• Title/Summary/Keyword: Air_Resistances

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Hydrogen Gas Sensing Properties in Air on PdO Thin Films

  • Kim, Yeon-Ju;Lee, Young-Taek;Lee, Jun-Min;Lee, Woo-Young
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04b
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    • pp.91-91
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    • 2009
  • In the past decade, Pd based thin films have been studied far hydrogen gas sensors due to their high possibility for energy industry and environmental applications. In this work, we report a navel method to fabricate highly sensitive hydrogen gas sensors based on PdO thin films. The films were deposited on Si substrates in Ar and $O_2$ ambient using reactive sputtering system. A semiconductor process has been utilized to fabricate PdO films with t=40nm. We observed the resistance changes of the PdO films with various $H_2$ concentrations. It was found that the electrical properties of the thin films depend on the composition of oxygen. The sensitivity is defined as $S\;=\;(R_0-R)/R{\times}100%$, where R and $R_0$ are the resistances in the presence of exposing the hydrogen gas and air, respectively. The sensitivity of the thin films was found to be as high as about 95%. After exposing to hydrogen gas, we discovered that the nano-sized cracks formed on the surface of the PdO thin films. The nano-cracks formed in deoxidized PdO thin films were known by playing a key role to reduce more than 4 times the response time of absorption. Our results illustrate that the deoxidized PdO thin films can be used as hydrogen sensors.

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Hollow SnO2 Hemisphere Arrays for Nitric Oxide Gas Sensing

  • Hoang, Nhat Hieu;Nguyen, Minh Vuong;Kim, Dojin
    • Korean Journal of Materials Research
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    • v.23 no.12
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    • pp.667-671
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    • 2013
  • We present an easy method of preparing two-dimensional (2D) periodic hollow tin oxide ($SnO_2$) hemisphere array gas sensors using polystyrene (PS) spheres as a template. The structures were fabricated by the sputter deposition of thin tin (Sn) metal over an array of PS spheres on a planar substrate followed by calcination at an elevated temperature to oxidize Sn to $SnO_2$ while removing the PS template cores. The $SnO_2$ hemisphere array structures were examined by scanning electron microscopy and X-ray diffraction. The structures were calcined at various temperatures and their sensing properties were examined with varying operation temperatures and concentrations of nitric oxide (NO) gas. Their gas-sensing properties were investigated by measuring the electrical resistances in air and the target gases. The measurements were conducted at different NO concentrations and substrate temperatures. A minimum detection limit of 30 ppb, showing a sensitivity of S = 1.6, was observed for NO gas at an operation temperature of $150^{\circ}C$ for a sample having an Sn metal layer thickness corresponding to 30 sec sputtering time and calcined at $600^{\circ}C$ for 2 hr in air. We proved that high porosity in a hollow $SnO_2$ hemisphere structure allows easy diffusion of the target gas molecules. The results confirm that a 2D hollow $SnO_2$ hemisphere array structure of micronmeter sizes can be a good structural morphology for high sensitivity gas sensors.

Development of 50W High Quality Factor Printed Circuit Board Coils for a 6.78MHz, 60cm Air-gap Wireless Power Transfer System (6.78MHz, 거리 60cm, 50W급 무선 전력 전송 시스템용 High Quality Factor PCB 코일 개발)

  • Lee, Seung-Hwan;Yi, Kyung-Pyo
    • Journal of the Korean Society for Railway
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    • v.19 no.4
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    • pp.468-479
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    • 2016
  • In order to supply power to online monitoring systems that are attached to high voltage catenary or overhead wires, a wireless power transfer system is required that is able to transmit power over the insulation gap. Such wireless power transfer systems have transmitter and receiver coils that have diameters of over 10cm. This paper focused on an investigation of the sources of loss in the coils when the coils are fabricated using printed circuit board technology. Using finite element simulation results, it has been shown that the dielectric loss in the substrate was the dominant source of the total loss. It has been demonstrated that the selection of a proper dielectric material was the most critical factor in reducing the loss. For further reduction of the loss, the distributed tuning capacitor method and the slotting of the inter-turn spaces have been proposed. For the evaluation of the proposed methods, four coils have been fabricated and their equivalent series resistances and quality factors were measured. Measured quality factors were greater than 300, which means that these devices will be helpful in achieving high coil-to-coil efficiency.

