• Title/Summary/Keyword: Ag sintering

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The Effects of Sintering Temperature of Organic Ag Complex on the Photoluminescence Characteristics of MEH-PPV (유기 은(Ag) 화합물의 소결 온도가 MEH-PPV의 PL특성에 미치는 영향)

  • Kang, Min-Ki;Moon, Dae-Gyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.328-329
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    • 2009
  • This paper presents the effect of organic Ag complex sintering temperature on the MEH-PPV photoluminescence (PL) properties. MEH-PPV and organic Ag complex was coated on the glass substrate by spin coating method. The coated Ag complex was sintered in an air atmosphere. The sintering temperature was varied from 100 to $200^{\circ}C$ and sintering time was 5 min. The Ag film sintered at temperature higher than $120^{\circ}C$ shows very low sheet resistance less than $0.5\;{\Omega}{/\square}$. The coated MEH-PPV measure photoluminescence (PL) intensity at 580 nm. The PL peak was shifted to the higher wavelength with increasing the sintering temperature.

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Study on the characteristics of transpatent electronic Ag (20%) ink by sintering conditions (투명전자잉크 Ag(20%)의 소성조건에 따른 특성 연구)

  • Kang, Min-Ki;Moon, Dae-Gyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04a
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    • pp.78-79
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    • 2009
  • We have investigated low temperature sintering characteristics of organic Ag complex. Organic Ag complex was coated on the glass substrate by spin coating method. The coated Ag complex was sintered in an air atmosphere. The sintering temperature was varied from 30 to $80^{\circ}C$ and sintering time was varied from 1 to 228 hour. The sheet resistance was abruptly changed at $80^{\circ}C$-6h, $65^{\circ}C$-24h, $30^{\circ}C$-228 hour and the thickness of the coated film was significantly decreased. The sheet resistance of Ag films were about $0.53\;{\Omega}/{\square}$ at the $80^{\circ}C$ - 12hour.

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The Influence of Production Process Parameters on Properties W-Ag, Mo-Ag Composites

  • Lezanski, Jan;Madej, Marcin
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1200-1201
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    • 2006
  • Attempts have been made to describe the influence of production process parameters on the microstructure and properties of W-Ag and Mo-Ag composites. The compositions of powder mixtures are W+30% Ag and Mo+30%Ag. Silver additions assists densification during sintering by a liquid phase sintering process. The main goal of this work is to compare properties and microstructure of as-sintered and as-infiltrated composites.

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Low Temperature Sintering Characteristics of Organic Ag Complex (유기 은 착화합물의 저온 소성 특성)

  • Kang, Min-Ki;Suh, Won-Gyu;Moon, Dae-Gyu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.431-432
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    • 2008
  • We have investigated low temperature sintering characteristics of organic Ag complex. Organic Ag complex was coated on the glass substrate by spin coating method. The coated Ag complex was sintered in an air atmosphere. The sintering temperature was varied from 100 to $300^{\circ}C$ and sintering time was varied from 1 to 4 min. The thickness of the coated film was significantly decreased as the film was sintered at the temperature between 110 and $120^{\circ}C$. The sintered Ag film at temperature higher than $115^{\circ}C$ shows very low sheet resistance less than 1 ${\Omega}{/\square}$.

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Sintering Behavior of Ag-Ni Electrode Powder with Core-shell Structure

  • Kim, Kyung Ho;Koo, Jun-Mo;Ryu, Sung-Soo;Yoon, Sang Hun;Han, Yoon Soo
    • Journal of the Korean institute of surface engineering
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    • v.49 no.6
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    • pp.507-512
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    • 2016
  • Expensive silver powder is used to form electrodes in most IT equipment, and recently, many attempts have been made to lower manufacturing costs by developing powders with Ag-Ni or Ag-Cu core-shell structures. This study examined the sintering behavior of Ag-Ni electrode powder with a core-shell structure for silicon solar cell with high energy efficiency. The electrode powder was found to have a surface similar to pure Ag powder, and cross-sectional analysis revealed that Ag was uniformly coated on Ni powder. Each electrode was formed by sintering in the range of $500^{\circ}C$ to $800^{\circ}C$, and the specimen sintered at $600^{\circ}C$ had the lowest sheet resistance of $5.5m{\Omega}/{\Box}$, which is about two times greater than that of pure Ag. The microstructures of electrodes formed at varying sintering temperatures were examined to determine why sheet resistance showed a minimum value at $600^{\circ}C$. The electrode formed at $600^{\circ}C$ had the best Ag connectivity, and thus provided a better path for the flow of electrons.

Enhancement of Electrical Conductivity for Ag Grid using Electrical Sintering Method (정전류 전기 소결법을 이용한 Ag 전극 배선의 전도성 향상)

  • Hwang, Jun Y.;Moon, Y.J.;Lee, S.H.;Kang, K.;Kang, H.;Cho, Y.J.;Moon, S.J.
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.114.1-114.1
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    • 2011
  • Electrical sintering of the front electrode for crystalline silicon solar cells was performed applying a constant DC current to the printed lines. Conducting lines were printed on glass substrate by a drop-on-demand (DOD) inkjet printer and silver nanoparticle ink. Specific resistance and microstructure of sintered silver lines and were measured with varying DC current. To find the relation between temperature increase with changing applied current and specific resistance, temperature elevation was also calculated. Sintering process finished within a few milliseconds. Increasing applied DC current, specific resistance decreased and grain size increased after sintering. Achieved minimum specific resistance is approximately 1.7 times higher than specific resistance of the bulk silver.

