• Title/Summary/Keyword: Ag+ solution

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Mode of Occurrence and Compositional Variation of Electrum from the Dunjeon and Baegjeon Gold Deposits (둔전(屯田) 및 백전광상(栢田鑛床)에서 산출(産出)되는 에렉트럼의 산출상태(産出狀態)와 조성변화(組成變化))

  • Lee, Chan Hee;Park, Hee-In
    • Journal of the Mineralogical Society of Korea
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    • v.6 no.2
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    • pp.94-104
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    • 1993
  • The compositional variation of electrums from gold-silver and antimony deposits in the Dunjeon Baegjeon mining area, range from 22.6 to 69.5 atom% of Ag. Ag contents in electrums vary with paragenetic sequences and associated minerals. Ag contents increase from core to margin in a single grain. Compositional range of electrums from the North ore deposits of the Dunjeon gold mine are from 22.6 to 29.5 atom% of Ag. Electrums contain Cu(0.40 to 0.55 atom%) and Bi(0.35 to 0.67 atom%). Composition of electrums from the South ore deposits of the Dunjeon gold mine vasies from 33.6 to 69.5 atom% of Ag. Cu and As contents in electrums range from 0.20 to 1.92 and from 0.70 to 1.90 atom%, respectively. As the content of Ag in electrums increase, the contents of Bi and As in electrums increase but that of Cu decrease. Electrums of the Baegjeon gold deposits contain 35.6 to 63.5 atom% of Ag, suggesting that Au contents in electrums associated with base metal sulfied be higher than those associate with Ag-minerals. Ag/Au rations in electrums increase with decreasing temperature, salinity and $fs_2$ of the mineralizing solution.

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Studies on the Emission control of methanol engine exhaust with modified 3-way catalyst at cold start condition (변형된 삼원촉매에 의한 저온시동조건에서의 메탄올엔진 배가스 정화효과에 관한 연구)

  • 홍종성;정석진
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.2
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    • pp.160-167
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    • 1993
  • As the major methanol fueled vehicle exhaust components, formaldehyde & methanol conversion over the existing commercial 3-way catalyst was examined in a labolatory tains different Ag loadings on commercial 3-way catalyst, and german commercial catalysts for methanol engine exhaust manufactured by a commercial manufacturer. Silver catalysts were prepared by the wet impregnation of silver nitrate solution on commercial 3-way catalyst. These catalysts were characterized with BET Surface area and pore size distribution. In general, the formaldehyde(HCHO) conversion of the tested catalysts was similar to that of methanol$(CH_3OH)$. At 100$^\circ$C, which is equivalent to the cold start condition, 5wt% Ag cat. showed the most excellent HCHO and $CH_3OH$ conversion. The order of activity for conversion of HCHO & $CH_3OH$ to carbon dioxide and water vapor was as follows ; 5wt% Ag/3-way cat.>2wt% Ag/3-way cat.>german cat. front(1) > german cat. rear(2) > 10wt% Ag/3-way cat.> commercial 3-wat catalyst. However there was no significant activity difference between those tested catalysts in the hot run condition of 400$^\circ$C. Therefore, it could be concluded that the Ag-modified 3-way catalyst was the most effective and practical catalyst system which could be capable of removal the HCHO and methanol at the special condition of low temperature such as cold start condition.

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Determination of Ag(Ⅰ) Ion at a Modified Carbon Paste Electrode Containing N,N'-Diphenyl Oxamide

  • Won, Mi-Sook;Yeom, Jeong-Sik;Yoon, Jang-Hee;Jeong, Euh-Duck;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • v.24 no.7
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    • pp.948-952
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    • 2003
  • New approach for the determination of Ag(I) ion was performed by using a carbon paste electrode (CPE) containing N,N'-Diphenyl oxamide (DPO) with anodic stripping voltammetry. The CMEs have been prepared by making carbon paste mixtures containing an appropriate amount of DPO salt coated onto graphite particles to analyze trace metal ions via complexation followed by stripping voltammetry. Various experimental parameters affecting the response, such as pH, deposition time, temperature, and electrode composition, were carefully optimized. Using differential pulse anodic stripping voltammetry, the logarithmic linear response range for the Ag(I) ion was 1.0 × $10^{-7}$ - 5.0 × $10^{-9}$ M at the deposition time of 10 min, with the detection limit was 7.0 × $10^{-10}$ M. The detection limit adopted from anodic stripping differential pulse voltammetry was 7.0 × $10^{-10}$ M for silver and the relative standard deviation was ± 3.2% at a 5.0 × $10^{-8}$ M of Ag(I) ion (n = 7). The proposed electrode shows a very good selectivity for Ag(I) in a standard solution containing several metals at optimized conditions.

