• Title/Summary/Keyword: AgO

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A Study on Characteristic of Superconductivity and Microstructure of $Y_1Ba_2Cu_3O_{7-y}$-Ag ($Y_1Ba_2Cu_3O_{7-y}$-Ag의 초전도성과 미세구조의 특성 연구)

  • Kim, Chae-Ok;Park, Jeong-Su;Yu, Deok-Su
    • Korean Journal of Materials Research
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    • v.5 no.7
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    • pp.786-793
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    • 1995
  • Ag-doped $Y_1$Ba$_2$Cu$_3$O$_{7-y}$ samples have been prepared by solid state reaction. High-Tc super conductivity, microstructure and mechanical property of the Ag-doped $Y_1$Ba$_2$Cu$_3$O$_{7-y}$ samples have been studied. As the Ag content increased, the grain size of $Y_1$Ba$_2$Cu$_3$O$_{7-y}$, increased and connectivity between the grains was improved, and the sample becomed denser and harder than the undoped. From the result, it is concluded that Ag addition reduced weak link and weak coupling between grains and led to the strong coupling. Furthermore, the anisotropy of crytstal structure was decreased and thermal stability, mechanical property of $Y_1$Ba$_2$Cu$_3$O$_{7-y}$-Ag were improved.mproved.

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Effect of the Alloying Elements in Ag-Cu-Zr-X Brazing Alloy on the Microstructure and the Bond Strength of $Al_2O_3$/Ni-Cr Steel Brazed Joint (알루미나/니켈크롬강 접합체의 미세조직 및 접합강도에 미치는 Ag-Cu-Zr-X 브레이징 합금성분의 영향)

  • Kim, Jong-Heon;Yoo, Yeon-Chul
    • Transactions of Materials Processing
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    • v.7 no.5
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    • pp.465-473
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    • 1998
  • The effect of alloying elements of Ag-Cu-Zr-X brazing alloy on the microstructure and the bond strength of $Al_2O_3/Ni-Cr$ brazed steel joint was investigated. The reaction layer, $ZrO_2$ (a=5.146 ${\AA}$ , b=5.213 ${\AA}$ , c=5.311 ${\AA}$ )was formed at the interface of $Al_2O_3/Ni-Cr$ steel joint by the redox reaction between alumina and Zr. The addition of An and Al to the Ag-Cu-Zr brazing alloy gave rise to changes in the thickness of the reaction product layer and the morphology of the brazement. Sn caused the segregation of Zr was decreased b Al the $ZrO_2$ layer formed at the Ag-Cu-Zr-Al alloy was thinner than that of $ZrO_2$ formed at the Ag-Cu-Zr-An alloy. The fracture shear strength was strongly dependent on the microstructure of the brazement. Brazing with Ag-Cu-Zr-Sn alloy resulted in a better bond strength than with Ag-Cu-Zr or Ag-Cu-Zr-Al alloy.

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The Effect of the Zn contents on Rapidly Solidified Ag-Zn Electric Contact Materials. (급속응고한 Ag-Zn계 전기접점재료에 미치는 Zn함량의 영향)

  • Kim, Jong Kyu;Jang, Dae Jung;Ju, Kwang Il;Lee, Eun Ho;Um, Seung Yeul;Nam, Tae Woon
    • Korean Journal of Metals and Materials
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    • v.46 no.7
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    • pp.443-448
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    • 2008
  • Contact materials are used in many electrical devices. Ag-Cd alloy has been widely used in electrical part, because Ag-Cd alloy has a good wear resistance and stable contact resistance. But nowadays Ag-Cd alloy isn't being used because of environmental challenges. Currently new research is being done on ($Ag-SnO_2$ and $Ag-SnO_2-In_2O_3$) as an alternative solution to fix any remainly environmental challenges. However $In_2O_3$ is more expensive and Ag-Sn alloy has low wear resistance. According to our research data Zn has a similar physical and chemical property. In this work, so we changed and optimized the Zn oxide to over 4 and added Sn oxide ratio 0.5, 1.0, 1.5wt%. Conclusions from the data recorded from the experiment of $Ag-ZnO-SnO_2$ are as follows.

