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Determination of Quantum well Thickness of ZnO-ZnMgO core-shell Cylindrical Heterostructures by Interband Optical Transitions

  • Sin, Yong-Ho;No, Seung-Jeong;Kim, Yong-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.208-208
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    • 2013
  • ZnO는 직접천이형 반도체로 약 3.37 eV의 넓은 에너지 band-gap과 60 meV의 비교적 큰 엑시톤 결합 에너지를 가지고 있다. 또한 단결정 성장 가능과 투명성 등 많은 장점들로 인하여 GaN와 대체할 자외선 또는 청색 발광소자나 ITO를 대체할 투명전극 같은 광범위한 광전소자로 큰 주목을 받으며 연구되어 왔다. 이러한 ZnO는 다양한 물질들의 첨가를 통해 인위적으로 특성변화가 가능한데 Mg, Be, Cd 첨가를 통한 에너지 밴드갭의 확장과 수축, Al 첨가를 통한 전기전도성의 증가 등이 그 예이다. 최근에는 밴드갭 조절을 이용한 ZnO-ZnMgO와 같은 이종접합구조가 광소자 등의 응용을 목적으로 많은 연구가 이루어지고 있다. 더불어 나노선이나 나노막대 같은 1차원 구조를 갖는 ZnO 계열 반도체의 연구는 현재 큰 이슈가 되고 있는 나노 크기의 소자 개발에 매우 큰 적용 가능성을 가지고 있다. 우리는 수열합성법을 이용하여 hexagonal ZnO 나노막대를 성장하고 그 표면에 core-shell 형태의 $ZnO-Zn_{1-x}Mg_xO$ (x=0.084) 양자우물을 원자층증착법으로 증착하였다. 본 연구에서는 만들어진 ZnO 나노막대와 ZnO-ZnMgO 나노막대, core-shell ZnO-ZnMgO 양자우물 sample들의 저온(5 K) Photoluminescence 측정을 통하여 광학적 band 구조를 분석하였다. 실험적으로 의도된 양자우물 두께와 다른 실제 형성된 양자무물의 두께를 알아내기 위하여 2차원 hexagonal 양자우물 band 구조에서 self-consistent nonlinear Poisson-Schr$\"{o}$dinger 방정식 계산과 컴퓨터 시뮬레이션을 이용하였으며, 이 방법으로 계산된 값과 실험값의 비교를 통하여 실제 형성된 양자우물의 두께를 정량적으로 유출할 수 있었다.

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Corelationship Study between Hwa-Byung and Coronary Heart Disease, by using Framingham Coronary Risk Score (Framingham Coronary Risk Score를 이용한 화병과 심혈관계 질환과의 관련성 연구)

  • Jeong, Ha-Ryong;Koh, Sang-Baek;Park, Jong-Ku;Yu, Jun-Sang;Lee, Jae-Hyok
    • Journal of Oriental Neuropsychiatry
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    • v.22 no.3
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    • pp.13-22
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    • 2011
  • Objectives : This study was to research the relationship between Hwa-Byung and Framingham coronary risk score(FRS), cardiovascular disease. Methods : 649 people participated in the community based cohort study in Wonju City of South Korea from July 2nd to August 30th in 2006. Educated investigators checked up systolic & diastolic blood pressure and surveyed Hwa-Byung Diagnostic Interview Schedule(HBDIS), cohort questionnaire about gender, age, smoking, diabetes. Blood sample was collected from participants to analyze total cholesterol, HDL-cholesterol. FRS was calculated from collected data. 10-year prediction of coronary heart disease was determined from FRS by using score sheet that is estimated by Wilson et al. Collected data were analyzed by the chi-square test. Results : 1. Low risk number of people was 18(52.9%) in Hwa-Byung group, 263(42.8%) in non Hwa-Byung group. p-value was 0.472. Difference of the two group was invalid. 2. The number of people below or equal to average 10-year prediction of coronary heart disease as gnder & age, Hwa-Byung group was 19(55.9%), non Hwa-Byung group was 412(67.0%). p-value was 0.251. Difference of the two group was invalid. Conclusions : There was no correlationship Between Hwa-Byung and 10-year prediction of coronary heart disease.