Basic Performance Test of a Three Phase AC Arc Plasma Torch System for Plasma Gas Reforming (플라즈마 가스 개질 응용을 위한 3상 아크 플라즈마 토치 시스템 특성 실험)

  • DONG-HYUN LEE;DARIAN FIGUERA-MICHAL;HAE-WON PARK;NAM-KI LEE;SANG-YUN PAEK;SHIYOUNG YANG;JUN-HO SEO
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.1
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    • pp.8-16
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    • 2023
  • In this work, we report basic performance test results of a lab-scale three phase alternative current (AC) arc plasma torch system for plasma gas reforming applications. The suggested system primarily consists of three graphite electrodes inclined at 12.5° to the central axis, a 𝞥 150 mm cylindrical gas path and a three phase-60 Hz AC power supply. At air flow rate of 50 Lpm and arc currents of 100-175 A, test results revealed that plasma resistances were decreasing from 1.08 Ω to 0.53 Ω with the increase of plasma power from 9.3 kW to 13.8 kW, causing the decrease of power factor and increase of the line voltages. However, the injected air can be heated quickly up to the temperatures of >1,200℃ when injecting AC arc plasma powers of >10 kW.

Meteorological Constraints and Countermeasures in Rice Breeding -Breeding for cold tolerance- (기상재해와 수도육종상의 대책 - 내냉성품종육성방안-)

  • Mun-Hue Heu;Young-Soo Han
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.27 no.4
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    • pp.371-384
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    • 1982
  • Highly cold tolerant varieties are requested not only at high latitute cool area but also tropical high elevated areas, and the required tolerance is different from location to location. IRRI identified 6 different types of cold tolerance required in the world for breeding purpose; a) Hokkaido type, b) Suweon type, c) Taipei 1st season type, d) Taipei 2nd season type, e) Tropical alpine type and, f) Bangladesh type. The cold tolerance requested in Korea is more eargent in Tongil group cultivars and their required tolerance is the one such as the physiological activities at low temperature are as active as in Japonica group cultivars at least during young seedling stage and reproduction stage. With conventional Japonica cultivars, such cold tolerant characters are requested as short growth duration but stable basic vegetative growth, less sensitive to high temperature and less prolonged growth duration at low temperature. The methods screening for cold tolerance were developed rapidly after the Tongil cultivar was reliesed. The facilities of screening for cold tolerance, such as, low temperature incubator, cold water tank, growth cabinet, phytotron, cold water nursery in Chuncheon, breeding nursery located in Jinbu, Unbong and Youngduk, are well established. Foreign facilities such as, cold water tank with the rapid generation advancement facilities, cold nurseries located in Banaue, Kathmandu and Kashimir may be available for the screening of some limitted breeding materials. For the reference, screening methods applied at different growth stages in Japan are introduced. The component characters of cold tolerance are not well identified, but the varietal differences in a) germinability, b) young seedling growth, c) rooting, d) tillering, e) discolation, f) nutrition uptake, g) photosynthesis rate, h) delay in heading, i) pollen sterility, and j) grain fertility at low temperature are reported to be distinguishable. Relationships among those traits are not consistent. Reported studies on the inheritance of cold tolerance are summarized. Four or more genes are controlling low temperature germinability, one or several genes are controlling seedling tolerance, and four or more genes are responsible for the pollen fertility of the rice treated with cold air or grown in the cold water nursery. But most of those data indicate that the results may come out in different way if those were tested at different temperature. Many cold tolerant parents among Japonicas, Indicas and Javanicas were identified as the results of the improvement of cold tolerance screening techniques and IRTP efforts and they are ready to be utilized. Considering a) diversification of germ plasm, b) integration of resistances to diseases and insects, c) identification of adaptability of recommending cultivars and, d) systematic control of recommending cultivars, breeding strategies for short term and long term are suggested. For short term, efforts will be concentrated mainly to the conventional cultivar group. Domestic cultivars will be used as foundation stock and ecologically different foreign introductions such as from Hokkaido, China or from Taiwan, will be used as cross parents for the adjustment of growth durations and synthsize the prototype of tolerances. While at the other side, extreme early waxy Japonicas will be crossed with the Indica parents which are identified for their resistances to the diseases and insects. Through the back corsses to waxy Japonicas, those Indica resistances will be transfered to the Japonicas and these will be utilized to the crosses for the improvement of resistances of prototype. For the long term, efforts will be payed to synthsize all the available tolerances identified any from Japonicas, Indicas and Javanicas to diversify the germ plasm. The tolerant cultivars newly synthsized, should be stable and affected minimum. to the low temperature at all the growing stages. The resistances to the diseases and insects should be integrated also. The rapid generation advancement, pollen culture and international cooperations were emphasized to maximize the breeding efficiency.

