• Journal of Soil and Groundwater Environment
• /
• v.22 no.6
• /
• pp.22-28
• /
• 2017

The accuracy of analytical results in response to the use of different additives ($NH_4Cl$, KCl, $LaCl_3$) and oxidant gases was evaluated and compared by using Atomic Absorption Spectrometry (AAS). Identification of spectroscopic interferences and possible improvements in Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) analysis were also discussed. The average accuracies of total chromium using Certified Reference Materials (CRMs) were found to be 72.1~94.2% in air/acetylene flame condition by AAS, and they were improved to 100.5~110.5% when the oxidants was changed to nitrous oxide rather than adding the additives. The field samples showed similar trends to CRMs, but chromium concentrations were highly variable depending on analytical conditions. The average accuracies using CRMs were estimated to be 89.3~166.1% by ICP-AES, and improved to below 121.7% after eliminating iron interference. Field samples with low chromium and high iron concentration were measured to be > 30% lower in total chromium concentrations by ICP-AES than AAS in nitrous oxide/acetylene flame. Total chromium concentrations in soil could be analyzed with better accuracy under nitrous oxide/acetylene flame by AAS because it was more effective to increase the temperature of the flame than to eliminate the chemical interference for maximizing atomization of chromium. When using ICP-AES, interference substances, total chromium levels, and analytical conditions should be also considered.

• Journal of ILASS-Korea
• /
• v.23 no.4
• /
• pp.192-204
• /
• 2018

In this study, a 3D CFD analysis method for the combustion process was established for a low calorific value syngas-diesel dual-fuel engine operating under very lean fuel-air mixture condition. Also, the accuracy of computational analysis was evaluated by comparing the experimental results with the computed ones. To simulate the combustion for the dual-fuel engine, a new dual-fuel chemical kinetics set was used that was constituted by merging two verified chemical kinetic sets: n-heptane (173 species) for diesel and Gri-mech 3.0 (53 species) for syngas. For dual-fuel mode operations, the early stage of combustion was dominated by the fuel burning inside or near the spray plume. After which, the flame propagated into the syngas in the piston bowl and then proceeded toward the syngas in the squish zone. With the baseline injection system and piston shape, a significant amount of unburned syngas was discharged. To solve this problem, effects of the injection parameters and piston shape on combustion characteristics were analyzed by calculation. The change in injection variables toward increasing the spray plume volume or the penetration length were effective to cause fast burning in the vicinity of TDC by widening the spatial distribution of diesel acting as a seed of auto-ignition. As a result, the unburned syngas fraction was reduced. Changing the piston shape with the shallow depth of the piston bowl and 20% squish area ratio had a significant effect on the combustion pattern and lessened the unburned syngas fraction by half.

• Journal of ILASS-Korea
• /
• v.24 no.1
• /
• pp.35-42
• /
• 2019

Syngas is widely produced by incomplete combustion of coal, water vapor, and air (oxygen) in a high-temperature/high-pressure gasifier through a coal-gasification process for power generation. In this study, a simulation syngas which was mainly composed of $H_2$, CO, $CO_2$, and $N_2$ was fueled with diesel. A modified single cylinder compression ignition (CI) engine is equipped with intake port syngas supply system and mechanical diesel direct injection system for dual fuel combustion. Combustion and emission characteristics of the engine were investigated by applying various syngas composition ratios and compression ratios. Diesel fuel injection timing was optimized to increase indicated thermal efficiency (ITE) at the engine speed 1,800 rpm and part load net indicated mean effective pressure ($IMEP_{net}$) 2 to 5 bar. ITE of the engine increased with the $H_2$ concentration, compression ratio and engine load. With 45% of $H_2$ concentration, compression ratio 17.1 and $IMEP_{net}$ 5 bar, ITE of 41.5% was achieved, which is equivalent to that of only diesel fuel operation.