Characterization of Asbestos Content in Friable Sprayed-on Surface Material and Airborne Asbestos Concentrations in Buildings by TEM (전자현미경을 이용한 건물내 비고형 표면자재의 석면 오염 및 기중 석면농도 특성조사)

  • Yu, Sung Whan;Kim, Hyun Wook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.6 no.2
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    • pp.165-175
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    • 1996
  • Fourteen(14) large commercial buildings located in Seoul with friable sprayed-on surface insulation material on ceiling were investigated for fiber types in bulk material and for airborne fiber concentrations in buildings by transmission electron microscopy (TEM) in order to compare the results with those by polarized light microscopy (PLM) and phase contrast microscopy (PCM). The results were as follows: 1. Chrysotile asbestos was found in one bulk sample out of total 14 bulk samples collected. Glass fiber and mineral wool were the two major constituents of the bulk samples. 2. The Na-Mg-Si-Ca-Fe-Al ratios of the EDX spectra which were normalized with the Si peak were 0-1.0-10-8.3-4.0-4.0 in mineral wool and 0-5-10-21-0-0 in chrysotile asbestos, respectively. 3. Airborne fiber concentrations were log-normalcy distributed and the geometric mean (geometric standard deviation) fiber concentrations by TEM in the underground parking lots and inside buildings were 0.0048 f/cc(1.93) and 0.0040 f/cc(2.27), respectively with no statistical difference. In the outdoor ambient air, statistically significantly lower concentration of 0.0018 f/cc(2.04) was measured. 4. The TEM/PCM ratios of airborne fiber concentrations ranged 0.5 - 2.0 for 80 % of airborne samples analyzed, end the regression equation between TEM and PCM was PCM=-0.2724+1.1355(TEM) with the coefficient of determination $R^2=0.52$. The results of this study confirmed that the sprayed-on surface insulation material found in some commercial buildings may possibly be contaminated with asbestos fiber. Since statistically significant relationship of fiber concentrations measured by PCM and TEM inside buildings and ambient air was found, previous results by PCM in ambient air could be used to estimate the ambient fiber concentrations in knowing the ratio of TEM/PCM.

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The Study on Coatings to Improve the Radiative Heat Dissipation of Aluminum Alloy (알루미늄 합금의 복사방열향상을 위한 코팅연구)

  • Seo, Mihui;Kim, Donghyun;Lee, Junghoon;Chung, Wonsub
    • Journal of the Korean institute of surface engineering
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    • v.46 no.5
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    • pp.208-215
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    • 2013
  • The aim of the present study was to improve the radiative heat dissipation of aluminum alloy, Al 1050. Resin/CuO coating and Cu/CuO composite plating were applied on aluminum alloy to improve the radiative heat dissipation. Resin/CuO coating was made using thermosetting silicon resin and Cu/CuO composite plating was made in pyrophosphate copper plating bath. Radiant heat flux($W/m^2$) was measured by self-produced radiant heat measurement device to compare each specimen. The cross section of specimen and chemical bonding of surface were analyzed by FE-SEM, XPS and FT-IR. As a result, radiant heat of Resin/CuO coating was higher than Cu/CuO composite plating due to the adhesion with aluminum plate and the difference in chemical bonding. But, Both of them were higher than aluminum alloy. In order to confirm the result of experiment, aluminum plate, Resin/CuO coating and Cu/CuO composite plating sample were applied LED and measured the LED temperature. As a result, LED temperature of samples were matched previous results and confirmed coated samples were lower about 10 degrees than the aluminum alloy.

Superplastic Deformation in the Low Stress Region

  • Jang, Chun-Hag;Kim, Chang-Hong;Ree, Tai-Kyue
    • Bulletin of the Korean Chemical Society
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    • v.5 no.2
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    • pp.73-78
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    • 1984
  • Superplastic alloys generally exhibit a three-stage sigmoidal variation of stress (f) with strain rate (s), the stages being named region 1, 2 and 3 according to the increasing order of stress or strain rate. In the recent years, two different types of papers have been published on the plastic deformation of Zn-22% Al eutectoid in region Ⅰ differing in strain-rate sensitivity m (= dln f/dln s). In this paper, the data of the two groups have been analysed by applying Kim and Ree's theory of superplastic deformation. (1) We obtained the parametric values of $X_{gj}/{\alpha}_{gj}\;and\;{\beta)_{gj}$ (g: grain boundary, j = 1,2 indicating flow units) appearing in Kim and Ree's theory [Eq. (2a)]. (2) It was found that the value of $X_{g^2}/{\alpha}_{g^2}$ is small for the group data with small m, i.e., ${\alpha}_{g^2}$, which is proportional to the size of flow unit g2, is large whereas ${\alpha}_{g^2}$ is small for the groups data with large m, i.e., the size of the flow unit g2 is small. In other words, the two types of behavior occur by the size difference in the flow units. (3) From the ${\beta}_{gj}$ value, which is proportional to the relaxation time of flow unit gj, the ${\Delta}H_{gj}^{\neq}$ for the flow process was calculated, and found that ${\Delta}H_{g^2}^{\neq}$ is large for the group data with small m whereas it is small for the group data with large m. (4) The flow-unit growth was studied, but it was concluded that this effect is not so important for differentiating the two groups. (5) The difference in ${\alpha}_{g^2}$ and in the growth rate of flow units is caused by minute impurities, crystal faults, etc., introduced in the sample preparation.