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Evaluation of Corrosion Characteristics of Underwater Hardening Paint (수중 경화형도료의 부식특성에 관한 전기화학적 고찰)

  • Moon, Kyung-Man;Oh, Min-Seok;Lee, Myung-Hoon;Lee, Syung-Yul;Kim, Yun-Hae
    • Journal of Ocean Engineering and Technology
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    • v.25 no.2
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    • pp.85-91
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    • 2011
  • Many protection methods such as surface coating, electric protection, or other methods have been applied to the numerous steel structures widely used in continental and marine areas to control their corrosion, which is done from an economic point of view. Most of these steel structures are primarily protected by coating methods. However, some steel piles under seawater are protected by the electric protection method, that is, either using an impressed current or a sacrificial anode method. Furthermore, environmental contamination may cause a severely corrosive environment, which, in turn, causes the accelerated corrosion of steel structures. Subsequently, coated steel structures could deteriorate more rapidly than the designed lifetime because of the acid rain caused by air pollution, etc. Therefore, a coating of marine paint exposed to seawater, that is, underwater hardening painting, is increasingly required to be fast drying as well as highly corrosion resistant. In this study, five types of underwater hardening paints were prepared with different resin series and additives. Their corrosion and water resistances were investigated using electrochemical methods such as corrosion potential, polarization curves, impedance and cyclic voltammogram measurements, etc. Even though it is generally accepted that the corrosion resistance of bare steel tends to increase with a shift of the corrosion potential in the noble direction, the corrosion resistance of a sample with a coating exhibited a relatively better tendency when it had a lower corrosion potential in this study. The corrosion current density was also decreased with a decrease in the diffusion limiting current density, which may mean that there is some relationship between corrosion and water resistance. The S sample of the ceramic resin series showed the relatively best corrosion and water resistance among those of samples, while the worst corrosion and water resistance were observed for the R sample of the epoxy resin series. The corrosion and water resistance of those samples tended to deteriorate with an increase in the immersion days, and their corrosion and water resistances were considered to be apparently improved by the types of resin and additives.

Corrosion and Oxidation Properties of Ni-Base Superalloy KM 1557 (Ni기 초내열 단조합금 KM 1557의 부식 및 산화성질)

  • Choi, Hyoung Il;Kim, Hyon Tae;Kim, Young Do;Yoon, Kook Han;Yoo, Myoung Ki;Kwun, Sook In;Choi, Ju
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.143-152
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    • 1992
  • Corrosion resistances in various acids and high temperature oxidation properties have been investigated for the Ni-base superalloy KM 1557. Corrosion tests were performed in $H_2SO_4$, HCl, $HNO_3$, $H_3PO_4$ and $CH_3COOH$. Oxidation tests were carried out in air for 20 and 110hrs at $900^{\circ}C$, $950^{\circ}C$ and $1050^{\circ}C$. Hot corrosion tests were done in salt bath of 75% $Na_2SO_4-25%$ NaCl at $900^{\circ}C$ for 20hrs. After the tests, the samples were observed by optical microscopy and analysed by EPMA and X-ray mapping in order to investigate the distribution of composition. It was shown that corrosion resistances in various acids and hot salt bath were proven to be excellent. It was suggested that the amounts of oxides were determined mainly by the depth of internal and intergranular $Al_2O_3$ oxide layers.