Suppressed Sheet Resistance of Ag Nanostructure Films by O2 Plasma Treatment (O2 플라즈마 처리를 통한 Ag 나노구조체 필름의 면저항 저감)

  • Kim, Wonkyung;Roh, Jong Wook
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.3
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    • pp.37-41
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    • 2019
  • Sheet resistance reduction in the Ag nanowire (NW) coated films is accomplished with slight improvement of optical properties for the application of transparent conducting electrodes by using $O_2$ plasma treatment. The sheet resistance was optimized after 30 seconds $O_2$ plasma treatment, showing the 27 % of maximum decrease of sheet resistance. It is found that the $O_2$ plasma treatment get rid of the residual organic materials at the junction of Ag NWs. However, the Ag NWs may be also snapped by the excessive $O_2$ plasma treatment can showing the collapses of Ag NWs networks. Furthermore, the optical properties such as optical transmittance and haze were monotonically improved with the $O_2$ plasma treatment time until 90 seconds.

Effect of Annealing Temperature on the Low Emissivity of TiO2/Ag/TiO2 Films (열처리 온도에 따른 TiO2/Ag/TiO2 박막의 근적외선 반사 특성 변화)

  • Kim, So-young;Moon, Hyun-joo;Kim, Daeil
    • Journal of the Korean Society for Heat Treatment
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    • v.28 no.3
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    • pp.134-138
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    • 2015
  • Ag intermediated $TiO_2$ films were deposited by RF and DC magnetron sputtering and then vacuum annealed at 100, 200 and $300^{\circ}C$ for 30 minutes to investigate the effect of annealing temperature on the structural and optical properties of the films. For all depositions, the thickness of the $TiO_2$ and Ag films were kept constant at 24 and 15 nm by controlling the deposition time. As-deposited $TiO_2/Ag/TiO_2$ trilayer films have a weak crystalline and an optical reflectance in a near infrared wavelength region of 77.8%, while the films annealed at $300^{\circ}C$ show the polycrystalline structure and an increased mean optical reflectance of 80.4%. From the experimental results, it can be concluded that increasing the annealing temperature enhanced the structural and optical properties of the $TiO_2/Ag/TiO_2$ films.

Electrical and optical properties of Ag/ZnO multilayer thin film by the FTS (FTS법으로 제작한 Ag/ZnO 박막의 전기적, 광학적 특성)

  • Rim, Y.S.;Kim, S.M.;Son, I.H.;Lee, W.J.;Choi, M.K.;Kim, K.H.
    • Journal of the Korean Vacuum Society
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    • v.17 no.2
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    • pp.102-108
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    • 2008
  • We have studied the properties of Ag/undoped ZnO (ZnO) multilayer thin films deposited on glass substrate by the facing targets sputtering method. In an attempt to find out the optimum conditions of the Ag thin film, which would be coated on the ZnO thin film, we investigated the changes of sheet resistance, transmittance and surface morphology as a function of deposition times and the substrate temperature. The electrical and optical characteristics of Ag/ZnO multilayers were evaluated by a four-point probe, a UV/VIS spectrometer with a spectral range of 390-770 nm, a X-ray Diffractometer (XRD), an atomic force microscope (AFM) and a Field Emission Scanning Electron Microscope (SEM), respectively. We were able to prepare the Ag/ZnO multilayer thin film with sheet resistance of 9.25 $\Omega/sq.$ and transmittance of over 80% at 550nm.

A Study on the Removal of Ag(I) in Water Using $TiO_2$ Photocatalysis ($TiO_2$ 광촉매반응을 이용한 수중의 은이온 제거에 관한 연구)

  • 김현용;조일형;양원호;김민호;이홍근
    • Journal of environmental and Sanitary engineering
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    • v.15 no.2
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    • pp.58-64
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    • 2000
  • The photocatalytic removal of Ag(I) in water by $TiO_2$ at a various conditions, which are initial Ag(I) concentration, circulation flow rate, $TiO_2$ dosage and methanol concentration, was studied. A continuous flow system with a circular type reactor of the TiO2 suspensions with UV light through an photoreactor column was applied. The major results of this study were as follows; 1. First order kinetics was observed from the result at different initial concentration of Ag(I). As the initial Ag(I) concentration was incereased, the reaction rate was decreased. 2. The removal efficiency of Ag(I) increased with increasing the circulation flow rate and $TiO_2$ dosage. However, over $4{\ell}/min$ of circulation flow rate and $1.5g/{\ell}$ of $TiO_2$ dosage, increasing of the efficiency reached a plateau. 3. The addition of methanol as hole scavenger enhanced the removal efficiency of Ag(I) but the removal efficiency reached a plateau over some level of methanol. 4. It was found that $TiO_2$ photocatalysis was effective method to remove of Ag(I) from aqueous solution.

