• 제목/요약/키워드: Ag$_2$O

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친환경 Ag-SnO2 전기접점재료의 분말야금 공정 최적화 (Process Optimization of Environment-Friendly Ag-SnO2 Electric Contact Materials through a Powder Metallurgy)

  • 김정곤
    • 한국분말재료학회지
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    • 제14권5호
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    • pp.327-332
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    • 2007
  • In a view point of environment, the advanced electric contact material without environmental load element such as cadmium has to be developed. Extensive studies have been carried out on $Ag-SnO_2$ electric contact material as a substitute of Ag-CdO contact materials. In the present study, powder metallurgy including compaction and sintering is introduced to solve the incomplete oxidation problems in manufacturing process of $Ag-SnO_2$ electrical contact material. The $Ag-SnO_2$ contact material, fabricated in this study, was actually set in an electric switchgear of which working voltage is 462V and current is between 25 and 40A, for the purpose of testing its performance. As a result, it exceeded the existing Ag-CdO contact materials in terminal-temperature ascent and main contact resistance.

확산방지막에 따른 $TiO_2/M/Ag/M/TiO_2$ 투명 열절연 박막의 광학적 성질 (Optical Properties of $TiO_2/M/Ag/M/TiO_2$ Films with Different Diffusion Barrier Layers)

  • 이경준;이진구;박주동;김진현;김영환;오태성
    • 한국진공학회지
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    • 제5권2호
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    • pp.147-155
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    • 1996
  • Optical properties of $TiO_2/M/Ag/M/TiO_2$ films have been changed with the diffusion barrier metal M. Optimum opticla properties of $TiO_2/M/Ag/M/TiO_2$ as the transparent heat mirror film, could be obtained with Ti among diffusion barrier metals of Ti, Cu, Zr and Al. $TiO_2/M/Ag/M/TiO_2$ film, which was fabricated by sputtering of 18 nm-thick $TiO_2$ and Ag, and 4nm-thick Ti, showed maximum transimittance of 89% at visible wavelength and infrared reflectance of 97% at wavelength of 3000 nm. Optical properties of this film was not degraded by Xenon-sunshine weather test for 240 hours. For specimens with barrier layers of Cu, Zr, and Al, degradation of optical properties by weather test was increased in a sequence of films with Cu, Zr, and Al barrier layers.

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PL and TL behaviors of Ag-doped SnO2 nanoparticles: effects of thermal annealing and Ag concentration

  • Zeferino, R. Sanchez;Pal, U.;Melendrez, R;Flores, M. Barboza
    • Advances in nano research
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    • 제1권4호
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    • pp.193-202
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    • 2013
  • In this article, we present the effects of Ag doping and after-growth thermal annealing on the photoluminescence (PL) and thermoluminescence (TL) behaviors of $SnO_2$ nanoparticles. $SnO_2$ nanoparticles of 4-7 nm size range containing different Ag contents were synthesized by hydrothermal process. It has been observed that the after-growth thermal annealing process enhances the crystallite size and stabilizes the TL emissions of $SnO_2$ nanostructures. Incorporated Ag probably occupies the interstitial sites of the $SnO_2$ lattice, affecting drastically their emission behaviors on thermal annealing. Both the TL response and dose-linearity of the $SnO_2$ nanoparticles improve on 1.0% Ag doping, and subsequent thermal annealing. However, a higher Ag content causes the formation of Ag clusters, reducing both the TL and PL responses of the nanoparticles.

Passivation of organic light emitting diodes with $Al_2O_3/Ag/Al_2O_3$ multilayer thin films grown by twin target sputtering system

  • Jeong, Jin-A;Kim, Han-Ki
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.420-423
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    • 2008
  • The characteristics of $Al_2O_3/Ag/Al_2O_3$ multilayer passivaton prepared by twin target sputtering (TTS) system for organic light emitting diodes. The $Al_2O_3/Ag/Al_2O_3$ multilayer thin film passivation on a PET substrate had a high transmittance of 86.44 % and low water vapor transmission rate (WVTR) of $0.011\;g/m^2$-day due to the surface plasmon resonance (SPR) effect of Ag interlayer and effective multilayer structure for preventing the intrusion of water vapor. Using synchrotron x-ray scattering and field emission scanning electron microscope (FESEM) examinations, we investigated the growth behavior of Ag layer on the $Al_2O_3$ layer to explain the SPR effect of the Ag layer. This indicates that an $Al_2O_3/Ag/Al_2O_3$ multilayer passivation is a promising thin film passivation scheme for organic based flexible optoelectronics.