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A Study on the Group Effect of the Inclined Ground Anchor (경사 지반앵커의 군효과에 대한 연구)

  • 임종철;홍석우
    • Geotechnical Engineering
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    • v.10 no.4
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    • pp.39-52
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    • 1994
  • The group effect of inclined ground anchor should be considered in design, but it has been hardly studied due to the difficulties of experimental or theoretical study. In this study, the model tests for the inclined ground anchors are made, and the displacements and strain fields of ground around anchor surface are analysed. As the results of this study, the group effect of the inclined ground anchor in air dried sand ground does not show even though two anchor surfaces are very close(10.7cm, surface to surface). That is to say, ,in the case that the final failure surface by pullout of anchor shows on the anchor surface, the pullout resistances of single anchors are almost same as those of the group anchors in these model tests.

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The Effects of Composition and Microstructure Variation on the Oxidation Characteristics of Stainless Steels Manufactured by Powder Metallurgy Method (분말야금 스테인리스 스틸의 산화특성에 미치는 조성 및 조직변화의 영향)

  • Lee, Jong-Pil;Hong, Ji-Hyun;Park, Dong-Kyu;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.22 no.1
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    • pp.52-59
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    • 2015
  • As well-known wrought stainless steel, sintered stainless steel (STS) has excellent high-temperature anti-corrosion even at high temperature of $800^{\circ}C$, and exhibits good corrosion resistance in air. However, when temperature increases above $900^{\circ}C$, the corrosion resistance of STS begins to deteriorate and dramatically decreases. In this study, the effects of phase and composition of STS on high-temperature corrosion resistances are investigated for STS 316L, STS 304 and STS 434L above $800^{\circ}C$. The morphology of the oxide layers are observed. The oxides phase and composition are identified using X-ray diffractometer and energy dispersive spectroscopy. The results demonstrate that the best corrosion resistance of STS could be improved to that of 434L. The poor corrosion resistance of the austenitic stainless steels is due to the fact that $NiFe_2O_4$ oxides forming poor adhesion between the matrix and oxide film increase the oxidation susceptibility of the material at high temperature.

Study on the Characteristics of the Corrosion Fatigue Crack Propagation of Al-Alloy used for the Shipbuilding (선박용 알루미늄 합금재의 부식피로구열 진전특성에 관한 연구)

  • Im, U-Jo;Lee, Jong-Rak;Lee, Jin-Yeol
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.24 no.2
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    • pp.94-100
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    • 1988
  • Recently with the rapid development in marine and shipbuilding industries such as marine structures, ship, and chemical plants, there occurs much interest in the study of corrosion fatigue characteristics was closed up an important role in mechanical design. In this study, the 5086 Al-Alloy was tested by used of a rotary bending fatigue tester and was investigated under the environments of various specific resistance and air. The specific resistance, as a corrosion environment, was changed 15, 20, 25 and 5000$\Omega$.cm. The corrosion fatigue crack initiation sensitivity was quantitatively inspected for 5086 Al-Alloy in the various specific resistance. The experimental constants of Paris rule were examined in the various specific resistances, and the influences of load and corrosion with affect the crack growth rate were compared with. Main results obtained are as follows: (1) Number of stress cycles to corrosion fatigue crack initiation delaies and corrosion fatigue crack initiation sensitivity decreases with the increasing for the specific resistance. (2) The experimental constant m of Paris rule decreases with the decreasing for specific resistance. Hence the effect of corrosion is more susceptible than that of stress intensity factor. (3) The corrosion fatigue crack of 5086 Aluminium Alloy appears intergranular fracture. (4) Corrosion sensitivity is decreased with the increasing stress intensity factor and is nearly uniform when stress intensity factor is over 40kg.mm super(-3/2)

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