ENVIRONMENTAL DEPENDENCE OF TYPE IA SUPERNOVA LUMINOSITIES FROM THE YONSEI SUPERNOVA CATALOG

  • Kim, Young-Lo;Kang, Yijung;Lee, Young-Wook
    • Journal of The Korean Astronomical Society
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    • v.52 no.5
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    • pp.181-205
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    • 2019
  • There is evidence that the luminosities of Type Ia supernova (SN Ia) depend on their environments. While the impact of this trend on estimating cosmological parameters is widely acknowledged, the origin of this correlation is still under debate. In order to explore this problem, we first construct the YONSEI (YOnsei Nearby Supernova Evolution Investigation) SN catalog. The catalog consists of 1231 spectroscopically confirmed SNe Ia over a wide redshift range (0.01 < z < 1.37) from various SN surveys and includes light-curve fit data from two independent light-curve fitters, SALT2 and MLCS2k2. For a sample of 674 host galaxies, we use the stellar mass and the star formation rate data in Kim et al. (2018). We find that SNe Ia in low-mass and star-forming host galaxies are $0.062{\pm}0.009mag$ and $0.057{\pm}0.010mag$ fainter than those in high-mass and passive hosts, after light-curve corrections with SALT2 and MLCS2k2, respectively. When only local environments of SNe Ia (e.g., locally star-forming and locally passive) are considered, this luminosity difference increases to $0.081{\pm}0.018mag$ for SALT2 and $0.072{\pm}0.018mag$ for MLCS2k2. Considering the significant difference in the mean stellar population age between the two environments, this result suggests that the luminosity evolution of SNe Ia with redshift is most likely the origin of the environmental dependence.

Financial Liberalization, Government Stability, and Currency Crises - Some Evidence from South Korea and Emerging Market Economies

  • Chiu, Eric M.P.
    • Journal of Korea Trade
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    • v.23 no.5
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    • pp.129-144
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    • 2019
  • Purpose - Recent empirical studies have reached mixed results on the effects of financial liberalization and currency crises. We argue that this relationship is likely to depend both on whether controls are primarily on the degrees of financial liberalization and on the stability of the government. Using the disaggregated data on financial liberalization recently developed by Abiad et al (2010) for a sample of 30 emerging countries over the period 1995-2015, we attempt to investigate the political economy determinants of currency crises. Design/methodology - Our empirical model considers the relationship between financial liberalization and currency crises for emerging market economies. This study employs the existing theoretical framework to identify the disaggregate level for financial liberalization across countries. Using a multivariate logit model, this study attempts to estimate the interrelationship among financial liberalization, government stability and currency crises complemented by a case study of South Korea. Findings - Our main findings can be summarized as follows: we find strong support for the proposition that more liberalized financial institutions are positively associated with the probability of currency crises especially under less stable governments, but reduce the risks of currency crises especially for more stable governments. We also examine the role of financial systems with the case of South Korea after Asian financial crises and the results are further supported and consistent with the empirical findings. Originality/value - Existing studies focus on the economic factors across countries. This paper instead attempts to evaluate the effects of financial liberalization and currency crises by incorporating political considerations with newly developed dataset on financial liberalization, which are essential to the understanding of the causes of currency crises.

Tailoring the Dielectric and Mechanical Properties of Si3N4 Ceramics (질화규소 세라믹의 유전 및 기계적 특성 제어에 관한 연구)

  • Lee, Seung Jun;Yong, Seok-Min;Park, Jin-Woo;Choi, Jaeho;Baek, Seungsu
    • Journal of the Korea Institute of Military Science and Technology
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    • v.21 no.6
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    • pp.760-766
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    • 2018
  • The present study investigates the effect of PMMA and BN content on microstructure, mechanical and dielectric properties of silicon nitride($Si_3N_4$) ceramics in $Y_2O_3-Al_2O_3$ additive system. The total additive content was fixed at 8 wt.% and the amount of PMMA varies from 0 to 40 wt.% and BN varies from 0 to 36 wt.%, respectively. The crystalline phases of the samples were determined by X-ray diffraction analysis. All the sintered sample shows complete transformation of ${\alpha}$ to ${\beta}-Si_3N_4$ during the sintering process indicated that the phase transformation was unaffected by the PMMA or BN content. However, the microstructure shows that the residual porosity increased with increasing PMMA and BN content. In addition, the flexural strength and the dielectric constant decrease with addition of PMMA and BN due to the residual porosity. This article provides empirical study of design parameters for $Si_3N_4$-based radome materials.