Positively Charged Silver Nanoparticles Threaded on Carbon Nanotube for the Efficient Delivery of Negatively Charged Biomolecules

  • Park, Hyung-Seok;Hwang, Ji-Young;Shin, Ueon-Sang;Kim, Hae-Won;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.10
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    • pp.3581-3586
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    • 2011
  • Silver nanoparticle (Ag-NPs)-immobilized and amine-functionalized carbon nanotubes (MWCNTs), MWCNT-Ag-$NH_2$, were easily prepared in order to develop an efficient delivery system of biomolecules without complicated processes of manufacture. For this, Ag-NPs-immobilized MWCNTs, MWCNT-Ag, were initially prepared in order to create large surface area to enable more efficient linkage with guest-molecules using pristine MWCNTs. The Ag-NPs on MWCNTs were further positively functionalized with 2-aminoethanthiol to allow ionic linkage with biomolecules. Ultimately, the positively charged delivery system proved to be highly effective for the binding capacity of bovine serum albumin (BSA) as a negatively charged model protein, when compared to that of lysozyme used as a positively charged model protein. The releasing profile of BSA was observed in almost linear pattern for about two weeks in a saline solution. This study demonstrated the potential usefulness of the pristine MWCNTs in conjunction with Ag-NPs for the selective delivery of many (negatively or positively) charged biomolecules including proteins and genes.

Chiral Separation of Arylalcohols by Capillary Electrophoresis Using Sulfonated β-Cyclodextrin and Ag Colloids as Additives

  • Choi, Seong-Ho;Noh, Hyen-Ju;Lee, Kwang-Pill
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1549-1554
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    • 2005
  • Chiral separation of arylalcohols such as 1-phenyl-1-propanol, 1-phenyl-2-propanol, and 2-phenyl-1-propanol by capillary electrophoresis was studied using sulfonated $\beta$-cyclodextrin (CD) as a chiral selector and Ag colloids as an additive. The optimum separation condition of arylalcohols was found to be the chiral selector concentration of 6.5 mM, applied voltage of 15 kV, and pH of 7.0. In order to improve chiral separation, an Ag colloid was mixed with a running buffer. The resolution in the Ag colloid-mixed running buffer was considerably superior to that obtained with the sulfonated $\beta$-CD alone. The molar ratio of sulfonated $\beta$-CD to Ag colloid, which is one of critical parameters affecting resolution, was found to be optimum at 65 : 1. In order to elucidate the resolution mechanism, an inclusion-complex of the arylalcohols with sulfonated $\beta$-CD was prepared by mixing and shaking in solution, and then characterized by cyclic voltammetry (CV). The inclusion mechanism was also discussed using experimental results.

Fabrication of Silver Nanowire-Graphene Oxide Hybrid Transparent Conductive Thin Film with Improved Mechanical Stability (기계적 안정성이 향상된 은나노와이어-그래핀옥사이드 하이브리드 투명 전도성 박막의 제작)

  • Kim, Ju-Tae;Woo, Ju Yeon;Han, Chang-Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.32 no.10
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    • pp.903-909
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    • 2015
  • In this study, we used GO (graphene oxide) in order to enhance the adhesion between Ag NWs (nanowires) and substrates. By using a mixture solution of GO and Ag NW, a vacuum filtration process was used to fabricate a 50nm diameter thin film. Next, by using a light annealing process, the mechanical and electrical stability of Ag NW network was improved without any other treatment. The physical properties of the Ag NW - GO hybrid transparent conductive thin film was characterized in terms of a bending test, resistance and transmittance test, and nanoscale imaging using field-emission scanning electron microscopy.

