• Title/Summary/Keyword: Air volume

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Nonstoichiometry and Physical Properties of the Perovskite $CaGa_{1-x}Fe_xO_{3-y}$ System (페롭스카이트 $CaGa_{1-x}Fe_xO_{3-y}$계의 비화학량론과 물리적 성질)

  • Rho, Kwon Sun;Ryu, Kwang Hyun;Chang, Soon Ho;Yo, Chul Hyun
    • Journal of the Korean Chemical Society
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    • v.40 no.5
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    • pp.295-301
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    • 1996
  • A series of solid solutions of the $CaGa_1-xFexO_3-y$ system with the compositions of x=0.25, 0.50, 0.75, and 1.00 has been prepared at $1150^{\circ}C$ under an atmospheric air pressure. The structure, nonstoichiometric chemical formula, and the distribution of cations for the solid solutions are determined by X-ray diffraction analysis, Mohr salt titration, Mossbauer spectroscopic analysis. Their physical properties are discussed with electrical conductivity and magnetic measurements. The crystal system of all the compositions is a brownmillerite orthorhombic system from the X-ray diffraction analysis and the reduced lattice volume increases linearly with x value except that of the composition of x=0.25. All the solid solutions do not contain $Fe^{4+}$ ion and the mole number of oxygen vacancies or y value is 0.50 from Mohr salt analysis. The oxidation state of Fe ion, the coordination state, the structure change in the Brownmillerite-type structure, and the distribution of $Ga^{3+}$ and $Fe^{3+}$ ions are discussed with Mossbauer spectroscopic analysis. The electrical conductivity increases and activation energy decreases, as x value increases. The traditional semiconducting property of this system is described in terms of band theory. The compositions of x=0.50∼1.00 show a thermal magnetic hysteresis in the magnetic measurement with the cooling conditions, which is discussed in terms of the space group and Dzyaloshinsky-Moriya interaction.

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An Experimental Study on Mortar to Apply Building Structure (건축물 구조체에 적용가능한 모르타르에 관한 실험적 연구)

  • Kwon, Mi-Ok;Yoon, Ki-Hyun;Jung, Kang-Sik;Kim, Gang-Ki;Paik, Min-Su;Jung, Sang-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.413-416
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    • 2008
  • The concrete used most in construction materials. There is an overcrowded iron dimensions use of the concrete at time of the other concrete theory on the reinforcing rod back which did congestion and compares it with this, and there are more few dimensions of the aggregate than concrete, and quantity of aggregate passage is superior in mortar than concrete. If a volume rate of the aggregate writes mortar than concrete against this, therefore, unit amount increases, and quantity of paste increases and quantity of dry shrinkage than increase concrete. However, I let I regulate lay priest distribution of the aggregate, and the results rates increase and reduce unit amount and decrease quantity of dry shrinkage, and separation resistance and the gap passage characteristics are judged because it can be it in a substitute document of very superior concrete. I came to carry out the study that I watched to let I was useful a little more and do the improvement repair of a become building wall body, a basement pillar and repair reinforcement of the assistant in the reinforcing rod back, the old age when I made congestion here. I regulated lay priest distribution of the aggregate in the study and regulated substitution rate of the aggregate (40%, 50%, 60%) and divided W/C 30%, 40% standards and produced mortar and I compared quantity of air by this, slump, compression robbery and showed it this time.

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Seismic Amplitude and Frequency Characteristics of Gas hydrate Bearing Geologic Model (가스 하이드레이트 지층 모델의 탄성파 진폭 및 주파수 특성)

  • Shin, Sung-Ryul;Lee, Sang-Cheol;Park, Keun-Pil;Lee, Ho-Young;Yoo, Dong-Geun;Kim, Young-Jun
    • Geophysics and Geophysical Exploration
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    • v.11 no.2
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    • pp.116-126
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    • 2008
  • In gas hydrate survey, seismic amplitude and frequency characteristics play a very important role in determining whether gas hydrate exists. According to the variation of source frequency and scatterer size, we study seismic amplitude characteristics using elastic modeling applied at staggered grids. Generally speaking, scattering occurs in proportion to the square of source frequency and the scatterer volume, which has an effect on seismic amplitude. The higher source frequency is, the more scattering occurs in gas hydrate bearing zone. Therefore, BSR is hardly observed in high frequencies. On the other side, amplitude blanking zone and BSR is clearly observed in lower frequencies although the resolution is poor as a whole. Seismic reflections traveling through free-gas layer below gas hydrate bearing zone decay so severely a high frequency component that a low frequency term is dominant. Amplitude anomaly of BSR result from high acoustic impedance contrast due to free-gas, which is a very crucial factor to estimate gas hydrate bearing zone. Seismic frequency analysis is carried out using wavelet transform method that frequency component could be decomposed with time variation. In application of wavelet transform to the seismic physical experiments data, we can observe that reflections traveling through air layer, which corresponds to the free-gas layer, decay a high frequency component.

