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Crystal Chemistry and Paragenesis of Aluminum Sulphates from Mudstones of the Yeonil Group (I): basaluminite, hydrbasaluminite, and metabasaluminite (연일층군 이암에서 산출되는 알루미늄 황산염 광물의 결정화학 및 생성 (I): 배사알루미나팅, 하이드로베사알루미나이트 및 메타배사알루미나이트)

  • 노진환
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.1
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    • pp.1-12
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    • 1998
  • In Pohang area, basaluminite accompanying a little amounts of hydrobasalumnite, super-genetically occurs as whitish cryptocrystalline (2-4 $\mu\textrm{m}$) clay-like aggregates in the vicinity of altered carbonate concretions embedded within mudstones of the Tertiary Yeonil Group. A hydrobasaluminite changed readily into a basaluminite at room temperature in air, and, in turn, into a metabasaluminite when heating to 150$^{\circ}$~30$0^{\circ}C$. For the basaluminite, a monoclinic unit-cellparameters (a=14.845$\AA$, b=10.006$\AA$, c=11.082$\AA$, $\beta$=122.15$^{\circ}$) were calculated by X-ray powder diffraction data. Its basal reflections (001 and 002) are XRD analyses strongly indicate that the aluminum sulphate mineral has a layer structure and, at least, three types of water, i.e., (1) interlayer water (9.0 wt %), (2) crystal water (8.0 wt %), and (3) structural water (19.0 wt %). may present in its lattice. Based on TG-DTG data combined with EDS and IR analyses, a new chemical formula of Al5SO4(OH)134H2O was given to the basaluminite. Field occurrence and stable isotope data ($\delta$18O, $\delta$D, $\delta$34S) for the basaluminite seem to reflect that it was formed by the leached meteoric solution from surrounding mudstones during or after uplifting. An interaction of the acid solution with carbonate concretion and the resultant local neutralization of the fluid rich in Al3+ and SO42- are major controls on the basaluminite formation.

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Experimental Investigation of the Water Droplet Dynamics inside the Simulated PEMFC Single Flow Channel with GDL (GDL을 고려한 고분자전해질형 연료전지 모사 단위 유로 채널에서의 물방울 유동 특성에 대한 실험적인 고찰)

  • Kim, Han-Sang;Ji, Yong-Whi;In, Ji-Hyun;An, Ji-Yong
    • Journal of Hydrogen and New Energy
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    • v.24 no.1
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    • pp.76-83
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    • 2013
  • Polymer electrolyte membrane fuel cells (PEMFCs) are regarded as a promising alternative to replace the existing automotive power sources. To get high performance and long-term durability for PEMFC systems, novel water management is essential. To this end, a comprehensive understanding of dynamics of the liquid water droplets within an operating PEMFC plays an important role. In this work, direct visualization of dynamic behaviors of the water droplet in the ex situ unit flow channel of a PEMFC including gas diffusion layer (GDL) is carried out as one of the fundamental studies for novel water management. Water droplet dynamics such as the movement and growth of liquid water droplets are mainly presented. Effects of GDL characteristics and inlet air flow rate on the water droplet transport and its removal from the flow channel are also discussed. The data obtained in this study can contribute to build up the fundamental operating strategy including balanced water removal capacity for automotive PEMFC systems.

Properties of Physical and Surface Glossing of Exposed Concrete with the Contents of Granulated Blast Furnace Slag (고로슬래그 미분말의 치환율 변화에 따른 노출 콘크리트의 물리 및 표면광택 특성)

  • 한천구;전충근
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.92-99
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    • 2002
  • This paper is Intended to investigate physical properties and surface glossing of exposed concrete incorporating granulated blast furnace slag(BS). According to test results there is no remarkable variations in fluidity and air content with increase of BS, but unit weight shows decline tendency Compressive strength at later age gains considerably due to potential hydraulicity reaction of BS. It shows that drying shrinkage increases. It is found that low W/B, surface coating and high BS content lead to favorable effects on the surface glossing of exposed concrete because of filling effects on the voids of the concrete. It is improved by about 7 % with increase every 10 % of BS content. The effects of form pannel kinds on the improvement of surface glossing are in order for acryl, fancy, steel and wood.