• Journal of ILASS-Korea
• /
• v.27 no.3
• /
• pp.117-125
• /
• 2022

This study examines whether engine fuel efficiency is improved by optimization of the exhaust valve timing in a state where the intake valve timing has been optimized in a small turbo gasoline engine that has intake cams and exhaust cams with fixed valve opening periods. When the exhaust valve is opened late, the expansion stroke is longer, and the efficiency can be improved. A 2-cylinder turbo gasoline engine with 0.8 liters of displacement and an MPI (Multi Point Injection) fuel system was used. The engine was operated at 1,500 and 3,000 rpm, and the load conditions included a partial load of 50 N·m and a high load of 70 N·m. Data was recorded as the exhaust valve timing was controlled, and this was used to calculate the efficiency of combustion using a heat release, the fuel conversion efficiency, and the pumping loss. Results and the hydrocarbon concentrations in the exhaust gas were compared for each condition. Experiment results confirmed that additional fuel efficiency improvements are possible through exhaust valve timing control at 1,500 rpm and 50 N·m. However, in other operating conditions, fuel efficiency improvements could not be obtained through exhaust valve timing control because cases where the pumping loss and fuel/air mixture slip increased when the exhaust valve timing changed and the fuel efficiency declined.

• Journal of ILASS-Korea
• /
• v.29 no.2
• /
• pp.68-74
• /
• 2024

As awareness of environmental pollution problems increases worldwide, interest in air pollutants is increasing. In particular, NOx and PM, which are major pollutants in diesel vehicles, are contributing significantly to emissions. As a result, its importance is increasing. In this study, based on research results applied to large diesel vehicles, the problem of natural regeneration caused by low exhaust gas temperature during low speed and low load operation is solved by applying a complex regeneration DPF that is not affected by temperature conditions to small diesel vehicles. The feasibility of application to small diesel vehicles was reviewed by measuring the emission reduction efficiency. As a result of the engine test, the power reduction rate and fuel consumption rate before and after device installation under full load conditions were 2.9% decrease and 3.5% increase, respectively, satisfying the standard for a 5% reduction, and as a result of the regeneration equilibrium temperature (BPT) test, the regeneration temperature was 310℃. appeared at the level. The reduction efficiency test results for the actual vehicle durability test equipment showed 97.3% PM, 51.0% CO, and 31.1% HC, while the city commuter vehicle had PM 97.5%, CO 61.7%, HC 40.0%, and the school bus vehicle had PM 96.8%, CO 44.4%, HC 34.3%, and low-speed logistics vehicles showed a reduction efficiency of 98.2% for PM, 36.0% for CO, and 45.7% for HC. Based on the results of this study, in the future, it is necessary to secure DPF technology suitable for all vehicle types through actual vehicle application research on temperature condition-insensitive composite regenerative DPF for medium-sized vehicles.

• Journal of the Korean Society of Food Science and Nutrition
• /
• v.44 no.7
• /
• pp.1064-1071
• /
• 2015

Viscous fermented red ginseng extracts were dried and coated using a fluidized bed coater to increase convenience and consumer acceptance. The methods for making spherical granules of fermented red ginseng extracts with increasing convenience were established by using indigestible dextrin. Spherical granules of fermented red ginseng extracts with increasing convenience were made by mixing indigestible dextrin at 40% (40% IDD), 50% (50% IDD), and 60% (60% IDD) versus the soluble solid content of fermented red ginseng extracts. Spherical granules of fermented red ginseng extracts showed less angle of repose than powder of fermented red ginseng extracts. This means that spherical granules of fermented red ginseng extracts had good fluency with increased convenience. The more indigestible dextrin showed higher yields. Although 50% IDD showed less yield than 60% IDD, 50% IDD was the best mixing ratio for making spherical granules of fermented red ginseng extracts, as fermented red ginseng extracts is known as a healthy food. The optimized operation conditions of the fluidized bed coater for making 50% IDD were feeding rate 0.54 mL/min, atomization air pressure 2.15 bar, and product temperature $83.03^{\circ}C$.