Changes in Internal Pressure of Frozen Fruits by Freezing Methods (동결방법에 따른 냉동 과일의 내부압력 변화)

  • 정진웅;정승원;박기재
    • Food Science and Preservation
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    • v.10 no.4
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    • pp.459-465
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    • 2003
  • This study was carried out to investigate the changes in internal pressure according to various freezing methods, as basic research to protect the destruction of tissues when fruits and vegetables are frozen. The rate of weight loss, caused by the freezing of fruits and vegetables, was found to be the least (0.44∼1.38%) when the immersion freezing method was applied. The difference in the rate of weight loss was the highest when freezing methods were applied to watermelon, and the freezing rate of watermelon whose moisture contents were greater have relatively greater influence on the weight loss. The difference in internal pressures was the least and caused by the volume increase and decrease, when pear, apple, and melon were frozen using the immersion freezing method, while the diffeyence the greatest when the air-blast freezing method was used. As the freezing rate was greater, the internal pressure was less. However, the internal pressure of strawberry and watermelon was the greatest when the immersion freezing method was applied. Frozen without using the thermal equalizing method, the change in internal pressure of fruits was about 2 psig. In contrast, the internal pressure of watermelon applied with the thermal equalizing method was changed in a way similar to that of watermelon not applied with the method, but the former generated a certain level of internal pressure and maintained a significantly low level of internal pressure (about 1.3 psig). When thawed, the internal pressure of samples to which the thermal equalizing method was applied was less than that of what the thermal equalizing method was not applied to. In comparison with the application of multi-step thermal equalizing method, 3∼4 times of application of the thermal equalizing method to the freezing resulted in the decrease of fluctuation range of internal pressure.

Influence of Physico.Chemical Properties of Root Substrates on the Growth of Mother Plants and the Occurrence of Daughter Plants during the Propagation of 'Maehyang' Strawberry Using a Bag Culture System ('매향' 딸기 번식을 위한 플라스틱 백 재배시 상토 물리.화학성이 모주생육과 자묘 발생에 미치는 영향)

  • Choi, Jong-Myung;Park, Ji-Young;Ko, Kwan-Dal;Lee, Chi-Won W.
    • Korean Journal of Agricultural Science
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    • v.37 no.2
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    • pp.191-197
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    • 2010
  • The objective of this research was to determine the influence of the physical and chemical properties of root substrates used during the production of 'Maehyang' strawberry propaguleson the growth of the mother plants and the rate of daughter plant formation. Plants were cultured in plastic bags containing six different formulations of root substrates composed of: a) 50% coir dust and 50% perlite (5:5 by volume, A), b) 60% coir dust and 40% perlite (6:4, B), c) 70% coir dust and 30% perlite (7:3, C), d) 70% coir dust and 30% coconut chip (7:3 D), e) 60% coir dust and 40% coconut chip (60:40, E), or f) 50% sphagnum peat and 50% vermiculite (50:50, F). All media formulations contained a moderate level of base fertilizers. Physical and chemical properties of each formulation were determined before plant establishment and after 120 days of stock plant culture and runner production. Total porosity (TP) and container capacity (CC) of all substrate formulations were higher than 85% and 55%, respectively, allowing a suitable range of air and water holding characteristics. Formulation F provided the highest TP and CC values among the all substrate modifications evaluated. Substrate formulations A, B, C and F had higher electrical conductivity (EC) and $NO_3{^-}$-N concentrations than formulations D and E, when determined before and after plant culture. Formulations A, B, C, and F, having higher EC readings, also performed better as root substrates thanthe formulations D and E in increasing fresh and dry weights of the runners as well as the production of daughter plants per plant. The 'Maehyang' strawberry plants grown in the formulation F had the highest tissue N content, followed by those grown in substrate B, A, C, or D for 120 days after transplanting. Formulation F also facilitated accumulation of higher tissue phosphorus (P) and copper (Cu) contents compared to other treatments. Results of this experiment suggest that the chemical properties, rather than physical properties, of root substrates had a major influence on the growth of mother plants and the occurrence of healthy daughter plants during the bag-culture phase of propagation.