An Evaluation of Atmospheric Environmental Capacity in Daegu (대구지역 대기환경용량 산정에 관한 연구)

  • Park, Myung-Hee;Choi, Geun-Sik;Jung, Woo-Sik;Kim, Hae-Dong;Lee, Joon-Soo
    • Journal of Environmental Science International
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    • v.19 no.10
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    • pp.1271-1281
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    • 2010
  • This study aims to implement the modeling of selected substances for the evaluation of Atmospheric Environmental Capacity by means of the data of 2006 atmospheric pollution substance emissions. As a result, it turned out that the substance with the concentration higher than Atmospheric Environmental standard concentration was NO2, and 17.6% of the total regions researched turned out to exceed the standard concentration. In addition, set was the targeted amount to be reduced in the areas where the upper limit of emission per unit lattice was exceeded, and the model was adopted accordingly. As a result, it turned out that about 80% of the actual emission should be reduced to meet the 2006 Atmospheric Environmental standard over the Daegu. In reality, it is impossible to reduce 80% of the actual emission. Thus, the same ratio of reduction was applied in all of the Daegu regions, and the modeling was applied. The results are as follows: When 30% was reduced, the level went down to 50 ppb, which is as high as 2006 Atmospheric Environmental standard; when 50% was reduced, the level went down to 30 ppb, which is as high as 2007 Atmospheric Environmental standard.

Characteristics of Organic Light-Emitting Diodes using PECCP Langmuir-Blodgett(LB) Film as an Emissive Layer (PECCP LB 박막을 발광층으로 사용한 유기 발광 다이오드의 특성)

  • Lee, Ho-Sik;Lee, Won-Jae;Park, Jong-Wook;Kim, Tae-Wan;Dou--Yol Kang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.111-114
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    • 1999
  • Electroluminescence(EL) devices based on organic thin films have been attracted lots of interests in large-area light-emitting display. In this stuffy, an emissive layer was fabricated using Langmuir-Blodgett(LB) technique in organic light-emitting (OLEDs). This emissive organic material was synthesized and named PECCP[poly(3.6-N-2-ethylhexyl carbazolyl cyanoterephthalidene)] which has a strong electron donor group and an electron acceptor group in main chain repeated unit. This material has good solubility in common organic solvents such as chloroform. THF, etc, and has a good stability in air. The Langmuir-Blodgett(LB) technique has the advantage of precise control of the thickness down to the molecular scale, In particular, by varying the film thickness it is possible to investigate the metal/polymer interface. Optimum conditions for the LB film deposition are usually determined by investigating a relationship between a surface pressure $\pi$ and an effective are A occupied by one molecule on the subphase. The LB films were deposited on an indium-tin-oxide(ITO) glass at a surface pressure of 10 mN/m and dipping speed of 12 mm/min after spreading PECCP solution on distilled water surphase at room temperature, Cell structure was ITO/PECCP LB film/Alq$_3$/Al. We considered PECCP as a hole -transport layer inserted between the emissive layer and ITO. We also used Alq$_3$ as an emissive layer and an electron transport layer. We measured current-voltage(I-V) characteristics, UV/visible absorption, PL spectrum and EL spectrum of the OLEDs.

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오염집약도와 국제경쟁력의 변화: 1993~98

  • Kim, Dong-Seok
    • KDI Journal of Economic Policy
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    • v.24 no.1
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    • pp.113-190
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    • 2002
  • The purpose of this paper is to perform empirical studies on the impact of pollution intensity on international competitiveness using 1993 and 1998 data, and to estimate the change in environmental regulation level faced by the firms during 1993~1998. Collecting relevant data and providing them for further studies in the area are another purposes of the paper. The first method is the regression of various indices of international competitiveness on factor costs, such as labor, capital, R&D and pollution abatement costs. Goal of the regression analysis is to estimate the scarcity and comparative advantage effect of each production factor, especially environmental resource. Regression results show that those industries which employ more environmental resource have higher comparative advantage in both years, which implies that Korean firms are endowed with abundant environmental resource compared to other countries. The second method is to compute the relative scarcity indices(HOVL indices) of production factors, proposed by Leamer based on Vanek's generalized Hecksher-Ohlin Theorem. This method estimates the relative scarcity of production factors by computing factor costs embodied in import and export of commodities. This method shows similar results as the regression method; i.e., trade pattern of production factors implies that the manufacturing sector in Korea is endowed with abundant environmental resource compared to other countries. Considering population density, water resource endowment, intensity of economic activity per unit area and current air and water pollution levels, it is evident that Korea is never endowed with abundant environmental resource compared to other countries. Then the abundance of environmental resource revealed by the trade patterns of commodities and production factors implies that Korea's environmental regulation level is excessively generous compared to environmental capacity, and that this increased the environmental resource endowment supplied to firms and thus distorted the inter-industry comparative advantages. Both regression and HOVL methods, on the other hand, show that overall environmental regulation level faced by the firms has been strengthened during 1993~1998.