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TiO2/Si3N4/Ag/Si3N4/TiO2 다층구조에서 Si3N4 버퍼층이 투과율에 미치는 영향 (Effect of Si3N4 Buffer Layer on Transmittance of TiO2/Si3N4/Ag/Si3N4/TiO2 Multi Layered Structure)

  • 이서희;장건익
    • 한국전기전자재료학회논문지
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    • 제25권1호
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    • pp.44-47
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    • 2012
  • The $TiO_2/Si_3N_4/Ag/Si_3N_4/TiO_2$ multi layered structure was designed for the possible application of transparent electrodes in PDP (Plasma Display Panel). Multi layered film was deposited on a glass substrate at room temperature by DC/RF magnetron sputtering system and EMP (Essential Macleod Program) was adopted to optimize the optical characteristics of film. During the deposition process, the Ag layer in $TiO_2/Ag/TiO_2$ became heavily oxidized and the filter characteristic was degraded easily. In thus study, Si3N4 layer was used as a diffusion buffer layer between $TiO_2$ and Ag. in order to prevent the oxidation of Ag layer in $TiO_2/Si_3N_4/Ag/Si_3N_4/TiO_2$ structure. It was confirmed that $Si_3N_4$ layer is one of candidate materials acting as diffusin barrier between $TiO_2/Ag/TiO_2$.

Sonochemical Synthesis and Sonocatalysis Performance Behavior of Ag2Se and Ag2Se/TiO2 Nanocomposites

  • Zhu, Lei;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제52권6호
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    • pp.489-496
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    • 2015
  • In this study, novel $Ag_2Se$ sensitized $TiO_2$ nanocomposites were prepared by facile sonochemical assisted synthesis method. The as-prepared products were characterized by X-ray diffraction (XRD), Scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM), and N2 adsorption BET analysis. The as-prepared $Ag_2Se/TiO_2$ nanocomposites simultaneously possessed great adsorptivity for organic dyes and efficient charge separation properties. In the decolorization of rhodamine B, a significant enhancement in the reaction rate was observed for the $Ag_2Se/TiO_2$ nanocomposite compared to the cases of using pure P25 or $TiO_2$. The sonocatalysis activity was higher due to the greater formation of reactive radicals, as well as to the increase of the active surface area of the $Ag_2Se/TiO_2$ nanocomposite.

스크린 프린팅 기법을 이용한 $SnO_2-Ag_2O-PtO_x$계 반도체식 마이크로 수소 가스센서에 관한 연구 (Semiconductor type micro gas sensor for $H_2$ detection using a $SnO_2-Ag_2O-PtO_x$ system by screen printing technique)

  • 김일진;한상도;이희덕;왕진석
    • 한국수소및신에너지학회논문집
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    • 제17권1호
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    • pp.69-74
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    • 2006
  • Thick film $H_2$ sensors were fabricated using $SnO_2$ loaded with $Ag_2O$ and $PtO_x$. The composition that gave the highest sensitivity for $H_2$ was in the weight% ratio of $SnO_2 : PtO_x : Ag_2O$ as 93 : 1 : 6. The nano-crystalline powders of $SnO_2$ synthesized by sol-gel method were screen printed with $Ag_2O$ and $PtO_x$ on alumina substrates. The fabricated sensors were tested against gases like $H_2$, $CH_4$, $C_3H_8$, $C_2H_5OH$ and $SO_2$. The composite material was found sensitive against $H_2$ at the working temperature $130^{\circ}C$, with minor interference of other gases. The $H_2$ gas as low as 100 ppm can be detected by the present fabricated sensors. It was found that the sensors based on $SnO_2-Ag_2O-PtO_x$ system exhibited the high performance, high selectivity and very short response time to $H_2$ at ppm level. These characteristics make the sensor to be a promising candidate for detecting low concentrations of $H_2$.