Microstructure and Mechanical Properties of AA6061/AA5052/AA6061 Complex Sheet Fabricated by Cold-Roll Bonding Process (냉간압연접합법에 의해 제조된 AA6061/AA5052/AA6061 복합판재의 미세조직 및 기계적 성질)

  • Hwang, Ju-Yeon;Lee, Seong-Hee
    • Korean Journal of Materials Research
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    • v.29 no.6
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    • pp.392-397
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    • 2019
  • A cold roll-bonding process is applied to fabricate an AA6061/AA5052/AA6061 three-layer clad sheet. Two AA6061 and one AA5052 sheets of 2 mm thickness, 40 mm width, and 300 mm length are stacked, with the AA5052 sheet located in the center. After surface treatment such as degreasing and wire brushing, sample is reduced to a thickness of 1.5 mm by multi-pass cold rolling. The rolling is performed at ambient temperature without lubricant using a 2-high mill with a roll diameter of 400 mm at rolling speed of 6.0 m/sec. The roll bonded AA6061/AA5052/AA6061 complex sheet is then hardened by natural aging(T4) and artificial aging(T6) treatments. The microstructures of the as-roll bonded and age-hardened Al complex sheets are revealed by optical microscopy; the mechanical properties are investigated by tensile testing and hardness testing. After rolling, the roll-bonded AA6061/AA5052/AA6061 sheets show a typical deformation structure in which grains are elongated in the rolling direction. However, after T4 and T6 aging treatment, there is a recrystallization structure consisting of coarse equiaxed grains in both AA5052 and AA6061 sheets. The as roll-bonded specimen shows a sandwich structure in which an AA5052 sheet is inserted into two AA6061 sheets with higher hardness. However, after T4 and T6 aging treatment, there is a different sandwich structure in which the hardness of the upper and lower layers of the AA6061 sheets is higher than that of the center of the AA5052 sheet. The strength values of the T4 and T6 age-treated specimens are found to increase by 1.3 and 1.4 times, respectively, compared to that value of the starting material.

Effect of Powder Preheating Temperature on the Properties of Cu based Amorphous Coatings by Cold Spray Deposition (저온분사로 제조된 Cu계 비정질 코팅층 특성에 미치는 분말 예열 온도의 영향)

  • Cho, Jin-Hyeon;Park, Dong-Yong;Lee, Jin-Kyu;Lee, Kee-Ahn
    • Korean Journal of Metals and Materials
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    • v.47 no.11
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    • pp.728-733
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    • 2009
  • Cu based amorphous ($Cu_{54}Zr_{22}Ti_{18}Ni_{6}$) powders were deposited onto Al 6061 substrates by cold spray process with different powder preheating temperatures (below glass transition temperature: $350^{\circ}C$, near glass transition temperature: $430^{\circ}C$ and near crystallization temperature: $500^{\circ}C$). The microstructure and macroscopic properties (hardness, wear and corrosion) of Cu based amorphous coating layers were also investigated. X-ray diffraction results showed that cold sprayed Cu based amorphous coating layers of $300{\sim}350{\mu}m$ thickness could be well manufactured regardless of powder preheating temperature. Porosity measurements revealed that the coating layers of $430^{\circ}C$ and $500^{\circ}C$ preheating temperature conditions had lower porosity contents (0.88%, 0.93%) than that of the $350^{\circ}C$ preheating condition (4.87%). Hardness was measured as 374.8 Hv ($350^{\circ}C$), 436.3 Hv ($430^{\circ}C$) and 455.4 Hv ($500^{\circ}C$) for the Cu based amorphous coating layers, respectively. The results of the suga test for the wear resistance property also corresponded well to the hardness results. The critical anodic current density ($i_{c}$) according to powder preheating temperature conditions of $430^{\circ}C$, $500^{\circ}C$ was lower than that of the sample preheated at $350^{\circ}C$, respectively. The higher hardness, wear and corrosion resistances of the preheating conditions of near $T_{g}$ and $T_{x}$, compared to the properties of below $T_{g}$, could be well explained by the lower porosity of coating layer.