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Improving Conductivity of Metal Grids by Controlling Sintering Process (배선 함몰 전극의 배선 소결공정 최적화에 따른 전기적 특성 향상)

  • Ahn, Wonmin;Jung, Sunghoon;Kim, Do-Geun
    • Journal of the Korean institute of surface engineering
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    • v.48 no.4
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    • pp.158-162
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    • 2015
  • To substitute indium tin oxide (ITO), many substituents have been studied such as metal nanowires, carbon based materials, 2D materials, and conducting polymers. These materials are not good enough to apply to an electrode because theses exhibit relatively high resistance. So metal grids are required as an additionalelectrode to improve the conductivities of substituents. The metal grids were printed by electrohydrodynamic printing system using Ag nanoparticle based ink. The Ag grids showed high uniformity and the line width was about $10{\mu}m$. The Ag nanoparticles are surrounded by dispersants such as unimolecular and polymer to prevent aggregation between Ag nanoparticles. The dispersants lead to low conductivity of Ag grids. Thus, the sintering process of Ag nanoparticles is strongly recommended to remove dispersants and connect each nanoparticles. For sintering process, the interface and microstructure of the Ag grid were controlled in 1.0 torr Ar atmosphere at aound $400^{\circ}C$ of temperature. From the sintering process, the uniformity of the Ag grid was improved and the defects on the Ag grids were reduced. As a result, the resistivity of Ag grid was greatly reduced up to $5.03({\pm}0.10){\times}10^{-6}{\Omega}{\cdot}cm$. The metal grids embedded substrates containing low pressure Ar sintered Ag grids showed 90.4% of transmittance in visible range with $0.43{\Omega}/{\square}$ of sheet resistance.

Fabrication of Low Temperature Cofired Ceramic (LTCC) Chip Couplers for High Frequencies ; II. Effect of Sintering Process on Ag Diffusion (고주파용 저온 동시소성 세라믹(LTCC)칩 커플러 제조: II. Ag 이온 확산에 대한 소결공정의 영향)

  • 이선우;김경훈;심광보;구기덕
    • Journal of the Korean Ceramic Society
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    • v.36 no.5
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    • pp.490-496
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    • 1999
  • The sintering behavior of LTCC (low temperature cofired ceramics) chip couplers was investigated in relation with Ag diffusion at the interface of glass ceramic substrate-Ag electrode. Sintering temperature was in the range of 825$^{\circ}C$-975$^{\circ}C$. The commercial green sheet and silver electrode were used. Below 875$^{\circ}C$ the diffusion of the Ag ion into the substrate and the penetration of glassy phases into the electrode occurred due to an increase of fluidity. Thus the lectrode line was severely deformed and damaged. At 975$^{\circ}C$ the transformation of crystalline phases into glassy phases and the melting of the Ag electrode resulted in the diffusion of the considerable amount of Ag ions.

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Effect of Frit and Sintering Conditions on the Microstructure and Electrical Property in Ag and Ag/Pd Thick Film Conductors (프릿트 및 소결조건이 Ag 및 Ag/Pd계 후막도체의 미세구조와 전기적성질에 미치는 영향)

  • 구본급;김호기
    • Journal of the Korean Ceramic Society
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    • v.25 no.6
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    • pp.623-630
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    • 1988
  • As a function of the composition and content of frit, the electrical property of Ag and Ag/Pd thick film conductors were investigated with microstructure. With increasing sintering temperature in Ag-frit thick film conductors, electrical sheet resistivity decreased, but again increased above 80$0^{\circ}C$. And when frit contents is 5wt%, compact and homogenious microstructure can be obtained, then electrical sheet resistivity has minimum value. In Ag/Pd-frit film conductor, the electrical sheet resistivity decreased with increasing sintering temperature. The system which having frit with low softing point has lower sheet resistivity then to add high softening point frit.

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Evaluation of Fe-Cr Systems Metallic Interconnectorby Spark Plasma Sintering (방전플라즈마 소결법을 이용한 Fe-Cr계 금속 연결재의 특성 평가)

  • Chang, Se-Hun;Hong, Ji-Min;Choi, Se-Weon;Kim, Hwi-Jun;Ahn, Jung-Ho;Oh, Ik-Hyun
    • Korean Journal of Materials Research
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    • v.17 no.8
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    • pp.397-401
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    • 2007
  • Fe based SOFC(Solid Oxide Fuel Cell) interconnector was fabricated by using the spark plasma sintering process and its microstructure and mechanical properties were investigated in this study. To fabricate the interconnector, the Fe-26Cr powder was mixed with the Ag (5, 10, 20wt.%) particles. In the Fe-26Cr-Ag sintered bodies, the Ag particles were almost dispersed at the grain boundary of the Fe-26Cr. The sintered bodies have the density of 87.2-97.5%, the density increases with increasing Ag content at sintering temperature of $850^{\circ}C$. Also, the compressive yield strength increases with increasing Ag content at the same sintering temperature.