전자접촉기의 접촉소재에 따른 동작속도 비교 연구 (Comparative Study on Operational Speeds Based on Contact Material of Magnetic Contactor)

  • 고영진
    • 전기전자학회논문지
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    • 제27권3호
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    • pp.246-250
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    • 2023
  • 전자접촉기의 연구에 있어서 접촉부의 소재 및 재질에 따른 아크소호를 중심으로 연구가 되고 있으나, 최근 직류기기의 활용과 고속처리가 요구됨에 따라 접촉기의 동작속도가 중요시되고 있다. 일반적으로 AgSnO2소재가 AgCdO보다 응답특성이 우수하다고 알려져 있으나, 소재 특성 차원에서 알려져 있다. 이에 본 논문에서는 전자접촉기의 완성품을 구성하여 AgSnO2소재와 AgCdO소재에 대하여 동작속도를 비교하도록 하였으며, 실험을 통해 검증하도록 하였다.

Ag와 $Y_2BaCuO_5$ 가 고온초전도체의 임계특성에 미치는 영향 (The Effects of Ag and $Y_2BaCuO_5$ on Critical Characteristics of $YBa_2Cu_3O_X$ Fabricated by MPMG Method)

  • 임성훈
    • 한국전기전자재료학회논문지
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    • 제11권6호
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    • pp.493-501
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    • 1998
  • $YBa_2Cu_3O_X$ samples were fabricated by MPMG(Melt Powdered Melt Growth). Intitial composition of the mixed powders were prepared as follow ; $YBa_2Cu_3O_X$ : $Y_2BaCuO_5$ = 1:0, 1:0.2, 1:0.3, 1:0.4. After the first melt and cooling, 5wt% to 20wt% fo Ag power was added to the powder. Effects of the different initial $Y_2BaCuO_5$ and Ag addition amount on $J_c$ and magnetization of $YBa_2Cu_3O_X$ fabricated by MPMG method were investigated. The critical current density increased with the amount of $Y_2BaCuO_5$ and Ag. It was also observed that the difference between negative and positive magnetization in the magnetization hysteresis measurement at 77K was larger than the case where $Y_2BaCuO_5$and Ag were not added to the $YBa_2Cu_3O_X$ powders. It is concluded that $Y_2BaCuO_5$ sample with 40wt% amount of $Y_2BaCuO_5$ and 20wt% amount of Ag has not only the largest $J_c$ but also the improved pinning effect.

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Electrochemical Reduction of SiO2 Granules to One-Dimensional Si Rods Using Ag-Si Eutectic Alloy

  • Lee, Han Ju;Seo, Won-Chul;Lim, Taeho
    • Journal of Electrochemical Science and Technology
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    • 제11권4호
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    • pp.392-398
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    • 2020
  • Producing solar grade silicon using an inexpensive method is a key factor in lowering silicon solar cell costs; the direct electrochemical reduction of SiO2 in molten salt is one of the more promising candidates for manufacturing this silicon. In this study, SiO2 granules were electrochemically reduced in molten CaCl2 (850℃) using Ag-Si eutectic droplets that catalyze electrochemical reduction and purify the Si product. When Ag is used as the working electrode, the Ag-Si eutectic mixture is formed naturally during SiO2 reduction. However, since the Ag-Si eutectic droplets are liquid at 850℃, they are easily lost during the reduction process. To minimize the loss of liquid Ag-Si eutectic droplets, a cylindrical graphite container working electrode was introduced and Ag was added separately to the working electrode along with the SiO2 granules. The graphite container working electrode successfully prevented the loss of the Ag-Si eutectic droplets during reduction. As a result, the Ag-Si eutectic droplets acted as stable catalysts for the electrochemical reduction of SiO2, thereby producing one-dimensional Si rods through a mechanism similar to that of vapor-liquid-solid growth.