered $Fe_3Al$ Intermetallic - A New Filter Element for Hot Gas Filtration

  • Xing, Y.;Kuang, X.;Wang, F.;Kuang, C.;Fang, Y.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.597-598
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    • 2006
  • Gas filtration at high temperature from industrial processes offers various advantages such as increasing process efficiency, improving heat recovery and materials resource recovery, etc. At the same time, it is an advanced environment protection technology. This paper describes a newly developed metallic filter element. The manufacturing process of sintered $Fe_3Al$ metallic powder and the mechanical and filtration characteristics of this filter element were investigated. In this work, the phase constituent changes of the $Fe_3Al$ powder during sintering were studied. The newly developed filter elements were found to have excellent corrosion resistance, good thermal resistance, high strength and high filtration efficiency.

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