Void Ratio Evaluation of Unsaturated Soils by Compressional and Shear Waves (압축파와 전단파를 이용한 불포화토의 간극비 산정)

  • Byun, Yong-Hoon;Cho, Se-Hyun;Yoon, Hyung-Koo;Choo, Yun-Wook;Kim, Dong-Su;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.28 no.12
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    • pp.41-51
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    • 2012
  • Soils are commonly unsaturated in the near surface. The stiffness of soils is affected by the amount of air and water. The objective of this study is to evaluate the porosity of the unsaturated soils by using the elastic waves including compressional and shear waves. The elastic waves are measured at different degrees of saturation by controlling the matric suction. Thus, the unsaturated soils are characterized at different levels of the matric suction. Shear and compressional waves are measured by using the bender elements and the piezo disk elements, respectively. Both transducers are installed on the walls of the rectangular cell. The unsaturated soils are prepared by using uniform size sands and silts. Test results show that both compressional and shear wave velocities change according to the matric suction. The elastic modulus, the shear modulus, and the Poisson's ratio are estimated based on the measured elastic wave velocities. In addition, the void ratio of the unsaturated soils estimated using elastic wave velocities matches well with the volume based void ratio. This study demonstrates that the elastic waves can be effectively used for the characterization of unsaturated soils.

Vulnerability Assessment to Urban Thermal Environment for Spatial Planning - A Case Study of Seoul, Korea - (공간계획 활용을 위한 도시 열환경 취약성 평가 연구 - 서울시를 사례로 -)

  • Eum, Jeong-Hee
    • Journal of the Korean Institute of Landscape Architecture
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    • v.44 no.4
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    • pp.109-120
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    • 2016
  • This study aims to assess vulnerability in urban thermal environments of Seoul by using indicators frequently used in previous studies as well as effective indicators for spatial planning like urban and environmental planning. For this purpose, fifteen indicators that influence urban thermal environments such as heat waves, urban heat island effects, and urban micro-climates were identified based on literature reviews. Indicators for presenting urban structure and spatial properties were included; for example, building volume as 'exposure to climate', buildings completed before 1980 as 'sensitivity', and green space areas as 'adaptive capacity'. Among them, twelve indicators were applied to assess vulnerability in urban thermal environments of Seoul by using a GIS spatial analysis combined with fuzzy logic. The results show that the Gangnam area is identified as more vulnerable to a heat environment as compared to the Gangbuk area. In the Gangnam area, Seocho-gu, Gangnam-gu, Dongjak-gu, Yeongdeungpo-gu, Gangseo-gu were relatively high in vulnerability, while Dongdaemun-gu, Gangbuk-gu, Gwangjin-gu, Jungrang-gu were relatively high in the Gangbuk area. Gwanak-gu, Dobong-gu, Eunpyeong-gu, and Nowon-gu, which include forested areas, have low vulnerability in the sectors of 'exposure to climate' and 'sensitivity' due to the impact of Gwanaksan and Bukhansan. However, some areas with high vulnerability like Seocho-gu and Gangnam-gu may have lower vulnerability if the indicator 'status of air conditioning' from the sector of 'adaptive capacity' is used. This study could support the establishment of a practicable thermal environment policy and spatial planning to reduce heat-related risks in the field of urban and environmental planning.

Study on Incineration Behavior of Heavy Oil Fly Ash for Valuable Metal Recovery (유가금속(有價金屬) 회수(回收)를 위한 중유회(重油灰)의 연소거동(燃燒擧動)에 관한 연구(硏究))

  • Choi, Young-Yeon;Nam, Chul-Woo;Kim, Byoung-Gyu
    • Resources Recycling
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    • v.18 no.1
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    • pp.22-29
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    • 2009
  • To design and construct a moving bed stoker incinerator for incineration treatment of the domestic oil fly ash, operating condition and moving bed area of incinerator were determined by performing incinerate experiment of the oil fly ash in the muffle furnace which simulates moving bed stoker incinerator in all conditions. Incineration process of the oil fly ash could be divided into 3 stages, every stage needs the appropriate operating condition for effective incineration. The optimum content of water in the heavy oil fly ash was found to be 20 wt% to prevent the ash from flying and reduce the volume. Science combustion rate of oil fly ash depends on the oxygen content, the incinerator must have a equipment to control the oxygen content in the combustion air. The optimum temperature was $750{\sim}800^{\circ}C$ in order to prevent adhesion to the stocker and evaporation of metal compounds of low melting point. Uniform combustion reaction and acceleration of combustion rate required agitation during the combustion of oil fly ash. The incineration rate was $12.53kg/m^2hr$ and the working area of moving bed incinerator was found to be $60m^2$ to incinerate 18 tons of oil fly ash per day.