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Adaptive Blowing Control Algorithm for Autonomous Control of Underwater Flight Vehicle (수중 비행체의 자율제어를 위한 적응 부상 제어 알고리즘)

  • Kim, Hyun-Sik
    • Journal of the Korean Institute of Intelligent Systems
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    • v.18 no.4
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    • pp.482-487
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    • 2008
  • In case of flooding, the underwater flight vehicle (UFV) executes the blowing by blowing ballast tanks off using high pressure air (HPA), while it also uses control planes and a propulsion unit to reduce the overshoot depth caused by a flooding and blowing sequence. However, the conventional whole HPA blow-off method lets the body on the surface after blowing despite slight flooding. This results in the unnecessary mission failure or body exposure. Therefore, it is necessary to keep the body at the near surface by the blowing control while reducing the overshoot depth. To solve this problem, an adaptive blowing control algorithm, which is based on the decomposition method expanding the expert knowledge in depth control and the adaptive method using fuzzy basis function expansion (FBFE), is proposed. To verify the performance of the proposed algorithm, the blowing control of UFV is performed. Simulation results show that the proposed algorithm effectively solves the problems in the UFV blowing control system online.

An Analysis of Voltage Characteristics for LC Resonant Frequency Band of Capacitor Compensation According to Moving of Electrical Separation Equipment of AF Track Circuit (AF궤도회로의 전기적 구분 장치 설치이전에 따른 커패시터 보상으로 LC공진 주파수 대역의 전압특성 분석)

  • Won, Seo-Yeon;Choi, Jae-Sik;Park, Hun-Jue;Kim, Hie-Sik
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.8
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    • pp.1466-1477
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    • 2016
  • This paper analyzes the electrical characteristic such as the impedance(Z), inductance(L), and cable resistance($R_p$) according to the change of cable length in order to move the electrical sorting device for distinguishing between AF non-insulated track circuits from the center of railway to outside railway. The simulation is performed to check the voltage difference between the voltage of sender and the voltage of receiver and determine the possibility of the voltage restoration availability in the frequency filter band through the capacitor compensation. It was applied to the results of the simulation to the sorting devices installed in the actual field. It is proved the availability by checking the measured voltage characteristic according to the capacitor compensating change of $10{\mu}F$ and $16{\mu}F$ before, and after the length of cable is increased with 6 meters. Through this, the prevention of breakdown and damage to facilities and the prevention the safety-related accidents of line workers from the train are expected according to moving the sorting devices of AR non-insulated track circuits to outside railway.

A Study on Plate & Shell type Evaporator in HVAC System for Offshore Plant (해양플랜트 HVAC 시스템용 플레이트·쉘 타입 증발기에 관한 연구)

  • Park, Jae-Hong
    • Journal of the Korean Institute of Gas
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    • v.24 no.1
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    • pp.33-40
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    • 2020
  • Chiller systems which have better temperature stability than Direction expansion coils are often used as condensing units in HVAC systems for offshore plants. Large capacity compressors and electronic expansion valves in chiller systems are mostly imported, and the size of a chiller system depends on heat exchangers such as evaporators and condensers which are locally produced. Due to limited space in the offshore plants, shipyards are demanding manufacturers to make equipment compact. In this paper, a shell & tube heat exchanger, which is used as an evaporator in the conventional flooded chiller system, is replaced by a newly developed compact plate & shell heat exchanger. The main development process of the plate & shell heat exchanger is introduced, and its performances were experimentally evaluated with a real flooded chiller system, and the results are presented.

Floods and Flood Warning in New Zealand

  • Doyle, Martin
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.20-25
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    • 2012
  • New Zealand suffers from regular floods, these being the most common source of insurance claims for damage from natural hazard events in the country. This paper describes the origin and distribution of the largest floods in New Zealand, and describes the systems used to monitor and predict floods. In New Zealand, broad-scale heavy rainfall (and flooding), is the result of warm moist air flowing out from the tropics into the mid-latitudes. There is no monsoon in New Zealand. The terrain has a substantial influence on the distribution of rainfall, with the largest annual totals occurring near the South Island's Southern Alps, the highest mountains in the country. The orographic effect here is extreme, with 3km of elevation gained over a 20km distance from the coast. Across New Zealand, short duration high intensity rainfall from thunderstorms also causes flooding in urban areas and small catchments. Forecasts of severe weather are provided by the New Zealand MetService, a Government owned company. MetService uses global weather models and a number of limited-area weather models to provide warnings and data streams of predicted rainfall to local Councils. Flood monitoring, prediction and warning are carried out by 16 local Councils. All Councils collect their own rainfall and river flow data, and a variety of prediction methods are utilized. These range from experienced staff making intuitive decisions based on previous effects of heavy rain, to hydrological models linked to outputs from MetService weather prediction models. No operational hydrological models are linked to weather radar in New Zealand. Councils provide warnings to Civil Defence Emergency Management, and also directly to farmers and other occupiers of flood prone areas. Warnings are distributed by email, text message and automated voice systems. A nation-wide hydrological model is also operated by NIWA, a Government-owned research institute. It is linked to a single high resolution weather model which runs on a super computer. The NIWA model does not provide public forecasts. The rivers with the greatest flood flows are shown, and these are ranked in terms of peak specific discharge. It can be seen that of the largest floods occur on the West Coast of the South Island, and the greatest flows per unit area are also found in this location.

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