Identification of 4-Chlorobenzoate Dechlorinating Bacteria by Simple Plate Assay (평판배지법에 의한 4-chlorobenzoate 탈염소화 세균의 검색)

  • Chae, Jong-Chan;Kim, Chi-Kyung;Min, Kyung-Hee;Park, Yong-Keun
    • Microbiology and Biotechnology Letters
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    • v.23 no.1
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    • pp.104-109
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    • 1995
  • The gene responsible for dechlorination of 4-chlorobenzoate (4CBA) was cloned in E. coli XL1-Blue from Pseudomonas sp. DJ-12. The cloned cell of E. coli Cjl had the hybrid pBluescript SK(+) plasmid, into which about 9.5 kb genomic DNA fragment of PseudOmonas sp. DJ-12 was inserted. The subclone of pCJlOl was constructed by inserting the 3.4 kb EcoRI-HindIII fragment of pCJl into the vector. Those cloned cells could be simply selected by halo formation around the colonies which was the precipitate of AgCl produced by reaction of AgNO$_{3}$ and chloride ion liberated by bacterial dechlorination of 4CBA- Such a plate assay method was standardized by the procedure that the colonies grown for 2 days on the Cl$^{-}$-free plate medium containing 1 mM 4CBA were flooded with 0.1 M AgNO$_{3}$ solution.

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Flexible OTFT-OLED Display Panel using Ag-paste for Source and Drain Electrodes

  • Ryu, Gi-Seong;Kim, Young-Bea;Song, Hyun-Jin;Song, Chung-Kun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1789-1791
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    • 2007
  • We fabricated OTFT-OLED display panel by using Ag-paste for source and drains electrode of OTFTs. The OTFTs were fabricated by solution processes such as spin-coating for PVP gate dielectric and screen printing for S/D electrodes with Ag-paste, except pentacene active layer which was deposited by evaporation. The mobility was 0.024 cm2/V.sec , off state current ${\sim}10-11A$, threshold voltage 7.6 V and on/off current ratio ${\sim}105$. The panel consisted of 16 x 16 pixels and each pixel consisted of 2 OTFTs, 1 Capacitor and 1 OLED. The pixels successfully worked in terms of current magnitude supplied to OLED and the control ability of driving and switching OTFTs.

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Photoelectrochemical Converision with $SrTiO_3$ Ceramic Electrodes ($SrTiO_3$ 세라믹 전극에 의한 광전기 화학변환)

  • 윤기현;김태희
    • Journal of the Korean Ceramic Society
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    • v.22 no.3
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    • pp.19-24
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    • 1985
  • The phtoelectrochemical porperties of $Nb_2O_5$, $Sb_2O_3$ and $V_2O_5$ doped and pure $SrTiO_3$ ceramic electodes were investigated. Shapes of I-V and I-λ characteristics of the pure $SrTiO_3$ ceramic electrode are similar to those of SrTiO3 single crystal electorde ; the anodic current strats at -0.9V (vs. Ag/AgCI) in 1 N-NaOH aqueous solution and the photoresponse appears at a wavelength of about 390nm and the quantum efficiency is about 3.5% at wavelength of 390nm under 0.5V vs. Ag/AgCl. Photocurrents of $Nb_2O_5$, $Sb_2O_3$ and $V_2O_5$ doped electrodes and $V_2O_5$ doped ceramic electrode appears at wavelength of 390nm and 500nm respectively.

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Effect of Inorganic Nanomater ials on the Morphology and Thermal Proper ties of PVA Nanocomposite Nanowebs

  • Choi, Jae-Young;Yeum, Jeong-Hyun
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.83-89
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    • 2011
  • Poly(vinyl alcohol) (PVA), PVA/Montmorillonite (MMT), PVA/Silver (Ag), and PVA/MMT/Ag nanocomposite nanowebs were prepared by electrospinning technique in aqueous solution. In order to investigate the effect of inorganic materials on the morphology and thermal properties of PVA based nanocomposite nanowebs, experiments were performed with 5 wt.% of MMT and Ag. Field emission type scanning electron microscopy, transmission electron microscopy (TEM), reflection type X-ray diffraction (XRD), and thermal gravimetric analyzer were utilized to characterize nanocomposite nanowebs. TEM and XRD results show MMT and Ag were well dispersed in PVA nanowebs. Those inorganic nanoparticles enhanced thermal property of the nanocomposite nanowebs.