A Study on Desorption Efficiency for Polar Solvents Collected on Charcoal Tube (활성탄관에 포집된 극성유기용제의 탈착효율에 관한 연구)

  • Kim, Kyeong-Ran;Paik, Nam-Won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.5 no.1
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    • pp.104-118
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    • 1995
  • This study was performed to evaluate factors affecting desorption of organic solvents collected on charcoal tube and to find out the optimum condition. Desorption efficiency for polar analytes was improved when several polar desorption solvents such as methanol, dimethylformamide(DMF), 2-(2-butoxyethoxy)ethanol were added to carbon disulfide($CS_2$). The best improvement was achieved when 10% dimethylformamide(DMF) in $CS_2$ was used as desorption solvent. During storage of polar analytes, recovery was greatly reduced. Especially, the recovery of cyclohexanone was decreased to 18.1 % after a month storage at $34^{\circ}C$. After two weeks storage, recovery of polar analytes was sharply decreased. Water adsorbed on charcoal interfered the recovery of polar analytes but didn't interfere that one of nonpolar solvent, toluene. When 10% DMF in $CS_2$ was used as desorption solvent, the effect of water on recovery was decreased, comparing with Desorption efficiency increased when analyte loading increased, and usage of 10% DMF in $CS_2$ decreased the loading effect. Increasing volume of desorption solvent was not effective to improve desorption efficiency of analytes when 10% DMF was used. Continuous shaking and sonication is not helpful to increase the desorption efficiency of analytes except cyclohexanone using 10% DMF. When silica gel used as adsorbent, methanol was better desorbent than dimethylsulfoxide. Analytes adsorbed on silica gel showed high recovery in low concentration and less affected by humidity. On the basis of this study, the following conclusions have been drawn. To improve the recovery of polar organic materials in air samples, it is necessary to analyze samples as soon as possible after they were collected. Otherwise, samples must be stored at low temperature. Using two components of desorption solvents, such as 10% DMF in $CS_2$, the effects of loading and humidity decreased for polar analytes such as methyl ethyl ketone and methyl isobutyl ketone. When work place has high humidity with low concentration of polar organic solvents, silica gel can be used as adsorbent, because it produces quantitative recovery for polar analytes at this condition. But it should be noted that high humidity makes breakthrough easy in silica gel samples.

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Introduction of Spring Cultivation of Onions by Adapting the Plug Seedling System in the Middle Region of Korean Peninsula (중부지방에서 플러그 육묘에 의한 양파의 춘파재배 가능성)

  • Lee, Jung-Soo;Seong, Ki-Cheol;Sin, Young-An;Ro, Hee-Myong;Um, Young-Cheol
    • Horticultural Science & Technology
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    • v.18 no.1
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    • pp.9-13
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    • 2000
  • Cultivation of onions in Korean peninsula is so restricted to Southern region, mainly due to inadequate air temperature for the growth of onions in this region. This sometimes resulted in unstable supply of onions. The fluctuation of market prices mainly results from the limited production of onions in such restricted areas. Onions are usually transplanted at the end of fall and cultivated until the beginning of next summer. This study was designed to examine the possibility of extending production region of onions by adopting the plug seedling system, and the effects of plug seedling age, transplanting date, plug cell volume, and variety on the yield of onions were investigated. Transplanting date (Mar. 15 or Apr. 15) did not affect the yield of onions. However, 60-day-old seedlings produced significantly greater bulb yield (107.2 ton/ha) than those of 30- or 90- day-old seedlings. Bulb yields of seedlings raised in 128 and 72 cell trays were 125.0 and 120.8 ton/ha, which were significantly greater than those in other cell trays. Yield of seedlings raised in 406 cell trays was the lowest. Seedlings of mid-late 'Chenjuwhang' yielded 130.5 Ton/ha, which was significantly higher than those of other varieties. Considering the rainy season during early summer, we suggest that seedlings of onions raised for 60 days and transplanted on Mar. 15 should be advantageous in producing of marketable bulbs and that an early 'Yongbongwhang' should be the best variety.

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