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Oxidation Behavior of Ag-Cu-Tio Brazing Alloys (Ag-Cu-Ti 브레이징 합금의 산화거동)

  • 우지호;이동복;장희석;박상환
    • Journal of the Korean Ceramic Society
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    • v.35 no.1
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    • pp.55-65
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    • 1998
  • The oxidation behavior of Ag-36.8a%Cu-7.4at%Ti alloy brazed on Si3N4 substrate was investigated at 400, 500 and 600$^{\circ}C$ in air. Under this experimental condition Si3N4 and Ag were not oxidized whereas Cu and Ti among the brazing alloy components were oxidizied obeying the parabolic oxidation rate law. The activation energy of oxidation was found to be 80kj/ mol which was smaller than that of pure Cu owing to the presence of oxygen active element of Ti. The outer oxide scale formed from the initial oxidation state was always composed of Cu oxides which were known to be growing by the outward diffusion of Cu ions. As the oxidation progressed the concentration gradient occurred due to the continuous consumption of Cu as Cu oxides and consequently build-up of an Ag-enriched layer below the Cu oxides resulted in the formation of multiple oxide scales composed of Cu oxide (CuO) /Ag-enriched layer/Cu oxide (Cu2O) /Ag-enriched layer. Also the inward diffusing of oxygen through Cu oxide and Ag-enriched layers led to the formation of internal oxides of TiO2.

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Improved Thermal Stability of Ag Nanowire Heaters with ZnO Layer (ZnO를 이용한 은 나노와이어 히터의 열 안정성 향상)

  • Choi, Wonjung;Jo, Sungjin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.8
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    • pp.530-534
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    • 2017
  • Transparent film heaters employing silver nanowires (Ag NWs) have attracted increasing attention because of their widespread applications. However, the low thermal resistance of Ag NWs limits the maximum operating temperature of the Ag NW film heater. In this study, Ag NW film heaters with high mechanical and thermal stability were successfully developed. The thermal power-out characteristics of the Ag NW heaters were investigated as a function of the Ag NW density. The results revealed that the prepared flexible Ag NW heater possessed high thermal stability over $190^{\circ}C$ owing to ZnO encapsulation. This indicates that the Ag NW film with excellent thermal stability have remarkably high potential for use as electrodes in film heaters operating at high temperatures.

Magnetic properties of ferromagnetic-antiferromagnetic bi-layers with different spin configuration

  • Kim, Won-Dong;Park, Ju-Sang;Hwang, Chan-Yong;Wu, J.;Qiu, Z.Q.;Park, Myeong-Gyu;Kim, Jae-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.304-304
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    • 2011
  • We investigated the effect of different spin direction of anti-ferromagnetic layer on the magnetic properties of ferromagnetic layer in Fe-NiO and Fe-CoO bi-layer systems. For Fe-NiO system, we prepared the clean MgO(001) surface half-covered with 20 nm Ag films as a substrate for magnetic layers. Then we grew NiO wedge layers on the substrate, and added 8 monolayer(ML) Fe layers on the wedge layer. We examined magnetic properties of the bi-layer system using the surface magnetic optical Kerr effect(SMOKE) and X-ray magnetic linear dichroism(XMLD). From SMOKE measurement we observed the coercivity enhancement due to the set-up of anti-ferromagnetic order of NiO films in both of the Fe/NiO/MgO(001) and Fe/NiO/Ag/MgO(001) system. The most remarkable results in our observation is that the coercivity enhancement of Fe/NiO/Ag/MgO(001) is much larger than that of Fe/NiO/MgO(001). XMLD experiments confirmed the out-of-plane spin direction of NiO layers in Fe/NiO/MgO(001) and in-plane spin-direction of NiO layers in Fe/NiO/Ag/MgO(001), and we concluded that the origin of large enhancement of coercivity is due to the strong parallel coupling between Fe layers and NiO layers. We also confirmed that this strong parallel coupling maintained across the thin Ag layer inserted between Fe and NiO layers. For Fe-CoO system, we prepared Fe/CoO/Ag(001) and Fe/CoO/MnO(001) systems and observed much larger coercivity enhancement in Fe/CoO/Ag(001).

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